Macle et structure cristalline de Mn0,75Ga2,17S4

Twins of $\text{Mn}{}_{\mathrm{<mtext>1?</mtext><mtext>x</mtext>}}\text{Ga}{}_{\mathrm{<mtext>2+</mtext><mtext>2</mtext><mtext>3</mtext><mtext>x</mtext>}}\text{S}{}_4$ were used for crystal structure determination. Twinning is explained by a reticular pseudomerihedry. Axis, plane and obliquity of the twin have been determined. Cell dimensions are: $\text{a = b}\text{= 5.456(2)}\text{A}\text{?}$; $\text{c}\text{= 10.220(4)}\text{A}\text{?}$; α = β = γ = 90°; space group 14; Z = 2. The final R value is 0.059. The material is isostructural with CdGa₂S₄.     

Half-life of 60Fe

The half-life of ⁶⁰Fe has been measured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= (1.49 ± 0.27) × 10}{}^6$ a, significantly longer than the one previous measurement of Roy and Kohman which reported a value of 3 × 10⁵ a uncertain by a factor of 3. The present value was obtained from measurements of specific activity and radioisotope concentration in a material produced by spallation of copper with 191 MeV protons. ⁶⁰Fe/Fe ratios in the range of 10^?8 were measured with the Argonne FN tandem-superconducting linear accelerator system in conjunction with an Enge split-pole spectrograph. The specific activity of ⁶⁰Fe in Fe was measured through the grow-in of the 1.332 MeV gamma-ray line of the ⁶⁰Co daughter activity.     

Prediction of weld pool and reinforcement dimensions of GMA welds using a finite-element model

Mathematical models of the gas metal arc (GMA) welding process may be used to study the influence of various welding parameters on weld dimensions, to assist in the development of welding procedures, and to aid in the generation of process control algorithms for automated applications. In this work, a three-dimensional (3-D), steady-state thermal model of the GMA welding process has been formulated for a moving coordinate framework and solved using the finite-element method. The model includes temperature-dependent material properties, a new finite-element formulation for the inclusion of latent heat of fusion, a Gaussian distribution of heat flux from the arc, plus the effects of mass convection into the weld pool from the melted filler wire. The influence of weld pool convection on the pool shape was approximated using anisotropically enhanced thermal conductivity for the liquid phase. Weld bead width and reinforcement height were predicted using a unique iterative technique developed for this purpose. In this paper, the numerical model is shown to be capable of predicting GMA weld dimensions for individual welds, including those with finger penetration. Also, good agreement is demonstrated between predicted weld dimensions and experimentally derived relations that describe the effects of process variables and their influence on average weld dimensions for bead-onplate GMA welds on steel plate. E. PARDO, formerly Postdoctoral Fellow, Department of Mechanical Engineering, University of Waterloo, Waterloo, ON, Canada N2L 3G1,     

Systeme Ga2S3FeS — Diagramme de phase — etude cristallographique

The system was studied by DTA, X-ray diffraction and in particular by the Guinier-Lenné method. Eight intermediate phases are described. 1) Three solid solutions in the Ga₂S₃ region : a) a wurtzite-type solid solution (T > 1000° C ; 0.05 < n < 0.23) (n = Fe $\text{at}\text{Fe}$ at+Ga at), b) a blende-type solid solution (700°C < T < 980°C ; 0.10 < n < 0.20) with many stacking faults, c) a non-stoichiometric hexagonal phase α'Ga₂S₃ type (T < 700°C, 0.07 < n < 0.12). 2) for n = 0.20 and T = 540°C a superstructure of orthorhombic wurtzite-like array FeGa₄S₇. 3) From n = 0.20 through n = 0.27, a non stoichiometric superstructure of tetragonal-like array has the CdGa₂S₄ type (600°C < T < 1030°C). 4) For n = 0.33, the FeGa₂S₄ has two forms depending from the temperature : a) a low temperature form is trigonal ; b) a high temperature form is orthorhombic type ZnAl₂S₄. Transition temperature is 1010°C. 5) For n = 0.50, Fe₂Ga₂S₅ polytypes : a) Fe₂Ga₂S₅α 1T type Mn₂Ga₂S₅ ; b) Fe₂Ga₂S₅ 2H ; c) Fe₂Ga₂S₅ 3R type Mn₂Al₂Se₅. A phase diagram is proposed.     

Etude des proprietes magnetiques,Mössbauer et electriques du compose lamellaire FeGa2S4α 1T

FeGa₂S₄α 1T shows a lamellar crystal structure characterized by an alternative localization in host sulfur framework of Fe,Ga and vacancies planes parallel to the c axis of the unit cell. Single crystals have been obtained by chemical vapor transport reaction with I₂ or Cl₂ as transporting agent. Magnetic, mössbauer and electrical experiments were performed on single crystals. Magnetic susceptibility deviates from the Curie-Weiss behaviour in explorated temperature range 4.2–300 K but the high temperature asymptote indicates a probable Fe²⁺ high spin state. At approximately 17 K susceptibility shows a maximum which is corrolated to an antiferromagnetic ordering at low temperature. Magnetic properties are discussed in the view of a two dimensional model. Electrical properties are in agreement with semiconducting state; mobility of the charge carriers is low.     

Characterization of grape seed oil from different grape varieties (Vitis vinifera)

In this work, oil obtained from seeds of different red grape varieties, grown in the Autonomous Regions of Castilla‐La Mancha and Murcia (Spain), was characterized by determining physicochemical and sensory quality parameters, stability, and the composition in fatty acids and sterols. The physicochemical quality parameters (free acidity, peroxide index, K₂₇₀ and wax) scored high (meaning low quality) compared with virgin olive oils, while the negative sensory attributes stood out over the positive ones. Therefore, the oil was not considered suitable for table use without undergoing a refining process. The samples showed high linoleic and low linolenic acid contents, while β‐sitosterol was the main sterol found. Drying grape seeds with hot air before extraction gave higher physicochemical quality, total phenolic content and stability, and lower wax content in comparison to air‐drying of seeds. The drying process affected the sterol composition but not the fatty acid composition.     

Differentiation of co-winemaking wines by their aroma composition

Co-winemaked Monastrell wines with Cabernet Sauvignon or Merlot, at different proportions have been studied for first time in terms of its odor activity value (OAV) in young wines, aging wines (after 9 months in French oak barrels) and bottled aging wines (aging wines after 6 months in the bottle). The co-winemaking wines showed a different aromatic complexity as they were fruitier and sweeter than the monovarietal ones, enhancing their aroma characteristics, being more evident at 60:40 proportion in case of Merlot for young and aging wines and Cabernet Sauvignon for bottled ones. In terms of extractable oak compounds, Monastrell–Merlot wines showed the highest values suggesting that they may need a shorter period within the barrel than Monastrell–Cabernet Sauvignon ones.     

Source time reversal (STR) method for linear elasticity

We study the problem of source reconstruction for a linear elasticity problem applied to seismicity induced by mining. We assume the source is written as a variable separable function $\mathit{f}\left(\mathit{x}\right)g\left(t\right)$. We first present a simple proof a local decay result for elasticity in the case of homogeneous media. We then extend the source time reversal method, originally developed for acoustic waves, to an elastic system of waves. Additionally, we present a fast reconstruction implementation for large data sets. This is especially useful in the elastic case, in which the numerical cost is higher than in fluid acoustics. We complement this work with several 2D and 3D numerical experiments and an analysis of the results.     

Development of electron beam ion source charge breeder for rare isotopes at Californium Rare Isotope Breeder Upgrade

Recently, the Californium Rare Isotope Breeder Upgrade (CARIBU) to the Argonne Tandem Linac Accelerator System (ATLAS) was commissioned and became available for production of rare isotopes. Currently, an electron cyclotron resonance ion source is used as a charge breeder for CARIBU beams. To further increase the intensity and improve the purity of neutron-rich ion beams accelerated by ATLAS, we are developing a high-efficiency charge breeder for CARIBU based on an electron beam ion source (EBIS). The CARIBU EBIS charge breeder will utilize the state-of-the-art EBIS technology recently developed at Brookhaven National Laboratory (BNL). The electron beam current density in the CARIBU EBIS trap will be significantly higher than that in existing operational charge-state breeders based on the EBIS concept. The design of the CARIBU EBIS charge breeder is nearly complete. Long-lead components of the EBIS such as a 6-T superconducting solenoid and an electron gun have been ordered with the delivery schedule in the fall of 2011. Measurements of expected breeding efficiency using the BNL Test EBIS have been performed using a Cs(+) surface ionization ion source for external injection in pulsed mode. In these experiments we have achieved ～70% injection∕extraction efficiency and breeding efficiency into the most abundant charge state of ～17%.