Reforming of olive mill wastewater through a Pd-membrane reactor

This work investigates the exploitation of olive mill wastewater (OMW) for producing hydrogen in a membrane reformer.     

Mimosa-Inspired High-Sensitive and Multi-Responsive Starch Actuators

Artificial intelligent actuators are extensively explored for emerging applications such as soft robots, human-machine interfaces, and biomedical devices. However, intelligent actuating systems based on synthesized polymers suffer from challenges in renewability, sustainability, and safety, while natural polymer-based actuators show limited capabilities and performances due to the presence of abundant hydrogen-bond lockers. Here this study reports a new hydrogen bond-mediated strategy to develop mimosa-inspired starch actuators (SA). By harnessing the unique features of gelatinization and abundant hydrogen bonds, these SA enable high-sensitivity and multi-responsive actuation in various scenarios. The non-gelatinized SA can be irreversibly programmed into diverse shapes, such as artificial flowers, bowl shapes, and helix structures, using near-infrared light. Furthermore, the gelatinized SA exhibit reversibly multi-responsive actuation when exposed to low humidity (10.2%), low temperature (37 °C), or low-energy light (0.42 W cm⁻²). More importantly, the SA demonstrate robust applications in smart living, including artificial mimosa, intelligent lampshade, and morphing food. By overcoming the hydrogen-bond lockers inherent in natural polymers, SA open new avenues for next-generation recyclable materials and actuators, bringing them closer to practical applications.     

Comparison of shear strength tests on AV119 epoxy-joined ceramics

The results of an experimental investigation on epoxy-joined CVD SiC and alumina tested in shear and apparent shear mode by four different configurations are presented. Ceramics have been joined by an epoxy adhesive (AV119), which is not to be considered as the final joining material for high temperature applications, but just as a model brittle joining material chosen to obtain several joined samples in a reasonable time. Advantages and disadvantages of each configuration are discussed and compared to results obtained with the same epoxy-joined carbon/carbon composites, tested by the same shear tests.     

Mofete geothermal field

This report deals with the Mofete geothermal field, which was discovered in southern Italy by AGIP, the Italian state-owned company for exploration of oil, gas and other alternative energy resources, such as geothermal. AGIP is the main operator in the Mofete geothermal field, in joint venture with ENEL, the National Electricity Board. Seven wells have been drilled, and two producing aquifers found at depths between 500 and 2000 m. The preliminary interpretation of a long-term test (three months), together with the model of the field, suggest that a 10 MW power-plant will operate in the near future in the limited area considered favourable so far for geothermal production.     

Chip-level differential encoding/detection of spread-spectrumsignals for CDMA radio transmission over fading channels

This paper is concerned with the design and performance evaluation of a direct-sequence spread-spectrum transmission and signal-detection technique for application to code-division multiple-access mobile radio networks. Unlike the conventional differential encoding/detection of data symbols, such a technique envisages differential encoding/detection of the spreading code chips to counteract the fast time-selective fading encountered in mobile radio transmissions. Binary PSK modulation on a Rician frequency-flat-fading channel is assumed, with Gaussian and Rayleigh channels as particular cases. The bit-error rate performance of the receiver is analytically evaluated as a function of the relevant system parameters, and the impact on the receiver performance of a carrier frequency offset is also investigated     

Viable synthesis of a self-assembling regioregular thiophenic copolymer for second-order non-linear optics

Regioregular azobenzene-substituted polythiophenic copolymers were prepared by a regiospecific organometallic polycondensation procedure based on a Grignard metathesis reaction. Copolymers with a high content of chromophoric groups in the side chains and a high degree of configurational order of the backbones were obtained. A sample was also functionalized with hydroxyalkyl chains capable of setting up ordered supramolecular structures through hydrogen bonds. The final materials were fully characterized via NMR, IR, elemental analysis, GPC, DSC and X-ray diffraction. Moreover, measurements of NLO activity on polymer films showed the synthetic strategies adopted and monomers used to be correct. Values obtained by the in situ deprotection of the interacting functional groups after the alignment of the chromophorized side chains were very promising, proving the procedure to be suitable for industrial and commercial applications.     

Land Subsidence Spreading Factor of the Northern Adriatic Gas Fields, Italy

The land subsidence spreading factor χ provides a useful straightforward indication on how much of a gas/oil reservoir compaction induced by field development migrates to ground surface with a possible adverse impact on the stability of low‐lying coastal areas. This factor depends primarily on the ratio between the depth of burial and a representative horizontal dimension of the reservoir. However, an important influence is also exerted by the active bottom/lateral aquifer hydraulically connected to the field (called “waterdrive” in reservoir engineering) that may undergo an extensive depressurization also after the field abandonment, thus contributing to enhance the overall land settlement. In the Northern Adriatic basin, Italy, χ is evaluated using a nonlinear finite element model of three representative gas reservoirs (Chioggia Mare, Dorotea, and Dosso degli Angeli) surrounded by important bottom/lateral aquifers in the interval depth between 1000 and 3300 m. Results show that χ may easily approach and even exceed one for the deepest field as well, contrary to the prediction of land subsidence based on the compaction of the gas‐bearing formations alone, that can thus be largely underestimated.     

Capacitance DNA bio-chips improved by new probe immobilization strategies

Label-free DNA detection plays a crucial role in developing point-of-care biochips. Capacitance detection is a promising technology for label-free detection. However, data published in literature often show evident time drift, large standard deviation, scattered data points, and poor reproducibility. To address these problems, mercapto-hexanol or similar alkanethiols are usually considered as blocking agents. The aim of the present paper is to investigate new blocking agents to further improve DNA probe surfaces. Data from AFM, SPR, florescence microscopy, and capacitance measurements are used to investigate new lipoate and ethylene-glycol molecules. The new surfaces offer further improvements in terms of diminished detection errors. Film structures are investigated at the nano-scale to justify the detection improvements in terms of probe surface quality. This study demonstrates the superiority of lipoate and ethylene-glycol molecules as blocking candidates when immobilizing molecular probes onto spot surfaces in label-free DNA biochip.