In-Flight Particle Measurement of Alkali-Free Glass Raw Materials in 12-Phase AC Arc Plasma

In-flight particle measurements of the surface temperature and velocity are important for understanding of melting behavior of glass particles during in-flight melting by multi-phase AC arc plasma. However, the use of optical pyrometry for particle surface temperature has inevitable uncertainties due to non-thermal emissions signals from the plasma plume. This work presents spectroscopic measurements of the non-thermal signals which were found to be caused mainly by the plasma emissions scattered by the particles and the radiation emitted by vapor. After that, the accuracy of thermal radiation measurement was estimated and surface temperature of in-flight glass particle was corrected.     

Measurement of the coating thickness on the back side of double-sided coated structures by means of acoustic resonant spectroscopy

This paper describes a technique for measuring the thickness of the back side coating of a double-sided coated structure using acoustic resonance. The technique is used to observe the resonant frequency of high frequency ultrasound for a steel/coating/air structure. The resonant frequency of the transmitted ultrasound occurs when a quarter wavelength corresponds to the thickness of the back side coating, and the reflection coefficient has a minimum value. The top surfaces of the samples are covered with a coating about 30 μm thick and the thickness of the back side coating is in the range of 10.3-17.5 μm. The resonant frequencies for the examined samples are observed in the frequency range of 46.8-75.6 MHz, and the thickness of the back side coating can be accurately determined from the measured resonant frequency. Note that the coating on the top surface of the structure does not affect the thickness measurement accuracy of the back side coating.     

Chaotic behavior of an elastoplastic bar in tensile test over a wide range of strain rate: a numerical investigation

Numerical tensile tests of an elastoplastic cylindrical bar at various high strain rates are performed by the use of a dynamic explicit FEM code (DYNA3D, a public domain version). The effects of mass (inertia) of the body, strain rate and strainrate sensitivity exponent (m-value) on the deformation pattern and the load curve are investigated. As for the material, strain-dependent nth power work hardening property is given by where is strain rate. The range of the prescribed average strain rate is 50–1000/s where the tensile tests with constant average strain rate and with constant tensile velocity are performed. Materials with higher density exert a greater influence on deformation mode at a high strain rate. Even if the tensile speed is less than that of plastic wave propagation, the deformation becomes non-uniform remarkably due to mass effect. It is unexpected that double necking occurs at certain computational conditions. The strain at maximum load point predicted by the numerical simulation does not coincide with the analytically predicted one. Maximum rate of decrease in cross sectional area within the straight portion of the bar is compared with Hart's instability criterion based on the imperfection in the cross section. In high-rate tension over , deformation behavior is chaotic in the sense that it varies very sensitively with a trivial change in material properties and/or in the prescribed strain rate.     

A numerical study of various plastically unstable behaviors in tension and compression

Various types of behavior due to plastic instability under uniaxial tension and compression are numerically investigated regarding sheet materials, plane strain blocks, and cylindrical bars and hollow cylinders. The code GOLDA for analysis of large elastic-plastic deformation previously developed by the author is used, which is one of quasi-static explicit FEM programs. Both of diffuse type and localized type of instability are concerned with. The role of vertex-hardening in plastic instability is payed attention, by using the J2G (J2-Gotoh’s corner theory) as the plasticity constitutive equation, which was proposed previously by the author and is a kind of vertex-hardening theory. Following results are mainly derived. 1) In plane strain tension, shear-type strain localization is realized by the use of J2G, but not by the conventional J2F (J2-flow theory). In axisymmetric tension of a cylindrical solid bar, however, such strain localization would never appear even by J2G, as expected by the experiment. 2) In axisymmetric tension of a hollow cylinder under the condition of no contractlion of its bore (therefore, in almost plane strain state with no circumferential strain), it is found that shear-type strain localization could occur. This is realized again by the use of J2G, whereas J2F never allows such strain localization. 3) In compression under the embedded edges condition, it is found that a sheet with initial aspect ratio of 2:1 (in height:breadth) yields double barreling, whereas a plane strain block yields double barreling at the initial aspect ratio of 3:1, not at 2:1 though expected from the conventional slip-line theory. As for a cylindrical solid bar, double barreling appears for the initial aspect ratio of 2:1 but only for higher n-vaiue (the strain hardening exponent), say n=0.5. 4) As for barreling mode, when thick-walled axisymmetric tubes with the initial ratio of thickness to inner diameter 1/5 to 1/3 are compressed axially, corresponding to the initial aspect ratios of 3:1, 2:1 and 1:1, triple barreling, double barreling and single barreling appear, respectively. 5) It is found that thin-walled tubes buckle in a progressive periodic mode with almost stationary compressive load under axial compression. Thus it can be used as a simplified model for buckling of more complex structures such as the honeycomb.     

Leaching of cell wall components caused by acid deposition on fir needles and trees

Virgin fir forests have been declining since the 1960s at Mt. Oyama, which is located at the eastern edge of the Tanzawa Mountains and adjacent to the Kanto plain in Japan. An acid fog frequently occurs in the mountains. We collected throughfall and stemflow under fir trees and rainfall every week during January-December 2004 at Mt. Oyama to clarify the influence of acid fog on the decline of fir (Abies firma) needles. In relation to throughfall and stemflow, D-mannose, D-galactose, and D-glucose are the major neutral sugar components; only D-glucose is a major component of rainfall. The correlation coefficient between the total neutral sugars and uronic acid (as D-galacturonic acid), which is a key component of the cross-linking between pectic polysaccharides, was high except for rainfall. The leached amount of calcium ion, neutral sugars, uronic acid, and boron is related to the nitrate ion concentration in throughfall. Results of a laboratory exposure experiment using artificial fog water simulating the average composition of fog water observed at Mt. Oyama (simulated acid fog: SAF) on the fir seedling needles also shows a large leaching of these components from the cell walls of fir needles. The leaching amount increased concomitantly with decreasing pH of the SAF solution. We also observed that a dimeric rhamnogalacturonan II-borate complex (dRG-II-B) that exists in the cell wall as pectic polysaccharide was converted to monomeric RG-II (mRG-II) by the leaching of calcium ion and boron. Results not only of field observations but also those of laboratory experiments indicate a large effect of acid depositions on fir needles.     

Permeability differences based on three-dimensional geometrical information of void spaces

In this study,the permeabilities of Berea and Otway sandstones were measured under different confining pressures,and porosity was investigated through mercury intrusion porosimetry(MIP).The total porosities of the Berea and Otway sandstones were approximately 17.4%and 25%,respectively.Pore size distributions of each sandstone were almost the same,but the pores in the Otway sandstone were slightly narrower.However,the permeability of the Otway sandstone was smaller than that of the Berea sandstone by one order of magnitude.Three-dimensional(3D)void geometry and geometrical properties of the void spaces relevant to flow were compared to obtain the relation between the permeability differences and porosities of the two sandstones.The 3D geometrical analysis using microfocus X-ray computed tomography(CT)was performed,and the pore geometries of both sandstones were compared using the 3D medial axis(3DMA)method.Pore and throat radii,pore coordination number,tortuosity,number of connecting paths,connecting path volume,and other factors were determined using 3DMA.The Otway sandstone was characterized by a small effective throat/pore radius ratio.Based on the fluid flow mechanism,the lower effective throat/pore radius ratio results in a lower permeability induced by the fluid energy loss,which means that the 3D geometrical shape of void spaces affects the permeability value.     

Indoor boundary layer chemistry modeling

Ozone (O₃) chemistry is thought to dominate the oxidation of indoor surfaces. We consider the hypothesis that reactions taking place within indoor boundary layers result in greater than anticipated hydroxyl radical (OH) deposition rates. We develop models that account for boundary layer mass‐transfer phenomena, O₃‐terpene chemistry and OH formation, removal, and deposition; we solve these analytically and by applying numerical methods. For an O₃‐limonene system, we find that OH flux to a surface with an O₃ reaction probability of 10^?8 is 4.3 × 10^?5 molec/(cm² s) which is about 10 times greater than predicted by a traditional boundary layer theory. At very low air exchange rates the OH surface flux can be as much as 10% of that for O₃. This effect becomes less pronounced for more O₃‐reactive surfaces. Turbulence intensity does not strongly influence the OH concentration gradient except for surfaces with an O₃ reaction probability >10^?4. Although the O₃ flux dominates OH flux under most conditions, OH flux can be responsible for as much as 10% of total oxidant uptake to otherwise low‐reactivity surfaces. Further, OH chemistry differs from that for ozone; therefore, its deposition is important in understanding the chemical evolution of some indoor surfaces and surface films.     

Stabilization by harmonic intensities for the output signal in heterodyne detection

We experimentally demonstrated that the technique to stabilize the output signal by harmonic intensities is useful in heterodyne detection with an incoherent light source such as a halogen lamp. The relation between the relative standard deviation of an output signal and the fluctuation of the light intensity is analyzed and simulated. Using the fundamental to sixth harmonics increases the stabilities of output signal approximately 3 times, and subtracting the relative standard deviation of the intensity of light source enhances the stabilities 49 times. The fluctuating phase that is due to the fluctuating frequency and temperature and its power spectrum density for an interferometer is also calculated with the Allan variance.     

Effect of geometry and dielectric material on thermo-mechanical strain on micro-vias in build-up substrates

Build-up substrates have been preferable solutions for small and high performance systems for more than a few decades. Micro-vias need to be smaller to realize ever higher wiring density in build-up substrates, but there has been concern on the reliability. This paper focuses on Cu filled micro-vias of 25 μm in diameter and investigates the strain on micro-vias using a finite element method for varying geometric parameters and material properties. The strain becomes smaller with shrinking micro-vias, and a prediction equation for the strain is developed as a function of the aspect ratio and material properties for both single and stacked micro-vias.     

Experimental characterization of high-speed impact damage behavior in a three-dimensionally woven SiC/SiC composite

This paper discusses high-speed impact damage in a three-dimensionally woven SiC/SiC composite (3D-CMC). The impact damage was introduced by a steel ball projectile in 3D-CMC plates with and without thermal exposure. The surface and internal damages were observed by optical microscopy and X-ray CT. A crater was observed on the collision surface. The X-ray CT measurement revealed that multiple pyramid-shaped cone cracks were generated beneath the crater when the impact speed was relatively low. At an impact speed exceeding the critical speed, a spall fragment was ejected from the back surface, while no internal damage was observed in the fragment. The spall fracture mode differed between the virgin and the thermally-exposed specimens. This difference is the result of embrittlement of the fiber/matrix interface due to oxidation of the carbon coating layer in the thermally-exposed specimen. In addition, it is found that z-yarns improve impact resistance by constraining delamination.