Prevention of liquid metal embrittlement cracks in resistance spot welds by adaption of electrode geometry

ABSTRACT

Advanced high strength steels are usually coated by a zinc layer for an increased resistance against corrosion. During the resistance spot welding of zinc coated steel grades, liquid metal embrittlement (LME) may occur. As a result, cracking inside and around the spot weld indentation is observable. The extent of LME cracks is influenced by a variety of different factors. In this study, the impact of the used electrode geometry is investigated over a stepwise varied weld time. A spot welding finite element simulation is used to analyse and explain the observed effects. Results show significant differences especially for highly increased weld times. Based on identical overall dimensions, electrode geometries with a larger working plane allow for longer weld times, while still preventing LME within the investigated material and maintaining accessibility.     

Development of high-throughput, polarization-maintaining, near-field probes

A novel, chemical-etching technique produces very high throughput, polarization-maintaining probes for near-field, scanning, optical microscopy (NSOM). The process includes coating the tips with aluminum and forming the apertures with a focused ion beam (FIB). The elliptical core fibers used resulted in elliptical apertures for the probes. The throughput of the probes depends on the incident polarization. For polarization parallel to the minor axis, the tip presents an insertion loss of only 20 dB for aperture widths of 55 nm. Probes have a typical polarization extinction of 100 to 1 in the far field. These tips produced NSOM images of gold dots on a GaAs substrate in reflection mode.     

The Self-Fulfilling Prophecy as an Intrafamily Dynamic.

This research examined whether parents' and children's perceptions of one another have reciprocal self-fulfilling effects on each other's behavior. Parents and their adolescent children completed self-report surveys and engaged in dyadic videotaped interaction tasks. The surveys assessed mothers', fathers', and children's perceptions of their own and the other's hostility and warmth. Observers coded the videotaped interactions to assess the actual hostility and warmth exhibited by parents and children. Data from 658 mother-child dyads were consistent with the conclusion that children had a self-fulfilling effect on their mothers' hostility but that mothers did not have a reciprocal self-fulfilling effect on their children's hostility. No other self-fulfilling prophecy effects emerged. Findings are discussed in terms of family relations and the differential power of negative versus positive self-fulfilling prophecies. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

利用氦流法真密度仪研究水泥水化过程

采用氦流法真密度仪测定了水泥水化过程中水泥浆体的绝对体积变化,并根据水泥浆体绝对体积变化曲线将水泥水化过程划分为极速收缩期、收缩暂停期、快速收缩期和收缩趋缓期4个阶段.结果表明:水泥浆体极速收缩期和快速收缩期发生的绝对体积变化最为明显,且变化幅度较大,其与C_3A和C_3S的水化密切相关;水泥浆体收缩暂停期的绝对体积通常呈线性规律缓慢减小,但变化幅度较小,其规律与"欠饱和度理论"相符;水泥浆体收缩趋缓期的绝对体积变化曲线通常会出现"膨胀"假象,不能反映水泥浆体绝对体积变化的实际情况,但与水泥浆体孔结构的发展有关,对水泥水化行为的表征仍具有重要的指导意义;水灰比不仅可以影响水泥水化过程,而且可以对水泥浆体各水化阶段的绝对体积变化产生明显影响.     

Harnstoffhydrolyse für die selektive katalytische Reduktion von NOx: Vergleich der Flüssig‐ und Gasphasenzersetzung

In order to reduce the NO_x concentration in car exhausts usually the selective catalytic reduction with ammonia is used. However, to avoid the transport of ammonia in vehicles urea is applied as NH₃ precursor. Controlled urea decomposition before the injection into the exhaust gas system itself may be accomplished by the use of a separate reactor. Urea decomposition to ammonia in the liquid phase under pressure in a heated reactor was compared to its decomposition in the gas phase. In the liquid phase, higher conversion rates relative to the reactor volume were realized than in the gas phase. Catalysts which showed high activity in the gas phase influenced the decomposition in the liquid phase only slightly.     

Specifying Real-Time Finite-State Systems in Linear Logic (Extended Abstract)

Abstract

Real-time finite-state systems may be specified in linear logic by means of linear implications between conjunctions of fixed finite length. In this setting, where time is treated as a dense linear ordering, safety properties may be expressed as certain provability problems. These provability problems are shown to be in pspace. They are solvable, with some guidance, by finite proof search in concurrent logic programming environments based on linear logic and acting as sort of model-checkers. One advantage of our approach is that either it provides unsafe runs or it actually establishes safety.     

Spectral Affine‐Kernel Embeddings

In this paper, we propose a controllable embedding method for high‐ and low‐dimensional geometry processing through sparse matrix eigenanalysis. Our approach is equally suitable to perform non‐linear dimensionality reduction on big data, or to offer non‐linear shape editing of 3D meshes and pointsets. At the core of our approach is the construction of a multi‐Laplacian quadratic form that is assembled from local operators whose kernels only contain locally‐affine functions. Minimizing this quadratic form provides an embedding that best preserves all relative coordinates of points within their local neighborhoods. We demonstrate the improvements that our approach brings over existing nonlinear dimensionality reduction methods on a number of datasets, and formulate the first eigen‐based as‐rigid‐as‐possible shape deformation technique by applying our affine‐kernel embedding approach to 3D data augmented with user‐imposed constraints on select vertices.     

Analysis of exempt paint solvents by gas chromatography using solid-phase microextraction

Acetone, methyl acetate, and parachlorobenzotrifluoride (PCBTF or Oxsol? 100) have been exempted as VOC solvents by the U.S. Environmental Protection Agency. In measuring coating VOC content, separate methods for determining exempt solvents are required. One such method utilizes solid-phase microextraction (SPME) to sample the headspace of solvent-based coatings to which the surrogates acetone-d6, methyl acetate-d3, and/or metachlorobenzotrifluoride have been added. The sampled exempt coating solvents are thermally desorbed and analyzed using gas chromatography with flame ionization or mass spectral detection. The SPME headspace method has also been used to analyze MEK, butyl acetate, tert-butyl acetate, toluene, and xylene in solventborne coatings, and alcohols in waterborne systems. This paper presents the results obtained for acetone and toluene in a large number of aerosol paints. Additionally, the results from a round-robin study for acetone, methyl acetate, and parachlorobenzotrifluoride in commercial solvent-based coatings are reported.