Correlation of vibrational intensity with fluorescence lifetimes in π conjugated polymers

A series of novel pi (π) conjugated polymers, originating from the archetypical Polyphenylene vinylene, in which the phenyl units are successively replaced by the larger naphthyl and anthryl acene units, were previously found to have a well-defined relationship between their relative fluorescence yields and their vibrational characteristics, as determined by Raman spectroscopy. In this study the Strickler-Berg equation is used to probe the influence of continual substitution of higher order acene units into the conjugated backbone in terms of the variation of the radiative and non-radiative rates. The deconvolution of the radiative and non-radiative rates enables the correlation of the reduction of the Raman intensity and concomitant increase in the fluorescence yield with the reduction of the non-radiative rate. This confirms that the reduction of the non-radiative rate is the dominant process introduced by the vibrational confinement originating from systematic substitution of higher order acene units into the polymer backbone.     

Estrogen effects on the hyperactivity induced by (+)-MDMA and cocaine in female rats.

This study compared the effects of estrogen (E) on the hyperactivity induced by (+)-3,4-methylenedioxymethamphetamine (MDMA) with E effects on cocaine-evoked hyperactivity in female rats. Sprague-Dawley rats were ovariectomized (OVX); half of them received a 17β-estradiol (E?) implant (OVX + E). Three weeks later, rats received saline, (+)-MDMA (1, 2, or 4 mg/kg) or cocaine (5, 10, or 20 mg/kg), and locomotor activity was monitored. OVX + E rats exhibited greater locomotor hyperactivity in response to both psychostimulants than did OVX rats. The enhanced response to cocaine appeared within 5 min following drug injection whereas the enhanced response to (+)-MDMA was delayed for approximately 30 min. The differential effects of E on hyperactivity may be due to the unique profiles of dopamine (DA) and serotonin (5-HT) in response to (+)-MDMA and cocaine. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Linking of serially ordered lists by macaque monkeys (Macaca mulatta): List position influences.

Five monkeys (Macaca mulatta) were trained on 2 sets of 3 5-item serially ordered lists. Then, each set was either linked or not in a counterbalanced, within-subject design. Linking entailed training on the 2 pairs that ordered the 3 5-item fists into a single overall 15-item series. Choices on novel pairings after linking conditions attempted to define the unique contributions of knowledge of within-list ordinal position and between-lists link training. With linkage, the series was immediately treated as a 15-item ordered list. Without linkage, choices reflected list positions from initial learning, but continued testing with directional reward yielded gradual ordering into a 15-itern list. Apparently, monkeys remembered and used initial list-position information, but linkage allowed inference of an integrated serial relationship among items. Results supported primate list memory as an organizational process. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Effect of functionalization and boron and nitrogen substitution on some properties of carbon nanotubes

Molecular orbital calculations of the ionization potential of single wall carbon nanotubes having donor NH₂ and acceptor NO₂ groups bonded to the side walls and ends and boron and nitrogen substituted for carbon show substantial increases in ionization potential compared to carbon nanotubes with no functional groups and no carbon substitutions. The presence of a carbon vacancy on the side wall also causes a substantial increase in the ionization potential. The effect of tube length on the ionization energy is also calculated. The calculations also suggest that at appropriate levels of boron and nitrogen doping the armchair carbon nanotubes could be high temperature organic ferromagnetic materials.     

Investigations of two-stage-pseudospark switches for high-currentapplications

To avoid the lowering of the holdoff voltage due to the electrode erosion in one stage high current pseudospark switches (PSS), a two stage PSS with no axial aperture in the intermediate electrode was tested. For investigations a pulse generator was used generating peak currents up to 120 kA at a maximum voltage of 30 kV with a period length of 5 μs of a weakly damped sine wave with 90% current reversal. In comparison with a one stage PSS the breakdown characteristic was shifted to higher pressure. With a free floating intermediate electrode, the device could not be triggered, however, with additional capacities of a few nF between the three electrodes the discharge was ignited. The discharge in the second gap is triggered by the pseudospark discharge in the cathode gap, discharging the auxiliary capacities. Simultaneously, observation of both gaps with fast shutter photography showed an independent movement of the discharges in the two gaps. In the cathode gap as current increases, the discharge moves away from the center to the plane electrode surface as has been observed in the one stage PSS. However, in the anode gap the discharge moves away from the center after a contraction to the center. The two discharges are transmitted to metal vapor arc type discharges as the erosion patterns prove. With this kind of a two stage PSS holdoff voltages exceeding 35 kV would be possible. The characteristic switch data, i.e., delay and jitter, are nearly equal to a one stage PSS     

Pseudolesions in liver sonography

Two different molecular forms of cholecystokinin (CCK) were studied with respect to their modulatory effect on non-MHC restricted or natural killer (NK) cell cytotoxicity. NK activity of peripheral blood mononuclear cells was found to be hardly affected by co-incubation with either CCK-8 or CCK-33 within a physiological concentration range against K-562 or Caco-2 tumour target cells. NK activity by lamina propria mononuclear cells isolated from histologically normal intestinal mucosa was found to be enhanced dose-dependently by incubation with CCK-8 in the 4-h assay against K-562, but not in the prolonged 18-h assay or against Caco-2 targets. In contrast, CCK-8 showed a tendency to inhibit NK activity in the prolonged 18-h assay against K-562; however, these alterations were not found to be statistically significant. CCK-33 was not found to modulate the NK activity of lamina propria mononuclear cells. It is suggested that NK activity by lamina propria mononuclear cells may be stimulated preferentially by CCK-8 because this molecular form of CCK in particular predominates in the nervous tissue of the intestinal mucosa.     

Convoys of social support in childhood and early adolescence: Structure and function.

Little is known about social networks in childhood, and even less is known about the networks of ethnically diverse children. Interviews were conducted with 333 African-American, Anglo/European-American, and Hispanic-American public school children in Grades 1–2, 4–5, and 8–9. The research was based on the social convoy model (R. L. Kahn and T. C. Antonucci, 1980), in which social networks are viewed as dynamic hierarchic structures affording the provision of support across the life span. An adapted convoy mapping procedure evidenced good test–retest reliability at all ages, and convoy support measures were associated with self-concept and teacher-rated sociability and mood. For all ethnic groups, the results reflect the significance of close family relations across age, an increase in involvement with extended family in middle-childhood, and the emergent role of peers as support providers in adolescence. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Lexical familiarity and processing efficiency: Individual differences in naming, lexical decision, and semantic categorization.

College students were separated into 2 groups (high and low) on the basis of 3 measures: subjective familiarity ratings of words, self-reported language experiences, and a test of vocabulary knowledge. Three experiments were conducted to determine if the groups also differed in visual word naming, lexical decision, and semantic categorization. High Ss were consistently faster than low Ss in naming visually presented words. They were also faster and more accurate in making difficult lexical decisions and in rejecting homophone foils in semantic categorization. Taken together, the results demonstrate that Ss who differ in lexical familiarity also differ in processing efficiency. The relationship between processing efficiency and working memory accounts of individual differences in language processing is also discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)