The dissolution of iron under cathodic polarization

It has been shown that the dissolution rate for iron at cathodic potential is higher than expected on the grounds of the Wagner-Traud mixed potential theory. This observation cannot be explained by a parallel chemical process as suggested by Kolotyrkin et al. The dissolution appeared to be unaffected by potential, pH, cations (Li⁺, Na⁺, K⁺), anions (SO^2?₄, Cl^?, ClO^?₄) and solvent (water-dioxan mixtures). However, the dissolution rate was decreased by an order of magnitude when the electrode was connected to a strong magnet, suggesting that the mechanical degradation of the surface under the influence of the cathodically evolved hydrogen is the main cause of the measured effects.     

Quantum Surface of Section Method: Decomposition of the Resolvent (E - Ĥ)-1

The paper presents the exact surface of section reduction of quantum mechanics. The main theoretical result is a decomposition of the energy-dependent propagator (E) = (E - )-1 in terms of the propagators which (also or exclusively) act in Hilbert space of complex-valued functions over the configurational surface of section, which has one dimension less than the original configuration space. These energy-dependent quantum propagators from and/or onto the configurational surface of section can be explicitly constructed as the solutions of the first order nonlinear Riccati-like initial value problems.     

Finite volume analysis of laminated composite plates

A numerical procedure for analysis of general laminated plates under transverse load is developed utilizing the Mindlin plate theory, the finite volume discretization, and a segregated solution algorithm. The force and moment balance equations with the laminate constitutive relations are written in the form of a generic transport equation. In order to obtain discrete counterparts of the governing equations, the plate is subdivided into N control volumes by a Cartesian numerical mesh. As a result, five sets of N linear equations with N unknowns are obtained and solved using the conjugate gradient method with preconditioning. For the method validation, a number of test cases are designed to cover thick and thin laminated plates with aspect ratio (width to thickness) from 4 to 100. Simply supported orthotropic, symmetric cross‐ply, and angle‐ply laminated plates under uniform and sinusoidal pressure loads are solved, and results are compared with available analytical solutions. The shear correction factor of 5/6 is utilized throughout the procedure, which is consistent with test cases used in the reviewed literature. Comparisons of the finite volume method results for maximum deflections at the center of the plate and the Navier solutions obtained for aspect ratios 10, 20, and 100 shows a very good agreement. Copyright © 2016 John Wiley & Sons, Ltd.     

The Bologna reform’s impacts on the scientific publication performance of Ph.D. graduates—the case of Slovenia

Scientometrics - In this paper, the impact of the Bologna reform is analyzed based on differences in scientific publication performance among the Ph.D. graduates that enrolled into doctoral study...     

A novel aggregation method for Pythagorean fuzzy multiple attribute group decision making

As an extension of fuzzy set, a Pythagorean fuzzy set has recently been developed to model imprecise and ambiguous information in practical group decision‐making problems. The aim of this paper is to introduce a novel aggregation method for the Pythagorean fuzzy set and analyze possibilities for its application in solving multiple attribute decision‐making problems. More specifically, a new Pythagorean fuzzy aggregation operator called the Pythagorean fuzzy induced ordered weighted averaging‐weighted average (PFIOWAWA) operator is developed. This operator inherits main characteristics of both ordered weighted average operator and induced ordered weighted average to aggregate the Pythagorean fuzzy information. Some of main properties and particular cases of the PFIOWAWA operator are studied. A method based on the proposed operator for multiple attribute group decision making is developed. Finally, we present a numerical example of selection of research and development projects to illustrate applicability of the new approach in a multiple attribute group decision‐making problem.     

Simulation of liquid micro-jet in free expanding high-speed co-flowing gas streams

We present the development of an experimentally validated computational fluid dynamics model for liquid micro jets. Such jets are produced by focusing hydrodynamic momentum from a co-flowing sheath of gas on a liquid stream in a nozzle. The numerical model based on laminar two-phase, Newtonian, compressible Navier–Stokes equations is solved with finite volume method, where the phase interface is treated by the volume of fluid approach. A mixture model of the two-phase system is solved in axisymmetry using?~?300,000 finite volumes, while ensuring mesh independence with the finite volumes of the size 0.25 µm in the vicinity of the jet and drops. The numerical model is evaluated by comparing jet diameters and jet lengths obtained experimentally and from scaling analysis. They are not affected by the strong temperature and viscosity changes in the focusing gas while expanding at nozzle outlet. A range of gas and liquid-operating parameters is investigated numerically to understand their influence on the jet performance. The study is performed for gas and liquid Reynolds numbers in the range 17–1222 and 110–215, and Weber numbers in the range 3–320, respectively. A reasonably good agreement between experimental and scaling results is found for the range of operating parameters never tackled before. This study provides a basis for further computational designs as well as adjustments of the operating conditions for specific liquids and gases.     

Fabrication of buried microfluidic channels with observation windows using femtosecond laser photoablation and parylene-C coating

We developed an advanced method for fabricating microfluidic structures comprising channels and inputs/outputs buried within a silicon wafer based on single level lithography. We etched trenches into a silicon substrate, covered these trenches with parylene-C, and selectively opened their bottoms using femtosecond laser photoablation, forming channels and inputs/outputs by isotropic etching of silicon by xenon difluoride vapors. We subsequently sealed the channels with a second parylene-C layer. Unlike in previously published works, this entire process is conducted at ambient temperature to allow for integration with complementary metal oxide semiconductor devices for smart readout electronics. We also demonstrated a method of chip cryo-cleaving with parylene presence that allows for monitoring of the process development. We also created an observation window for in situ visualization inside the opaque silicon substrate by forming a hole in the parylene layer at the silicon backside and with local silicon removal by xenon difluoride vapor etching. We verified the microfluidic chip performance by forming a segmented flow of a fluorescein solution in an oil stream. This proposed technique provides opportunities for forming simple microfluidic systems with buried channels at ambient temperature.     

Design of Mobile Phones for Older Adults: An Empirical Analysis of Design Guidelines and Checklists for Feature Phones and Smartphones

Design guidelines and checklists are suggested as a useful tool in the development and evaluation of interface design of mobile phones for older adults. Given the intense evolution of mobile phone design, understanding how the design guidelines and checklists have taken into account the advances in mobile phone usability for older adults is important for their correct application and future development. Thus, this study explores the usability dimensions of mobile phone design for older adults and the related changes in terms of time and the type of device (feature phones vs. smartphones) based on an expert coding of the eight mobile phone design guidelines and checklists for older adults published between 2006 and 2014. The results of the expert coding show that design guidelines and checklists most frequently deal with visual and haptic issues (e.g., high contrast, button type, and button size), whilst they hardly ever address various elements of textual interface (e.g., ease of text entry, a button’s feedback, and font type). Over time, the design guidelines and checklists have become more complex in terms of the average number of included usability categories and dimensions. For smartphones, the guidelines, on average, put more emphasis on the screen, touchscreen, text, and exterior related issues, whereas the design guidelines for feature phones stress the usability of the keypad and menus. Besides revealing potential usability dimensions that could be further expanded in the guidelines, this study also highlights the need for research that would empirically validate the design guidelines and checklists in the future.     

Modeling of dynamic mechanical properties of vulcanized fluoroelastomer

The dynamic mechanical properties of a vulcanized fluoroelastomer (FKM) were studied over a range of temperatures and shear frequencies. Dynamic mechanical analysis and differential scanning calorimetry were used for the purpose of the study. A model was developed in order to describe FKM's viscoelastic behavior at various temperatures. The model was fitted to experimental data using an algorithm, which was developed for this purpose. As a result the FKM discrete relaxation spectrum at two reference temperatures was obtained, as well as the Williams‐Landel‐Ferry (WLF) equation parameters or the activation energy equivalent. Further on, the model was applied on storage modulus and loss tangent values obtained from the experiments, during which the temperature increased linearly. It was observed that the WLF equation fits well with the results during the glass transition, while the Arrhenius‐type relationship predicted too rapid decrease of the storage modulus during the glass transition. The master curves were constructed using the previously calculated WLF parameters and the activation energy equivalent. The developed model may be readily applied for the prediction of the numerous FKM compounds' frequency–temperature behavior using the dynamic mechanical properties obtained from either isothermal or low linear heating rate program measurements. POLYM. ENG. SCI., 47:2085–2094, 2007. © 2007 Society of Plastics Engineers