Low-temperature thermoelectric properties of α- and β-Zn4Sb3 bulk crystals prepared by a gradient freeze method and a spark plasma sintering method

The low temperature thermoelectric properties of Zn₄Sb₃ samples prepared by the gradient freeze (GF) method and sintering have been characterized. With decreasing temperature a dramatic rise in the thermal expansion is observed associated with the structural transition from β- to α-phase; Δl/l=2.8×10⁻⁴ at T_s^GF=257.4 K for GF and Δl/l=1.6×10⁻⁴ at T_s^S=236.5 K for sintered samples. Enhancement is observed in electrical conductivity and p-type thermopower at T_s^GF and T_s^S, while a reduction is observed in the magnetic susceptibility. The GF sample exhibits higher thermoelectric performance than the sintered sample. The power factor of the α-phase in the GF sample is twice as large as that of the β-phase; it exceeds 20 μW/cm·K² between 120 and 240 K, indicating that the α-phase Zn₄Sb₃ is one of the prime candidates for thermoelectric materials for cryogenic use.     

Application of human thermal load into unsteady condition for improvement of outdoor thermal comfort

Human thermal comfort is studied as a countermeasure to the thermal stress in outdoor urban space. Outdoors, people experience the strong impact of solar radiation in states that are unsteady and non-uniform. The feeling of comfort is a mixed sensation that can be easier to improve overall, as compared with a global large-scale effort, and can lead to improved ways of saving energy and reducing costs. Moreover, this can be directly beneficial to human experience and fulfill natural human desires. Since a thermal comfort index is a useful tool for understanding the present state and evaluating the impact of countermeasures, we examine the effects of the human thermal load, which is a thermal comfort index based on the energy balance of the human body. In a steady state, and even in an unsteady state with its variations in weather and human factors, thermal comfort values can generally be obtained by using the overall human thermal load. The reason for this is that the human thermal load takes physiological factors in account as well as weather parameters. This leads to the idea that thermal sensations follow from the human thermal load, which can then well describe a given human environment. As a result, human sensations as expressed by the human thermal load pave the way to the creation of comfortable urban spaces that require minimum expense and energy as an example of simple heat transport model focusing on urban outer structure.     

Process integration technologies for sub-half micron BiCMOS LSls

Contents The process integration issues and various approches to reduce process steps for high performance/low cost sub-half micron BiCMOS LSIs are reviewed. Using these technologies, the bipolar transistor process is added with minimum increase in process complexity, while maintaining compatiblity with a state-of-the-art CMOS process. Future prospects for high performance BiCMOS device/process technologies are addressed.

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Technologien der Prozeßintegration für Sub-half Micron BiCMOS LSls

Übersicht Aspekte der Prozeßintegration sowie verschiedene Ansätze zur Reduzierung der Prozeßschritte für hochleistungsfähige und preisgünstige sub-half micron BiCMOS LSIs werden in diesem Aufsatz diskutiert. Die Anwendung der zu beschreibenden Technologien ermöglicht das Hinzufügen des Bipolartransistor-Prozesses bei einem nur minimalen Anstieg der Prozeßkomplexität und Erhalt der Kompatibilität zur gegenwärtigen CMOS-Technologie. Abschließend werdenZukunftsperspektiven der BiCMOS-Technologie erörtert.

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The authors would like to thank Drs. M. Kamoshida, K. Okada and M. Nakamae for their encouragement throughout this work.     

Effects of some carbide stabilizing elements on creep-rupture strength and microstructural changes of 18-10 austenitic steel

The creep rupture test has been carried out for 18Cr-10Ni-0.1 wt pct C stainless steels bearing individually Ti, Nb(Cb), and V, followed by the microstructural study. The highest value of 700°C-10⁴ h rupture strength in a titanium and niobium series (the steel containing various amounts of titanium and niobium, respectively) has been obtained at Ti/C and Nb/C atomic ratio of 0.8 and 0.2 to 0.4, respectively. On the other hand, in a vanadium series, the creep rupture strength of the steel showed its maximum at V/C atomic ratio of about unity in the testing at the temperature of 700° and 800°C, but at 600°C, the strength increases monotonically with vanadium content up to 1.53 wt pct. Such high strength in the steels con-taining proper amount of Ti, Nb, and V is related mainly with the fine distribution of M₂₃C₆ precipitates which is caused by the acceleration of nucleation due to the foregoing precipi-tation of a MC type carbide within the austenite grains. And it has been deduced that the solid solution strengthening effect of the vanadium contributes also to the remarkable in-crease in the rupture strength of the vanadium steel at 600°C.