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991.
Martin PA Daum R Beil A Vogt U Vital A Graehlert W Leparoux M Hopfe V 《Applied spectroscopy》2004,58(5):543-551
The in situ Fourier transform infrared (FT-IR) spectrum of gasphase SiO produced in silicon oxynitride fiber growth has been quantitatively analyzed. Both absorption and emission FT-IR spectra at a spectral resolution of 0.5 cm(-1) were produced from the reaction zone at 1450 degrees C. The fundamental and hot bands were observed with vibrational levels up to v = 7. For the purposes of quantitative analysis the individual vibration-rotation integrated line strengths for the three main isotopes,( 28)SiO,( 29)SiO, and( 30)SiO, were calculated based on ab initio quantum chemical calculations of the electric dipole moment function and the transition moment. Vibrational anharmonicity and Hermann-Wallis correction factors were also incorporated. From the line strengths at specific temperatures and the known Dunham coefficients, the absorbance spectrum was simulated with best fits giving the averaged SiO concentration in the 400 mm reaction zone of 1.0 x 10(17) molecules/cm(3). Such quantitative measurements demonstrate the power of in situ infrared (IR) spectroscopy combined with quantum chemical calculations. The rapid determination of synthetic calibration datasets for chemometric analysis can thus lead to correlation of gas-phase species concentrations with fiber growth properties and subsequently to real-time process control. 相似文献
992.
We prove upper bounds for combinatorial parameters of finite
relational structures, related to the complexity of learning a
definable set. We show that monadic second-order (MSO) formulas
with parameters have bounded Vapnik–Chervonenkis dimension over
structures of bounded clique-width, and first-order formulas with
parameters have bounded Vapnik–Chervonenkis dimension over
structures of bounded local clique-width (this includes planar
graphs). We also show that MSO formulas of a fixed size have
bounded strong consistency dimension over MSO formulas of a fixed
larger size, for labeled trees. These bounds imply positive
learnability results for the PAC and equivalence query learnability
of a definable set over these structures. The proofs are based on
bounds for related definability problems for tree automata. 相似文献
993.
Karol?MikulaEmail author Tobias?Preusser Martin?Rumpf 《Computing and Visualization in Science》2004,6(4):197-209
We present a morphological multi-scale method for image sequence processing, which results in a truly coupled spatio-temporal anisotropic diffusion. The aim of the method is not to smooth the level-sets of single frames but to denoise the whole sequence while retaining geometric features such as spatial edges and highly accelerated motions. This is obtained by an anisotropic spatio-temporal level-set evolution, where the additional artificial time variable serves as the multi-scale parameter. The diffusion tensor of the evolution depends on the morphology of the sequence, given by spatial curvatures of the level-sets and the curvature of trajectories (=acceleration) in sequence-time. We discuss different regularization techniques and describe an operator splitting technique for solving the problem. Finally we compare the new method with existing multi-scale image sequence processing methodologies. 相似文献
994.
Frecer V Kabelác M De Nardi P Pricl S Miertus S 《Journal of molecular graphics & modelling》2004,22(3):209-220
We have designed small focused combinatorial library of hexapeptide inhibitors of NS3 serine protease of the hepatitis C virus (HCV) by structure-based molecular design complemented by combinatorial optimisation of the individual residues. Rational residue substitutions were guided by the structure and properties of the binding pockets of the enzyme's active site. The inhibitors were derived from peptides known to inhibit the NS3 serine protease by using unusual amino acids and alpha-ketocysteine or difluoroaminobutyric acid, which are known to bind to the S1 pocket of the catalytic site. Inhibition constants (Ki) of the designed library of inhibitors were predicted from a QSAR model that correlated experimental Ki of known peptidic inhibitors of NS3 with the enthalpies of enzyme-inhibitor interaction computed via molecular mechanics and the solvent effect contribution to the binding affinity derived from the continuum model of solvation. The library of the optimised inhibitors contains promising drug candidates-water-soluble anionic hexapeptides with predicted Ki* in the picomolar range. 相似文献
995.
We give an overview of some generalized-ensemble techniques that have proven successful in all-atom simulations of proteins. We show that these techniques enable efficient investigations of secondary structure formation and folding in peptides and small proteins. Results are presented for various alanine-based artificial peptides and a small protein, the 36-residued villin headpiece subdomain (HP-36). Our results indicate that all-atom simulations of proteins may be more restricted by the accuracy of the present energy functions than by the efficiency of the search algorithms. 相似文献
996.
Beginning with a model of social perception in which the perceiver is assumed to operate according to the conventional canons of statistical inference, it was hypothesized that trait judgments of groups of individuals represented by facial photographs would match the mean values of these photographs judged individually and that confidence and the amount of information required before a judgment is reported will vary inversely with the variance in the set of photographs comprising the group, and directly with the significance of the judgment for the judge. Using different procedures and measures of the dependent variables, 2 experiments were performed which agreed in supporting the hypotheses. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
997.
The fields scattered from small dielectric spheres illuminated by a plane wave have been computed as part of a study of spherical dielectric antennas. Studies of scattering of 3 cm wavelength from a 6.6 cm diameter sphere of dielectric constant between 2 and 3 show large regions on the surface of the sphere where the Poynting vector is inwardly directed. These regions form sidelobes of inwardly directed power density between the sidelobes of outwardly directed power density in the principal planes. Away from the sphere the angular extent of the centripetal power flow is reduced until they disappear at 2-3 cm from the surface. 相似文献
998.
Mohammad A. Alim Martin A. Seitz Richard W. Hirthe 《Journal of the American Ceramic Society》1988,71(1):52-C-
The ac electrical response of the grain boundary in the ZnO–Bi2 O3 -based varistor system (in the frequency range 10−2 ≤f≤107 Hz) has been analyzed using complex plane analysis techniques as a function of temperature (90°≤T≤150°C) and electric field (E60%lmA/cm2 ≤E≤ElmA/cm2 ). The high-temperature/field data were best represented in the impedance plane. The lumped parameter equivalent circuit representation, containing a voltage variable resistive element associated with the grain boundary, was in agreement with a model previously reported in the literature. The resulting equivalent circuit representation of the grain-boundary response consisting of a resistance and a capacitance are interpreted in terms of various phenomena occurring at the electrical thickness of the grain boundary. 相似文献
999.
The measured radiation pattern of a dielectric sphere fed from a conical horn is given. An appropriate matching device is shown to be a circular dielectric rod in the horn. Improvements in gain and circularity of the beam obtained by dielectric loading are demonstrated. 相似文献
1000.
Pettinati Helen M.; Evans Frederick J.; Orne Emily C.; Orne Martin T. 《Canadian Metallurgical Quarterly》1981,90(4):345
Evaluated memory for successful and unsuccessful responses to hypnotic suggestions in partially amnesic Ss and in those Ss with normal forgetting. Two analyses (278 undergraduates) demonstrated that highly hypnotizable Ss experiencing partial posthypnotic amnesia tended to show no selective recall for their successes or failures during amnesia, whereas the remainder of the Ss showed definite selective recall of hypnotic success posthypnotically. These findings support F. J. Evans and J. F. Kihlstrom's (see record 1974-06307-001) hypothesis that posthypnotic amnesia involves a disruption of memory organization and suggest that the phenomenon may be mediated by a restriction in the use of normally employed retrieval cues. (37 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献