Prediction of vortex penetration depth at thermal stratification by cavity flow in a branch pipe with closed end (effect of heat radiation condition on temperature fluctuations)

In a branch pipe with one closed end, the cavity flow penetrates into the branch pipe from the main loop and a thermal boundary layer occurs because the cavity flow is a hot fluid, but heat removal causes a colder fluid in the branch pipe. This thermal stratification may affect the structural integrity. Therefore, a pipe design standard to suppress thermal fatigue should be established. The pipe design standard consists of the maximum penetration depth L_sv and the minimum penetration depth L_sh. In order to establish an evaluation method for L_sh, a visualization test and a temperature fluctuation test were carried out. A theoretical formula for thermal stratification was introduced from the heat balance model. Then the model was used to obtain an empirical equation from the map of fluid temperature fluctuation. This method can predict the vortex penetration depth by cavity flow in horizontal branch pipes. © 2006 Wiley Periodicals, Inc. Heat Trans Asian Res, 36(1):38–55, 2007; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20135     

Multi‐Enzymatic Synthesis of Optically Pure β‐Hydroxy α‐Amino Acids

A novel enzymatic production system of optically pure β‐hydroxy α‐amino acids was developed. Two enzymes were used for the system: an N‐succinyl L ‐amino acid β‐hydroxylase (SadA) belonging to the iron(II)/α‐ketoglutarate‐dependent dioxygenase superfamily and an N‐succinyl L ‐amino acid desuccinylase (LasA). The genes encoding the two enzymes are part of a gene set responsible for the biosynthesis of peptidyl compounds found in the Burkholderia ambifaria AMMD genome. SadA stereoselectively hydroxylated several N‐succinyl aliphatic L ‐amino acids and produced N‐succinyl β‐hydroxy L ‐amino acids, such as N‐succinyl‐L ‐β‐hydroxyvaline, N‐succinyl‐L ‐threonine, (2S,3R)‐N‐succinyl‐L ‐β‐hydroxyisoleucine, and N‐succinyl‐L ‐threo‐β‐hydroxyleucine. LasA catalyzed the desuccinylation of various N‐succinyl‐L ‐amino acids. Surprisingly, LasA is the first amide bond‐forming enzyme belonging to the amidohydrolase superfamily, and has succinylation activity towards the amino group of L ‐leucine. By combining SadA and LasA in a preparative scale production using N‐succinyl‐L ‐leucine as substrate, 2.3 mmol of L ‐threo‐β‐hydroxyleucine were successfully produced with 93% conversion and over 99% of diastereomeric excess. Consequently, the new production system described in this study has advantages in optical purity and reaction efficiency for application in the mass production of several β‐hydroxy α‐amino acids.

     

Close-Packed Silicon Lens Antennas for Millimeter-Wave MKID Camera

We have been developing a large-format millimeter-wave camera based on lens-antenna-coupled microwave kinetic inductance detectors (MKIDs) for a planned telescope at Dome Fuji (3810 m a.s.l.), Antarctica. Optical coupling to the MKID incorporates double-slot antennas and a silicon lens array. To realize a large-format camera ( \(>\) 10,000 pixels), a highly integrated small-diameter lens array and fast optics are required. Lens diameters of 1.2, 2, and 3 times the target wavelength are investigated for the main beam symmetry, side-lobe level, cross-polarization level, and bandwidth, considering the effects of the surrounding lenses. In this study, we present the simulated beam pattern profiles of close-packed lens antenna and the effect of misalignment between the silicon lens and double-slot antenna. We also show the evaluations of the developed 721-pixel close-packed silicon lens array.     

Simulation of migration from internal can coatings

Migration from can-coatings into retorted canned food simulants (canned oil and water, 121 degrees C, 30 min) was investigated through HPLC with a fluorescence detector and evaporative light scattering detector, and by measurements of residue on evaporation and consumption of potassium permanganate. HPLC analysis revealed that migration into the canned oil was hundreds of times more than that into n-heptane (25 degrees C, 60 min, the official test conditions according to the Japanese Food Sanitation Law), whereas it was similar to the migration into isooctane-butyl acetate mixtures (60 degrees C, 60 min), and that migration into the canned water was several times more than that into water (95 degrees C, 30 min, the official test conditions). Residue on evaporation for the n-heptane extract was several-fold lower than 30 ppm (the official limit), whereas that for the isooctane-butyl acetate mixtures exceeded 30 ppm. Consumption of potassium permanganate for the canned water was 30 times higher than that for the water extract (95 degrees C, 30 min). The official test conditions for can-coatings, in particular the use of n-heptane as an oil simulant, were suggested to lead to substantial underestimation of migration into canned food.     

Targeted proteome analysis of microalgae under high-light conditions by optimized protein extraction of photosynthetic organisms

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A Rapid and Simple Method for the Determination of 2-Alkylcyclobutanones in Irradiated Meat and Processed Foods

A rapid and simple method has been developed for the determination of 2-alkylcyclobutanone, 2-dodecylcyclobutanone (DCB), and 2-tetradecylcyclobutanone (TCB) in irradiated meat and processed foods. The procedure consists of extraction with n-hexane, following defatting and cleanup with a silica gel mini-column before gas chromatograph–mass spectrometry analysis. The method was evaluated using samples of beef, pork, Parmesan cheese, fried chicken, hamburger, gyoza (Chinese dumplings), and gyudon (boiled beef and onion seasoned with soy sauce and sugar). The recoveries of spiked DCB were 67–88 %, and those of TCB were 70–86 %. Furthermore, the method could detect DCB and TCB from samples irradiated at 1.0 and 2.6 kGy at levels dependent on dose; DCB and TCB were not detected in any nonirradiated samples. The method did not require special equipment, such as Soxhlet extraction, accelerated solvent extraction, or supercritical fluid extraction, for sample preparation. Thus, this method would be useful for determining DCB and TCB levels in irradiated meat and processed foods.     

A comparative study on cost and life‐cycle analysis for 100 MW very large‐scale PV (VLS‐PV) systems in deserts using m‐Si,a‐Si,CdTe, and CIS modules

This paper is a study of comparisons between five types of 100 MW Very Large‐Scale Photovoltaic Power Generation (VLS‐PV) Systems, from economic and environmental viewpoints. The authors designed VLS‐PV systems using typical PV modules of multi‐crystalline silicon (12·8% efficiency), high efficiency multi‐crystalline silicon (15·8%), amorphous silicon (6·9%), cadmium tellurium (9·0%), and copper indium selenium (11·0%), and evaluated them by Life‐Cycle Analysis (LCA). Cost, energy requirement, and CO₂ emissions were calculated. In addition, the authors evaluated generation cost, energy payback time (EPT), and CO₂ emission rates. As a result, it was found that the EPT is 1·5–2·5 years and the CO₂ emission rate is 9–16 g‐C/kWh. The generation cost was 11–12 US Cent/kWh on using 2 USD/W PV modules, and 19–20 US Cent/kWh on using 4 USD/W PV module price. Copyright © 2007 John Wiley & Sons, Ltd.     

Improvements in time resolution and signal-to-noise ratio in a compact pico-second pulse radiolysis system

A compact pico-second pulse radiolysis system has been developing at Waseda University for studying primary processes in radiation chemistry. The system is composed of a photo-injector system and a pico-second all-solid-state laser system. An infrared (IR) and an ultraviolet (UV) laser pulses are obtained from mode-locked Nd:YLF laser system and used for generation of the white light continuum as a probe light and the irradiation to the Cu cathode of a photo-cathode RF-gun, respectively. To improve signal-to-noise (S/N) ratio and time resolution of this pulse radiolysis system, we optimized both probe light and pump electron beam. As a result, our pico-second pulse radiolysis system has been enough to study the primary processes of radiation chemistry. The experimental results and the improvements of our system are described in this paper.     

Tracking and readout characteristics of a minute aperture mounted optical head slider flying above a chromium patterned medium

Recent rapid progress in a digital network society necessitates storage devices with higher-density and faster transfer rates. In optical storage, a novel recording principle is eagerly awaited that will drastically improve recording density without being restricted by a wavelength shortening limit or a numerical aperture (NA) limit of the optics utilized. Storage based on the “near-field” principle is thought to be one of the most promising breakthroughs for overcoming various limitations governing traditional optical recording. We have already proposed an integrated optical head slider assembly that relies on the novel near-field principle for its operation; it is mounted on a minute tapered aperture and has a planar focusing lens and a micro silicon mirror. Readout signals corresponding to a 200-nm-long bit have demonstrated a frequency band up to approximately 10 MHz, using a chromium patterned medium. In this study, we have investigated the accuracy of the tracking characteristics of an aperture-mounted head slider by using linearly arranged 1-mm-long line-and-space patterns. Based on the step or inverse step responses that occur when an aperture flies obliquely across the linearly arranged pattern region boundary, we present a simple method of predicting accurate tracking characteristics in detail, and also by using a 350-nm line-and-space pattern signal, we were able to predict both tracking characteristics and tracking sensitivities of arbitrary wide tracks to a track width of 100 nm.