The Numerical Comparison of Heat Transfer in a Coated and Fixed Bed of an Adsorption Chiller

Ecological adsorption technology is becoming a focus of attention by industry due to the utilization of low grade thermal energy sources for cooling production. It can be a promising part of sustainable development concept of the global economy. Therefore, research aiming at improving their performance i.e. Coefficient of Performance (COP) by optimizing the construction of sorption beds with a built in heat exchanger system is crucial. The heat transfer characteristics between the bed of porous media (sorbent) and surface of the heat exchanger system determine the heating power of an adsorption chiller. The HP increase can be obtained by heat transfer intensification due to the increase in the thermal conductivity of the sorbent layer in the vicinity of the heat exchanger’s surface. The novel modification of the sorbent layer structure is proposed in the paper in order to improve the heat transfer processes in the heat exchanger boundary layer. The analysis of desorption process conditions in the parametric model of a coated and fixed adsorption bed design is presented in the paper. The computational fluid dynamics (CFD) with conjugate heat transfer analysis is used to determine the crucial input parameters (temperature distribution in the sorbent bed) for further analytical calculations. The commercial code Ansys Fluent was used to perform numerical simulations. The developed computational model consisted of three subdomains representing heating water, heat exchanger material (copper) and sorbent (silica gel). The comparison of a novel coated design and a conventional fixed bed is discussed in the paper. The numerical analysis is based on experimental thermal conductivity measurements of the sorbent layer in different configurations, which were performed using Laser Flash Method.     

On Stochastic Modeling of Interface Defects in Composite Materials

The article presents mathematical and computational research dealing with the problem of stochastic interface defects occurring in composite materials between their constituents. A mathematical model of the periodic composite with such defects is presented in detail, as well as probabilistic numerical methods enabling computational experiments which are shown in a further part of the text. The fiber-reinforced and laminated composite has been tested in numerical tests as well as the superconducting coil cable-four-component composite to verify how the structural defects considered, according to the model introduced, influence the static behavior of the composites analyzed. All the results obtained and discussed in the article are summarized in concluding remarks which show the directions of further model development, while numerous references enable the reader to study the problem further.     

Antimicrobial Activity of a Pullulan–Caraway Essential Oil Coating on Reduction of Food Microorganisms and Quality in Fresh Baby Carrot

This research evaluated the antimicrobial efficacy of pullulan films containing caraway essential oil (CEO). The films were prepared from a 10% of pullulan, containing from 0.12% to 10.0% of CEO. The composition of the CEO was analyzed with the use of gas chromatography. The antimicrobial activity of the CEO was evaluated with the method of serial microdilutions, and the films containing CEO—with the agar diffusion method against selected Gram‐negative, Gram‐positive bacteria, and fungi. The structure of the film surface and its cross‐section were analyzed using a scanning electron microscope (SEM). Analyses were also carried out to determine the efficacy of a pullulan coating with 10% CEO on baby carrots experimentally inoculated with Salmonella enteritidis, Staphylococcus aureus, Saccharomyces cerevisiae, or Aspergillus niger and stored at a room temperature for 7 d. At a concentration of 0.12%, CEO inhibited the growth of all the tested microorganisms. Pullulan films containing 8% to 10% of CEO were active against all tested microorganisms. Populations of S. aureus on carrot samples were reduced by approximately 3 log CFU/g, while those of A. niger and S. cerevisiae by, respectively, 5 and 4 log CFU/g, after 7 d of storage. S. enteritidis was the most resistant among the tested species, since it was not significantly reduced after 7 d of storage. At the end of storage, samples treated with pullulan–caraway oil coating maintained better visual acceptability than control samples. Results of this study suggest the feasibility of applying a pullulan film with incorporated CEO to extend the microbiological stability of minimally processed foods.     

Identification of Mg<Subscript>2</Subscript>Cu particles in Cu-alloyed austempered ductile iron

In the present work, the Mg₂Cu precipitates in copper-alloyed austempered ductile iron (ADI) were identified by analyzing techniques such as TEM and SEM with EDS. It was revealed that, in castings made of ADI-containing copper, highly dispersed particles of Mg₂Cu are formed, whose size does not exceed <1 μm. The research work was carried out on ductile iron that was austenitized at 900 °C, followed by austempering at 380 °C. The microstructure was investigated using various techniques, including optical microscopy, XRD, SEM, and TEM. In addition to this, the exhibited impact properties of castings with Cu, Ni, and Cu+Ni were also determined. This study casts a new light on the formation of the structure of Cu-alloyed ADI. The highly-dispersive and brittle Mg₂Cu particles that are located in the vicinity of the graphite nodules have a negative effect on the impact properties of ADI. It has also been shown that impact strength decreases from levels of 160-180 J (for copper-free ADI) to 90-120 J (for copper-and copper-nickel-alloyed ADI).     

Block cipher based on reversible cellular automata

We propose a new encryption algorithm relying on reversible cellular automata (CA). The behavior complexity of CA and their parallel nature makes them interesting candidates for cryptography. The proposed algorithm belongs to the class of symmetric key systems. Marcin Seredynski: He is a Ph.D. student at University of Luxembourg and Polish Academy of Sciences. He received his M.S. in 2004 from Faculty of Electronics and Information Technology in Warsaw University of Technology. His research interests include cryptography, cellular automata, nature inspired algorithms and network security. Currently he is working on intrusion detection algorithms for ad-hoc networks. Pascal Bouvry, Ph.D.: He earned his undergraduate degree in Economical & Social Sciences and his Master degree in Computer Science with distinction (’91) from the University of Namur, Belgium. He went on to obtain his Ph.D. degree (’94) in Computer Science with great distinction at the University of Grenoble (INPG), France. His research at the IMAG laboratory focussed on Mapping and scheduling task graphs onto Distributed Memory Parallel Computers. Next, he performed post-doctoral researches on coordination languages and multi-agent evolutionary computing at CWI in Amsterdam. He gained industrial experience as manager of the technology consultant team for FICS in the banking sector (Brussels, Belgium). Next, he worked as CEO and CTO of SDC (Ho Chi Minh city, Vietnam) in the telecom, semi-conductor and space industry. After that, He moved to Montreal Canada as VP Production of Lat45 and Development Director for MetaSolv Software in the telecom industry. He is currently serving as Professor in the group of Computer Science and Communications (CSC) of the Faculty of Sciences, Technology and Communications of Luxembourg University and he is heading the Intelligent & Adaptive Systems lab. His current research interests include: ad-hoc networks & grid-computing, evolutionary algorithms and multi-agent systems.     

Rigorous Numerical Approach to Isolation in Dynamical Systems on the Example of the Kuramoto-Sivashinsky Equation

This paper describes a method of rigorous verification of an isolating neighborhood based on computer assisted computations. As an application we study the Kuramoto-Sivashinsky equation. The result of the computer assisted proof was directly used in [9] to prove the existence of heteroclinic solutions of the Kuramoto-Sivashinsky equation.     

New Results in Minimum-Comparison Sorting

We prove that sorting 13, 14 and 22 elements requires 34, 38 and 71 comparisons, respectively. This solves a long-standing problem posed by Knuth in his famous book The Art of Computer Programming, Volume 3, Sorting and Searching. The results are due to an efficient implementation of an algorithm for counting linear extensions of a given partial order. We also present some useful heuristics which allow us to decrease the running time of the implementation.     

Liquid / liquid ion-transfer processes at the dioctylphosphoric acid (N,N-didodecyl-N',N'-diethylphenylenediamine) / water (electrolyte) interface at graphite and mesoporous TiO2 substrates

Biphasic electrode systems are studied for the case of the oxidation of the water-insoluble liquid N,N-didodecyl-N',N'-diethylphenylenediamine (DDPD) neat and dissolved in bis(2-ethylhexyl) phosphate (HDOP) and immersed in aqueous electrolyte media. The oxidation process in the absence of HDOP is accompanied by transfer of the anion (perchlorate or phosphate) from the water into the organic phase. However, in the presence of HDOP, oxidation is accompanied by proton exchange instead. This electrochemically driven proton exchange process occurs over a wide pH range. Organic microdroplet deposits of DDPD in HDOP at basal plane pyrolytic graphite electrodes are studied by voltammetric techniques and compared in their behavior to organic microphase deposits in mesoporous TiO2 thin films. The mesoporous TiO2 thin film acts as a host for the organic liquid and provides an alternative biphasic electrode system compared to the random microdroplet/graphite system. Two types of mesoporous TiO2 thin-film electrodes, (i) a 300-400-nm film on ITO and (ii) a 300-400-nm film on ITO sputter-coated with a 20-nm porous gold layer, are investigated.     

Charge-Density-Wave Pseudogap and Two-Dimensional Superconductivity Within Strong-Coupling Description

We have considered the role of charge-density-pseudogap for phonon-mediated super-conductivity on two-dimensional lattice. The propagators that enter generalized Eliashberg equations have been renormalized to account for quasi-particle energies related to the formation of the pseudogap, which has been assumed to be of d-wave symmetry. We have evaluated the superconducting transition temperature T_c as a function of doping. It occurs that T_c for d-wave symmetry well reflects experimental behavior. Our results for the isotope shift exponent show that at low doping, the presence of the pseudogap may contribute to > 1/2 as well as to > 1/2 values.     

Analysis of VME-Bus communication protocol - RTCP-net approach

The paper discusses an RTCP-net approach to design and analysis of an example of VMEbus communication protocol. RTCP-nets are a novel Petri net class, based on time coloured Petri nets but were defined to give users powerful tools for easy and rapid design of real-time systems. Page templates are one of the main advantages of the new nets' design stage. Just modifying values of parameters in the page hierarchy graph is enough to change some features of a modelled system. Therefore, it is easy to experiment on different versions of the same model with very little additional effort. It is also very easy to reorganize page templates in order to model a different structure of a system.Relevant definitions and main properties of RTCP-nets are presented in the paper. A VMEbus communication protocol case study is used to demonstrate some applications of this approach.The work is carried out within KBN Research Project, Grant No. 4 T11C 035 24. Marcin Szpyrka received the M.S. degree in mathematics from the Rzeszów University (Poland) in 1997. He received the Ph. D. degree in computer science from AGH University of Science and Technology in Kraków (Poland) in 2000. Marcin Szpyrka is currently an assistant professor at the Institute of Automatics, AGH-UST. His research interests include: formal methods (Petri nets, process algebras), real-time systems and safety-critical systems. He has published over 40 papers and one book.