乙炔羰基化合成丙烯酸甲酯的研究

以乙炔、一氧化碳和甲醇为原料,卤化镍为主催化剂,羰基化合成丙烯酸甲酯,考察其在不同的反应温度、反应初始压力、原料配比、反应时间和催化剂用量下对反应结果的影响,确定最优的工艺条件。实验表明：以甲醇为溶剂,在185℃左右和5．2～5．5MPa的条件下,n（甲醇）：n（乙炔）：n（CO）=5．5～6．2：1：1,催化剂用量0．85wt％～0．9wt％,反应4～5h,丙烯酸甲醣的收率（相对乙炔）达到90％以上。     

Multivariate Analysis of Multiple Datasets: a Practical Guide for Chemical Ecology

Chemical ecology has strong links with metabolomics, the large-scale study of all metabolites detectable in a biological sample. Consequently, chemical ecologists are often challenged by the statistical analyses of such large datasets. This holds especially true when the purpose is to integrate multiple datasets to obtain a holistic view and a better understanding of a biological system under study. The present article provides a comprehensive resource to analyze such complex datasets using multivariate methods. It starts from the necessary pre-treatment of data including data transformations and distance calculations, to the application of both gold standard and novel multivariate methods for the integration of different omics data. We illustrate the process of analysis along with detailed results interpretations for six issues representative of the different types of biological questions encountered by chemical ecologists. We provide the necessary knowledge and tools with reproducible R codes and chemical-ecological datasets to practice and teach multivariate methods.     

Perpendicular to grain and shear mechanical properties of veneer-based elements glued from single veneer sheets recovered from three species of juvenile subtropical hardwood plantation logs

This paper quantifies the mechanical properties perpendicular to the grain and in shear of glued rotary peeled veneers, as would be encountered in veneer-based structural products (i.e. by including both the effects of hot pressing the veneers and the glue used during the manufacturing process), of three species recovered from juvenile (early to mid-rotation) subtropical hardwood plantation logs. This underutilised resource has currently little to no commercial value in Australia but proven potential to produce attractive veneer-based structural products. Determining these unknown properties is important as they constitute essential input data to ultimately predict the behaviour and design properties of veneer-based structural products in cost-effective numerical simulations. Two species planted for solid timber end-products (Gympie messmate—Eucalyptus cloeziana and spotted gum—Corymbia citriodora) and one species traditionally grown for pulpwood (southern blue gum—Eucalyptus globulus) are considered in the paper. The dynamic modulus of elasticity, compressive and tensile strengths perpendicular to the grain of veneer-based elements, each manufactured from single veneer sheets, were experimentally measured and are analysed herein. These properties are found to have no to weak correlation to the parent veneer sheet dynamic modulus of elasticity parallel to the grain, a value which is commonly measured in line to grade veneers. The shear modulus (in the longitudinal-tangential plane), also referred to as “modulus of rigidity”, through-the-thickness and rolling shear strengths were also experimentally measured, and the results are discussed in the paper. Little to no correlation to the veneer sheet dynamic modulus of elasticity parallel to the grain was found for these properties. Weibull distributions are fitted to all test results and presented to probabilistically consider the investigated properties in numerical simulations of veneer-based structural products.     

Effect of heating on the distribution of transforming growth factor-��2 in bovine milk

The objective of this study was to characterize the impact of heat treatments on the distribution of transforming growth factor-beta (TGF-??2) between cream and skim milk and between the casein and whey fractions of skim milk. Skimming removed 45% and 62% of the TGF-??2 from raw and pasteurized milks and only 8% of the total TGF-??2 in skimmed pasteurized milk was found in whey, compared to 37% in whey from raw skimmed milk. The TGF-??2 content of whey decreased as the heat treatment of the milk increased in intensity (thermization > pasteurization > UHT sterilization). Using milk held for 1 or 2 min at temperatures ranging from 57 to 84 °C, it was shown that TGF-??2 in the whey portion decreases at temperatures above 66 °C and becomes undetectable at temperatures higher than 76 °C. Altogether, these data on the heat-induced changes in TGF-??2 content of cream, skim milk, casein and whey reveal a potentially negative impact of certain heat treatments in developing TGF-??2-enriched fractions from milk.     

Pressure control in a PEM fuel cell via second order sliding mode

Pressure difference inside the Polymer Electrolyte Membrane Fuel Cells (PEMFC) arises due to load variations, during which the pressure difference between anode and cathode rises. Practically, this problem can be avoided by equalizing anode and cathode pressures, to protect the fuel cell from permanent damage. This paper focuses on pressure regulation in the anode and cathode sides of the PEMFC. The control objective is achieved using second order sliding mode multi-input multi-output (MIMO) controller based on “Twisting algorithm”. Parametric uncertainty is formally presented and included in a nonlinear dynamic fuel cell model. The resultant nonlinear controller is robust and is proved to guarantee performance around any equilibrium point and under parametric uncertainty. Simulation results show that the proposed controller has a good transient response under load variations.