Strategies to obtain pattern fidelity in nanowire growth from large-area surfaces patterned using nanoimprint lithography

Position controlled nanowire growth is important for nanowire-based optoelectronic components which rely on light emission or light absorption. For solar energy harvesting applications, dense arrays of nanowires are needed; however, a major obstacle to obtaining dense nanowire arrays is seed particle displacement and coalescing during the annealing stage prior to nanowire growth. Here, we explore three different strategies to improve pattern preservation of large-area catalyst particle arrays defined by nanoimprint lithography for nanowire growth. First, we see that heat treating the growth substrate prior to nanoimprint lithography improves pattern preservation. Second, we explore the possibility of improving pattern preservation by fixing the seed particles in place prior to annealing by modifying the growth procedure. And third, we show that a SiN _x growth mask can fully prevent seed particle displacement. We show how these strategies allow us to greatly improve the pattern fidelity of grown InP nanowire arrays with dimensions suitable for solar cell applications, ultimately achieving 100% pattern preservation over the sampled area. The generic nature of these strategies is supported through the synthesis of GaAs and GaP nanowires.

Open image in new window

     

Conformance testing in systems with semicontrollable interfaces

In a conformance testing environment, an implementation under test (iut) communicates with multiple entities. A tester may have differing degrees of control on the interactions between these entities and the iut : directly controllable, semicontrollable, or uncontrollable. Semi-controllable inputs most likely render portions of an IUT untestable. In addition, multiple communicating entities may create race conditions during testing. This paper presents a test generation methodology for systems where the semicontrollable inputs can be generated indirectly. The test sequences obtained from the converted graph fully utilize the semicontrollable inputs (where possible) while avoiding the race conditions. Although, for the most general case, the graph conversion results in a exponentially large number of nodes, practical considerations make the converted graph size feasible. This approach is used to generate tests for mil-std 188-220B. By applying the proposed graph conversion and the race condition elimination techniques, the number of testable state transitions increased from approximately 200 to over 700, which represents a coverage of 95% of the transitions defined in the specification.     

A New Analyzer Based on Pellistor Sensor with Neural Network Data Postprocessing for Measurement of Hydrocarbons in Lower Explosive Limit Range

We present the results of a first stage of development work on a new type of analyzer for hydrogen and C₁–C₃ hydrocarbons concentration measurements in the lower explosive limit range, based on single pellistor sensor with artificial neural network data postprocessing.     

Terminal Mannose Residues in Seminal Plasma Glycoproteins of Infertile Men Compared to Fertile Donors

The impact of seminal plasma components on the fertilization outcomes in humans is still under question. The increasing number of couples facing problems with conception raises the need for predictive biomarkers. Detailed understanding of the molecular mechanisms accompanying fertilization remains another challenge. Carbohydrate–protein recognition may be of key importance in this complex field. In this study, we analyzed the unique glycosylation pattern of seminal plasma proteins, the display of high-mannose and hybrid-type oligosaccharides, by means of their reactivity with mannose-specific Galanthus nivalis lectin. Normozoospermic infertile subjects presented decreased amounts of lectin-reactive glycoepitopes compared to fertile donors and infertile patients with abnormal semen parameters. Glycoproteins containing unveiled mannose were isolated in affinity chromatography, and 17 glycoproteins were identified in liquid chromatography-tandem mass spectrometry with electrospray ionization. The N-glycome of the isolated glycoproteins was examined in matrix-assisted laser desorption ionization mass spectrometry. Eleven out of 27 identified oligosaccharides expressed terminal mannose residues, responsible for lectin binding. We suggest that lowered content of high-mannose and hybrid type glycans in normozoospermic infertile patients may be associated with impaired sperm protection from preterm capacitation and should be considered in the search for new infertility markers.     

Use of grape by‐product as a source of dietary fibre and phenolic compounds in sourdough mixed rye bread

The study evaluated the effect of grape by‐products (GP) on the chemical composition, soluble (SDF) and insoluble (IDF) dietary fibre, phenolic compounds and antioxidant activity (AA) and organoleptic characteristics of sourdough mixed rye bread. The following samples of sourdough mixed rye bread were prepared: control bread (BC) and breads with GP at four different levels: 4%, 6%, 8% and 10%. Addition of GP significantly improves dietary fraction contents, as bread with a 10% addition of GP accounts for 39% and 37% higher contents of IDF and SDF than BC. The assay of radical‐scavenging activity and reducing ability showed that GP addition greatly enhanced antioxidant properties of mixed rye breads. Profiles of phenolic compounds of supplemented breads were dominated by procyanidin B1 and B2, catechin, epicatechin, caffeic acid and myricetin. With an increase in the level of GP, the hardness and gumminess of the bread significantly increase. Although both BC and supplemented breads showed common volatile compound profiles, there were slight differences in the concentrations of those components. Sensory evaluation of GP‐enhanced breads revealed that a maximum of 6% GP could be incorporated to prepare acceptable products.     

Oligocarbonate diols from ethylene carbonate—Optimization of the synthesis process

Oligocarbonate diols due to their resistance to oxidation and hydrolysis are particularly valuable components of polyurethanes for biomedical applications. It was shown that for their synthesis “green monomer,” ethylene carbonate can be used in the reaction with 1,6‐hexanediol, instead of usually applied toxic and harmful phosgene. Depending on reaction conditions, besides ester exchange leading to the desired product, competitive etherification is often observed. To optimize the reaction conditions leading to oligocarbonates of high molecular weight without oxyethylene fragments, the method of an experimental design was applied. Such approach enabled the estimation of the influence of reaction temperature, ethylene carbonate to 1,6‐hexanediol molar ratio and catalyst (NaCl) concentration on the molar mass of oligocarbonate diol, content of ether bonds and reaction time. Application of central composite method as an experimental design allowed not only to choose the optimal set of conditions, but also the coefficients of the regression equation were interpreted in a chemical way. Oligocarbonate diols obtained under optimal conditions were used for synthesis poly(urethane‐urea)s which exhibited very good mechanical properties (tensile strength 45–50 MPa and elongation at break up to 500%). © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Characterization of catalysts obtained from rapidly quenched alloy precursors by electrochemical/chemical processes of material degradation—selected examples

Rapidly quenched amorphous alloys—containing metallic or metalloid elements—are precursors for selective catalysts of many technically important reactions. To increase their activity, various methods of material degradation occurring at the surface and in the bulk of the rapidly quenched alloys have been used for promoting the catalytic performance of such materials. The modifications of the structure, composition, and morphology of the substrate proved to be efficient in transforming inactive metal alloy precursors into active and selective catalysts for hydrogenation, and dehydrogenation of organic compounds, as well as for other processes like steam reforming of methanol. This article presents several examples of characterization of such catalysts and discusses their selectivity and activity in a connection with physical and chemical properties of their surfaces. Moreover, it is shown that scanning electron microscopy, Auger electron spectroscopy, scanning Auger microscopy, and energy dispersive spectrometry allowed the local changes occurring during the activation process to be identified and their implications for catalytic function to be considered.     

Supported gold clusters and cluster-based nanomaterials: characterization, stability and growth studies by in situ GISAXS under vacuum conditions and in the presence of hydrogen

This contribution is devoted to study of the thermal stability and growth of gold nanoparticles supported on SiO₂/Si(111) and Al₂O₃/SiO₂/Si(111) as a function of initial cluster size, support material and level of surface coverage. Experimental evidence for “flipping” of two dimensional cluster structures from vertical orientation to horizontal on the support is presented.     

MCFC versus other fuel cells—Characteristics, technologies and prospects

Characteristics of molten carbonate fuel cell (MCFC) were critically compared to these of polymer electrolyte membrane fuel cell (PEMFC), alkaline fuel cell (AFC), phosphoric acid fuel cell (PAFC) and solid oxide fuel cell (SOFC). In comparison to the other fuel cells, the MCFC operates with the lowest current densities due to limited zones of effective electrode reactions and low solubilities of oxygen and hydrogen in molten carbonates; also it has a thickest electrodes–electrolyte assembly. In consequence, the applications of MCFC are almost limited to stationary power generators. Although the MCFC stationary power generators have now approached high technological level of precommercialization, in the future they may face a serious contest from SOFC and PEMFC, for which improvement of operational parameters is believed to be achieved easier.