Fabrication of dense Ce0.9Mg0.1P2O7-PmOn composites by microwave heating for application as electrolyte in intermediate-temperature fuel cells

In the present work, we report a method of fabrication of dense 10 mol% Mg²⁺-doped cerium pyrophosphate-phosphate (Ce_0.9Mg_0.1P₂O₇-P_mO_n; CMP-P) composites by microwave heat-treatment of the preformed Ce_0.9Mg_0.1P₂O₇ substrates in the presence of phosphoric acid. The composite was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS). The microwave heating at 375 °C for 5 min resulted in the formation of dense CMP-P composites which retained most of the pyrophosphate phase. The electrical conductivity was extracted from the EIS data and for the CMP-P composite prepared by H₃PO₄ loading for 10 h and microwave heat-treatment for 5 min it was found to be >10^?2 S m^?1 in 100–250 °C range with a maximum of 0.062 S cm^?1 at 190 °C, which was significant for its application as electrolyte in intermediate temperature fuel cells.     

Development and analysis of a tool for speed up of EnergyPlus through parallelization

This paper describes how the EPparallel tool splits a single annual simulation into 12 simulations of one month each and runs them in parallel. The paper also describes the methodology to prepare input files, enable file sharing between nodes, collate results generated by the nodes, and ensure quality check on the simulations. The EPparallel tool uses Message Passing Interface library and runs on Linux. The tool has been tested on 16 commercial reference buildings over 16 US weather files. The results of these 256 runs which include the run times, computing time overheads, speed gains and accuracy of results are presented in this paper. The speed gain ranged from 2.9×to 7.8×and deviation (percentage of output values obtained in parallel simulation which were off by more than 1% as compared to output values obtained in annual simulation) ranged from 0% to 4%.     

Modelling and kinetic aspects of a BTEX contaminated air-treating biofilter

In this study, the overall performance of a biofilter was evaluated in terms of its elimination capacity by using 3-D mesh techniques. The overall results indicate that the agreement between experimental data and model predictions is excellent for benzene, toluene, ethylbenzene and o-xylene (BTEX). In this study, the maximum removal rate (r _max) values for BTEX were 0.0117, 0.0126, 0.0081 and 0.0146 g m^–3 h^–1, and the half-saturation constant (K_S ) values were calculated to be 0.269, 0.297, 0.156 and 0.394 g m^–3, respectively. For this system, the coefficients of determination (r ²) of BTEX compounds were greater than 0.97. The BTEX concentration profiles along the depth were also determined using a convection–diffusion reactor (CDR) model. The sums of squares of the errors (SSEs) of BTEX were 0.0078, 0.0059, 0.0129 and 0.0269, respectively, with r ² values greater than 0.99 for all four compounds at low concentrations.     

Strategies for the construction sector in the information technology era

The construction industries in many countries are starting to consider seriously the strategic use of information technology (IT). The use of information technology in construction is extending beyond the stage of piecemeal application for improving the efficiency of discrete operations by individual organizations to the advanced stage where IT is applied strategically in commercial enterprises, government agencies and professional institutions. Progress in construction in this regard appears to lag behind that in most other sectors of the economy. This paper considers the nature and the background of this progression in construction by examining proposals by Earl (1989) of nine basic prerequisites to the IT era which make a strategic approach timely. Each prerequisite is outlined and how it has been met in other sectors of the economy considered. The extent to which these prerequisites apply in construction and the scope for their application in the near future are examined. It is argued that all organizations involved in construction will ultimately have to think strategically about their use of IT, and how some are already doing so is described.

In discussing the factors which hinder the strategic application of IT in construction, the nature of the design and construction processes and initiatives that may be necessary to overcome the perceived problems are examined in detail. The strategies that are evolving at a national level in Singapore are outlined.     

Performance analysis of a solar photovoltaic operated domestic refrigerator

This paper describes the fabrication, experimentation and simulation stages of converting a 165 l domestic electric refrigerator to a solar powered one. A conventional domestic refrigerator was chosen for this purpose and was redesigned by adding battery bank, inverter and transformer, and powered by solar photovoltaic (SPV) panels. Various performance tests were carried out to study the performance of the system. The coefficient of performance (COP) was observed to decrease with time from morning to afternoon and a maximum COP of 2.102 was observed at 7 AM. Simulations regarding economic feasibility of the system for the climatic conditions of Jaipur city (India) were also carried out using RETScreen 4. It was observed that the system can only be economically viable with carbon trading option taken into account, and an initial subsidy or a reduction in the component costs – mainly SPV panels and battery bank.     

Vocal-tract modeling: fractional elongation of segment lengths in a waveguide model with half-sample delays

Digital waveguide models are commonly used for simulating vocal-tract acoustics based on physiological data. In particular, waveguide models with half-sample delays are known to be well suited for speech production research. This paper presents enhancements to such a model, aimed at improved accuracy in mapping physiological vocal-tract data (shape and length of the airway) to waveguide parameters. The enhancements allow the length of the vocal tract to be continuously varied, thus enabling more realistic synthesis. This is achieved by smoothly varying the individual segment lengths of a piecewise-cylindrical representation of the airway, without altering the system sampling frequency. Fractional-delay filters are used for spatial interpolation of the digital waveguide model. The algorithms are validated by modeling the protrusion of lips, lowering of larynx and lengthening of intermediate segments for a static vowel shape.     

A method for isolation of sequences missing in one of two related genomes

We describe a novel technique for isolation of sequences that are present in one genome (tracer), but absent in another (driver). Tracer DNA, cleaved with Sau 3A and capped with a single stranded PCR adapter, is allowed to hybridize with an excess of sheared biotinylated driver; biotinylated DNA and its hybrids with the tracer are removed by phenol/chloroform extraction after incubation with streptavidin. After several rounds of subtraction the ends of self-annealed tracer molecules from the nonextractable fraction are filled-in with Tag polymerase and amplified, using the single stranded PCR adapter as a primer. The method has been applied to purification of fragments from a 2.9 kb plasmid added to E. coli DNA at equimolar quantity. Plasmid derived fragments (250-1000 bp), initially comprising 1/1400th part of tracer DNA, were purified to homogeneity after two rounds of subtraction followed by PCR.     

Extended tuning range in sampled grating DBR lasers

The authors demonstrate, for the first time, successful implementation of a distributed Bragg reflector laser with two sampled grating mirrors, which they previously predicted should give tuning range in excess of 50 nm. This device uses a uniform grating pitch throughout the structure, and relies on the same fabrication technology as a standard DBR laser. Initial results show 57 nm of mathematical tuning at 1.475 μm with side-mode suppression ratio (SMSR)>30 dB over much of the tuning range. The observed change in operating wavelength versus mirror currents along with below threshold spectra agree with theoretical expectations