Electron-Affinity Substituent in 2,6-Dicarbonitrile Diphenyl-1λ5-Phosphinine Towards High-Quality Organic Lasing and Electroluminescence under High Current Injection

Rationally manipulating the functional substituents plays a crucial role in tuning the luminescence and lasing properties of organic gain media. Herein, a cyanophenyl-moiety, which exhibits relatively weaker electron affinity, is connected to 2,6-dicarbonitrile diphenyl-1λ⁵-phosphinine (DCNP) via para-linking. Resultantly, the appreciated locally-excited characteristics ensuring a large oscillator strength and high radiative rate can be reserved in DCNP-4-(4-cyanophenyl) (DCNP-pCN). Interestingly, the weak charge-transfer state from the relative donor (D)/acceptor (A) interplay enables small singlet-triplet splitting (ΔE_ST ≈ 0.45 eV). Thus the triplets generated on DCNP-pCN can be efficiently scavenged by 4,4'-bis[(N-carbazole)styryl]biphenyl (BSBCz), which is used as the host with a lower-lying triplet energy level for DCNP-pCN. Moreover, benefitting from the mediation between the conjugated length extension and weak D/A interplay, the emission spectrum cannot be largely shifted, which can effectively suppress the overlap between the lasing emission of DCNP-pCN and the excited-state absorption of BSBCz, thereby avoiding detrimental singlet-triplet annihilation. Thus, high-quality distributed feedback lasings with ≈2.0 μJ cm⁻² thresholds are achieved, and the organic light-emitting diodes exhibit external quantum efficiency exceeding 2.0% without efficiency rolloff under high current injection, indicating the potential for electrical-pumping organic lasings.     

Molar-Volume Dependence of the Pressure in hcp Solid 3He in Magnetic Fields

Pressure measurements have been made in a hcp solid ³ He at molar volumes from 18.90 to 19.45 cm ³ /mol, at temperatures down to 1 mK and in magnetic fields up to 0.16 Tesla. The results are analyzed by a high-temperature series expansion with multiple-exchange processes. The molar volume dependence of the multiple-exchange interactions has been determined by pressure measurements in magnetic fields. The results indicate that the exchange frequencies determined by the pressure measurements in a hcp solid ³ He are consistent with those obtained by magnetization measurements.     

Molecular modeling of single polypeptide chain of calcium-binding protein p26olf from dimeric S100B()

P26olf from olfactory tissue of frog, which may be involvedin olfactory transduction or adaptation, is a Ca²⁺-binding proteinwith 217 amino acids. The p26olf molecule contains two homologousparts consisting of the N-terminal half with amino acids 1–109and the C-terminal half with amino acids 110–217. Eachhalf resembles S100 protein with about 100 amino acids and containstwo helix–loop–helix Ca²⁺-binding structural motifsknown as EF-hands: a normal EF-hand at the C-terminus and apseudo EF-hand at the N-terminus. Multiple alignment of thetwo S100-like domains of p26olf with 18 S100 proteins indicatedthat the C-terminal putative EF-hand of each domain containsa four-residue insertion when compared with the typical EF-handmotifs in the S100 protein, while the N-terminal EF-hand ishomologous to its pseudo EF-hand. We constructed a three-dimensionalmodel of the p26olf molecule based on results of the multiplealignment and NMR structures of dimeric S100B(ßß)in the Ca²⁺-free state. The predicted structure of the p26olfsingle polypeptide chain satisfactorily adopts a folding patternremarkably similar to dimeric S100B(ßß). Each domainof p26olf consists of a unicornate-type four-helix bundle andthey interact with each other in an antiparallel manner formingan X-type four-helix bundle between the two domains. The twoS100-like domains of p26olf are linked by a loop with no sterichindrance, suggesting that this loop might play an importantrole in the function of p26olf. The circular dichroism spectraldata support the predicted structure of p26olf and indicatethat Ca²⁺-dependent conformational changes occur. Since theC-terminal putative EF-hand of each domain fully keeps the helix–loop–helixmotif having a longer Ca²⁺-binding loop, regardless of the four-residueinsertion, we propose that it is a new, novel EF-hand, althoughit is unclear whether this EF-hand binds Ca²⁺. P26olf is a newmember of the S100 protein family.     

Weighting matrix of quadratic performance index and design method of optimal deadbeat control system

A method of determination of the weighting matrix of the quadratic performance index and a method of design of an optimal deadbeat control system are discussed. First, the relationship between the weighting matrix of the quadratic performance index and the extra poles of the overparametrized pulse transfer function model is indicated. Next, a method of design of an optimal deadbeat control system is explained. Lastly, to demonstrate the effectiveness of the proposed method, some numerical examples are presented. © 2000 Scripta Technica, Electr Eng Jpn, 133(1): 53–63, 2000     

Measurement of electric intensity distribution inside human cadaver cochlea for multichannel cochlear implants

We have proposed a Tripolar Electrode Stimulation Method (TESM) which may succeed in narrowing the stimulation region and continuously moving the stimulation site for cochlear implants. The TESM stimulates the auditory nerve array through lymphatic fluid by means of three adjacent electrodes selected from among an electrode array. Currents are emitted from the electrodes on each side and the central electrode receives them. The current received by the latter electrode is equal to the sum of the currents emitted from the electrodes on the two sides. In this paper, the electric intensity profiles produced by the TESM and by monopolar stimulation were measured in a human cadaver cochlea and in a saline solution. We found that in the TESM, the electric intensity profile produced in the human cadaver cochlea was about the same as that in the saline solution. In addition, in the TESM, the electric intensity profile was much sharper than that of monopolar stimulation in the human cadaver cochlea. Furthermore, the nervous excitation region could be localized in a certain range by means of TESM. © 1999 Scripta Technica, Electr Eng Jpn, 129(1): 1–9, 1999     

Optimization of heat sink geometries for impingement air-cooling of LSI packages

This paper describes the use of our previous study's prediction procedures for calculating thermal resistance and pressure drop. The procedures are used in the optimization of heat sink geometries for impingement air-cooling of LSI packages. Two types of heat sinks are considered: ones with longitudinal fins and ones with pin fins. We optimized the heat sink geometries by evaluating 16 parameters simultaneously. The parameters included fin thickness, spacing, and height. For the longitudinal fins, the optimal fin thicknesses were found to be between 0.12 and 0.15 mm, depending on which of the four types of fans were used. For pin fins, the optimal pin diameters were between 0.39 and 0.40 mm. Under constant pumping power, the optimal thermal resistance of the longitudinal fins was about 60% that of the pin fins. For both types of heat sinks, the optimal thermal resistance for four off-the-shelf fans was only slightly (maximum about 1%) higher than the theoretical optimum for the same pumping power. When manufacturing cost performance is considered, the most economical fin thickness and diameter are about 5 to 10 times higher than the optimal values calculated without respect for manufacturing costs. These values almost correspond to the actual limits of extrusion and press heat-sink manufacturing processes. © 1999 Scripta Technica, Heat Trans Asian Res, 28(2): 138–151, 1999     

Computable urban economic model incorporated with economies of scale for urban agglomeration simulation

Urban agglomeration has attracted attentions of urban planners, economists, and policymakers. For the sake of urban agglomeration simulation, this paper attempts to develop a computable urban economic (CUE) model incorporated with economies of scale, through the approach of new economic geography. It is assumed that each firm produces a product variant in a monopolistic competition market, and the number of firms is explicit and determined endogenously. The Dixit–Stiglitz type utility function with product variety is adopted into the households’ behavior to reflect consumers’ preference for variety. On the other hand, internal increasing returns to scale and fixed cost are introduced in firms’ behavior to extend the model with economies of scale. The model’s parameter estimations and calibration are conducted on the basis of empirical data from several approved sources for Changzhou in 2008. Numerical computations are implemented by employing the extended CUE model incorporated with economies of scale to explain and examine how the urban agglomeration comes into being. Simulation results show that the extended model incorporated with economies of scale is able to commendably represent the urban agglomeration mechanism, providing a promising simulation tool for urban planning and policymaking.     

Stabilization of flavylium dye by incorporation into the pore of protonated zeolites

Flavylium dye, a model compound of natural anthocyanin, has a defect that its color stability is very poor. We have complexed the flavylium dye with protonated zeolites and succeeded to enhance both the thermal and chemical stability of the dye. The aqueous dispersion of the flavylium/zeolite complex maintains its color even at 353 K or at pH 9, under which conditions the aqueous solution of the flavylium loses its color immediately. The stability is enhanced when the dye is incorporated into the pore of the zeolites, and a large stabilization effect is obtained by a tight adsorption with a narrow pore, as long as the dye is incorporated into the pore. Because of its enhanced color stability, the flavylium dye incorporated in the zeolite pore can be a candidate for an environmentally friendly coloring material.     

Formulation of the rotational transformation of wave fields and their application to digital holography

Rotational transformation based on coordinate rotation in Fourier space is a useful technique for simulating wave field propagation between nonparallel planes. This technique is characterized by fast computation because the transformation only requires executing a fast Fourier transform twice and a single interpolation. It is proved that the formula of the rotational transformation mathematically satisfies the Helmholtz equation. Moreover, to verify the formulation and its usefulness in wave optics, it is also demonstrated that the transformation makes it possible to reconstruct an image on arbitrarily tilted planes from a wave field captured experimentally by using digital holography.