The Inhibition Performance of trans-Cinnamaldehyde as a Green Compound for Mild Steel in Acidic 1 M HCl Medium: Correlation between Experimental and Theoretical Studies

Protection of Metals and Physical Chemistry of Surfaces - Corrosion inhibition propriety of (2E)-3-phenylprop-2-enal, known as trans-cinnamaldehyde (TCA) for mild steel in 1 M HCl medium was...     

A short communication on growing Jatropha in Oman

A stripping technique has been used to cencentrate selected hydrocarbons present in water samples at the parts per billion level for analysis by gas chromatography. The chromatograms of hydrocarbons thus stripped from several different water samples show similarities. Washing out of atmospheric pollutants by rainfall is postulated as an explanation of these results. This hypothesis is supported by a comparison of the data with those for trace atmospheric analysis. The comparison shows that the same compounds are present in similar relative amounts both in water samples and the atmosphere. After a period of rain the atmospheric concentrations decrease whilst the water bound concentrations increase.     

Water absorption,biodegradation, thermal and morphological properties of Spartium junceum fiber-reinforced polyvinylchloride composites: effects of fibers content and surface modification

In this study, we want to investigate the effects of fibers content and surface modification of Spartium junceum (SJ) fibers on the water absorption characteristics, thermal degradation, and morphological properties of SJ-reinforced poly (vinyl chloride) (PVC) composites. In addition, the change in mechanical proprieties of the composites after biodegradation test was evaluated by tensile strength. In order to improve the interfacial interactions between the PVC matrix and the SJ fibers, SJ fibers were modified by sodium hydroxide (NaOH), vinyltrimethoxysilane (VTMS) and treated with sodium hydroxide solution followed by VTMS (NaOH+VTMS). The results show that the water uptake of PVC/SJ fibers composites increases with the increase in the fibers’ content. However, the surface modification reduces water uptake. Moreover, the results indicate that the kinetics of water absorption of the PVC/SJ fibers composites approaches the Fickian diffusion mechanism. Also, the results indicate that the tensile strength of the composites is affected by the biodegradation test and chemical treatments. The atomic force microscope pictures of the composites illustrate the reduction of roughness via surface treatments of fibers.     

飞屋改造记 厄瓜多尔某住宅

<正>本住宅建于18世纪末,乍一看会让人觉得这是座一无是处的破房子。住宅仅有一层,砖地已经破败不堪,黑暗和寒冷充斥着整个房子,木质的屋顶结构也已经腐坏。只有土墙看上去还有翻新的可能,毕竟它们好像并没有那么糟糕。住宅的业主并不强调私密性:厨房、起居室、餐厅和卫生间都是公用的。这样设计的原因是业主经常在这里接待来访者和朋友。在这所房子里,私人空间被压缩成每位家庭成员的床位。     

LCZ696 Protects against Diabetic Cardiomyopathy-Induced Myocardial Inflammation,ER Stress,and Apoptosis through Inhibiting AGEs/NF-κB and PERK/CHOP Signaling Pathways

The present study is designed to determine the effect of LCZ696 on DCM in rats and investigate the underlying mechanism involved. Diabetes was induced by feeding rats with a high-fat diet for six weeks following a single injection of STZ (30 mg/kg). Diabetic rats were divided into three groups (n = 10). LCZ696 and valsartan treatment was started two weeks after diabetic induction and continued for eight weeks. At the end of the treatment, serum and cardiac tissues were analyzed by RT-PCR, Western blot, and ELISA kits. LCZ696 and valsartan ameliorated DCM progression by inhibiting AGEs formation at activity levels; pro-apoptotic markers (BAX/Bcl2 ratio and caspase-3) in mRNA and protein expressions, the NF-κB at mRNA; and protein levels associated with the restoration of elevated proinflammatory cytokines such as the TNF-α, IL-6, and IL-1β at the activity level. Furthermore, LCZ696 and valsartan contribute to restoring the induction of ER stress parameters (GRP78, PERK, eIF2a, ATF4, and CHOP) at mRNA and protein levels. LCZ696 and valsartan attenuated DCM by inhibiting the myocardial inflammation, ER stress, and apoptosis through AGEs/NF-κB and PERK/CHOP signaling cascades. Collectively, the present results reveal that LCZ696 had a more protective solid effect against DCM than valsartan.     

Solid Tumors and Kinase Inhibition: Management and Therapy Efficacy Evolution

The increasing numbers of cancer cases worldwide and the exceedingly high mortality rates of some tumor subtypes raise the question about if the current protocols for cancer management are effective and what has been done to improve upon oncologic patients’ prognoses. The traditional chemo-immunotherapy options for cancer treatment focus on the use of cytotoxic agents that are able to overcome neoplastic clones’ survival mechanisms and induce apoptosis, as well as on the ability to capacitate the host’s immune system to hinder the continuous growth of malignant cells. The need to avert the highly toxic profiles of conventional chemo-immunotherapy and to overcome the emerging cases of tumor multidrug resistance has fueled a growing interest in the field of precision medicine and targeted molecular therapies in the last couple of decades, although relatively new alternatives in oncologic practices, the increased specificity, and the positive clinical outcomes achieved through targeted molecular therapies have already consolidated them as promising prospects for the future of cancer management. In recent years, the development and application of targeted drugs as tyrosine kinase inhibitors have enabled cancer treatment to enter the era of specificity. In addition, the combined use of targeted therapy, immunotherapy, and traditional chemotherapy has innovated the standard treatment for many malignancies, bringing new light to patients with recurrent tumors. This article comprises a series of clinical trials that, in the past 5 years, utilized kinase inhibitors (KIs) as a monotherapy or in combination with other cytotoxic agents to treat patients afflicted with solid tumors. The results, with varying degrees of efficacy, are reported.     

Cloaking a receiving antenna or a sensor with plasmonic metamaterials

In this contribution, we discuss the possibility of applying the scattering-cancellation-based plasmonic cloaking technique to reduce the scattering from a sensing device, lowering its disturbance on sensing without affecting its ability to measure and “sense” the external world. The plasmonic cloak, while allowing the external fields to penetrate into the cover, may be able to suppress the scattering without necessarily shielding its interiors from the impinging light, which may be of great use if we wish to “sense” the external world, or receive an external signal, from inside the cloak. Our results may provide a unique sensing system that may receive and transmit signals, while its presence may not be perceived by the surrounding. This may be of great importance in a wide range of biological, optical, physical and engineering applications.     

Organic solvent pretreatment to enhance enzymic saccharification of straw

Enzymic saccharification of wheat straw in the absence of any pretreatment was only about 20 %. Acid hydrolysis did not improve the overall cellulose enzymic breakdown, nor did pretreatment by flash autohydrolysis under pressure or sodium chlorite delignification. When wheat straw was treated with N-methyl-morpholine-N-oxide (MMNO) at J20°C for 20–30 min, this treatment and subsequent enzymic hydrolysis produced carbohydrate conversion of 73%. Similar results could be obtained by treating straw with 0·1 M sodium hydroxide. When MMNO treatment was combined with any other pretreatment, the saccharification yield was greatly enhanced. Nearly quantitative conversion was obtained by swelling straw in 0·1 M sodium hydroxide followed by MMNO treatment. The results show that lignin content of plant material does not represent the limiting factor to enzymic saccharification.     

Composite right/left handed artificial transmission line structures in CMOS for controlled insertion phase at 30 GHz

Two CMOS integrated circuits are presented that utilize metamaterial composite right/left handed (CRLH) transmission lines (TLs) for zero insertion phase at 30 GHz. Specifically, 2 and 3 unit cell structures are presented with controlled insertion phase that is achieved by cascading lumped element capacitors and spiral inductors in an LC network configuration defining the TL unit cells. Furthermore, the fixed TL structures suggest the possibility of zero, advanced or delayed insertion phases by element variation, or by the use of simple active components. Simulation and measured results are in good agreement with CRLH TL theory, and display a linear insertion phase and flat group delay values that are dependent on the number of unit cells with an insertion loss of ～0.8 dB per cell. These findings suggest that such high speed CRLH TLs structures can be implemented for linear array feeding networks and compact antenna designs in CMOS at millimeter wave frequencies. © 2008 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2009.     

Investigation of charge transport mechanism in semiconducting La<Subscript>0.5</Subscript>Ca<Subscript>0.5</Subscript>Mn<Subscript>0.5</Subscript>Fe<Subscript>0.5</Subscript>O<Subscript>3</Subscript> manganite prepared by sol–gel method

Here in, we report the charge transport mechanism in semiconducting La_0.5Ca_0.5Mn_0.5Fe_0.5O₃ (LCMFO) polycrystalline material synthesized via sol–gel auto combustion route. X-ray diffraction (XRD) analysis confirmed the orthorhombic phase of the prepared material. Temperature dependent resistivity and impedance spectroscopy measurements have been carried out to probe the dielectric and electrical conduction mechanism which revealed a change of Mott variable range to the small polaronic hopping conduction mechanism around 303 K. The complex impedance and modulus spectra undoubtedly showed the contribution of both grain and grain boundary effect on the conduction properties of LCMFO. An equivalent circuit [(R_gbQ_gb) (R_gQ_g)] model has been used to address the electrical parameters associated with the different phases (grains and grain boundaries) having different relaxation times. The values of resistances of two phases obtained after fitting the equivalent circuit in the nyquist plot have been analyzed which confirmed the change of conduction mechanism around 303 K. The resultant change in conduction mechanism is also supported by the conductivity plots.