Development and Simulation of Sulfur‐doped Graphene Supported Platinum with Exemplary Stability and Activity Towards Oxygen Reduction

Sulfur‐doped graphene (SG) is prepared by a thermal shock/quench anneal process and investigated as a unique Pt nanoparticle support (Pt/SG) for the oxygen reduction reaction (ORR). Particularly, SG is found to induce highly favorable catalyst‐support interactions, resulting in excellent half‐cell based ORR activity of 139 mA mg_Pt ^?1 at 0.9 V vs RHE, significant improvements over commercial Pt/C (121 mA mg_Pt ^?1) and Pt‐graphene (Pt/G, 101 mA mg_Pt ^?1). Pt/SG also demonstrates unprecedented stability, maintaining 87% of its electrochemically active surface area following accelerated degradation testing. Furthermore, a majority of ORR activity is maintained, providing 108 mA mg_Pt ^?1, a remarkable 171% improvement over Pt/C (39.8 mA mg_Pt ^?1) and an 89% improvement over Pt/G (57.0 mA mg_Pt ^?1). Computational simulations highlight that the interactions between Pt and graphene are enhanced significantly by sulfur doping, leading to a tethering effect that can explain the outstanding electrochemical stability. Furthermore, sulfur dopants result in a downshift of the platinum d‐band center, explaining the excellent ORR activity and rendering SG as a new and highly promising class of catalyst supports for electrochemical energy technologies such as fuel cells.     

Multicast Network Security with Asymmetric Cooperative Relaying

International Journal of Wireless Information Networks - This paper exhibits the confidentiality performance study of a cooperative multicast network consisting of $${\mathcal {K}}$$ asymmetric...     

PbS and CdS Quantum Dot‐Sensitized Solid‐State Solar Cells: “Old Concepts,New Results”

Lead sulfide (PbS) and cadmium sulfide (CdS) quantum dots (QDs) are prepared over mesoporous TiO₂ films by a successive ionic layer adsorption and reaction (SILAR) process. These QDs are exploited as a sensitizer in solid‐state solar cells with 2,2′,7,7′‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD) as a hole conductor. High‐resolution transmission electron microscopy (TEM) images reveal that PbS QDs of around 3 nm in size are distributed homogeneously over the TiO₂ surface and are well separated from each other if prepared under common SILAR deposition conditions. The pore size of the TiO₂ films and the deposition medium are found to be very critical in determining the overall performance of the solid‐state QD cells. By incorporating promising inorganic QDs (PbS) and an organic hole conductor spiro‐OMeTAD into the solid‐state cells, it is possible to attain an efficiency of over 1% for PbS‐sensitized solid‐state cells after some optimizations. The optimized deposition cycle of the SILAR process for PbS QDs has also been confirmed by transient spectroscopic studies on the hole generation of spiro‐OMeTAD. In addition, it is established that the PbS QD layer plays a role in mediating the interfacial recombination between the spiro‐OMeTAD⁺ cation and the TiO₂ conduction band electron, and that the lifetime of these species can change by around 2 orders of magnitude by varying the number of SILAR cycles used. When a near infrared (NIR)‐absorbing zinc carboxyphthalocyanine dye (TT1) is added on top of the PbS‐sensitized electrode to obtain a panchromatic response, two signals from each component are observed, which results in an improved efficiency. In particular, when a CdS‐sensitized electrode is first prepared, and then co‐sensitized with a squarine dye (SQ1), the resulting color change is clearly an addition of each component and the overall efficiencies are also added in a more synergistic way than those in PbS/TT1‐modified cells because of favorable charge‐transfer energetics.     

A Distance Based Communication Mode Selection Mechanism for M2M Communications Over Cellular Networks

The implementation of machine-to-machine (M2M) communications in fifth-generation (5G) cellular networks can facilitate with several benefits like enhancement of bandwidth utilization, accommodating large number of users and decreasing traffic load on evolved node B (eNB). Integration of location information of unknown machine in communication mode selection mechanism is the key feature of this research. In this paper, a distance based communication mode selection mechanism using non-orthogonal resource sharing scheme is adopted in the proposed system model. Under the proposed mechanism, the expressions of throughput and RBs utilization policy are derived, which are the key parameters to evaluate the performance in the proposed network. Depending on the mode selection condition, such as threshold distance and threshold SINR between M2M users and regular cellular users, a UE can automatically choose its communication mode in the network. It is supposed that selection of mode before data transfer can improve the system performance. On the other hand, designing of efficient distance assisted proposed resource blocks (RBs) utilization policy reduces the traffic load on the eNB. Extensive simulations are carried out for evaluating the performance of the proposed mechanisms. The system performance is compared with various changeable parameters, such as throughput, mode selection threshold SINR, threshold distance and RBs. Besides, the proposed mechanism provides better network performance as well as reduces the traffic load in the proposed network.

     

Node to Node Performance Evaluation through RYU SDN Controller

In this paper a novel jamming technique is presented. The idea of the proposed jamming technique is based on adding inphase and quadrature impairments to the jamming signal. The jammer is simply a quadrature phase shift keying signal. The bit error rate probability (BER) of the proposed jamming signal is derived analytically and validated with the aid of the software defined radio SystemVue design software. The standard multi input multi output (MIMO) wireless local area network (WLAN) IEEE802.11n communication system is chosen as the victim system. Its BER performance is simulated in the presence of the proposed jamming signal in multipath fading channel. Finally, the efficiency of the proposed jamming signal on the MIMO WLAN IEEE802.11n communication system is practically measured in the laboratory where a practical experiment is held and the efficiency of the proposed jamming signal is compared with the traditional single tone jamming signal. It will be shown practically that the proposed jamming technique outperforms the traditional single tone jamming signal by nearly 15 dBm on the impact of efficiently jam the MIMO WLAN IEEE802.11n communication system.

     

Cross-layer selective routing for cost and delay minimization in IEEE 802.11ac wireless mesh network

Wireless Networks - A Wireless Internet-access Mesh NETwork (WIMNET) provides scalable and reliable internet access through the deployment of multiple access points (APs) and gateways (GWs). In...     

Delay‐insensitive identification of neighbors using unslotted and slotted protocols

For many applications, it is desirable for a node to be able to identify the neighbor nodes currently within range. However, the identification procedures for terrestrial communication networks (TCNs) are inefficient when implemented in long‐delay networks (LDNs) such as underwater acoustic networks or satellite networks, where the propagation time of a packet cannot be neglected. Here, we propose a time‐efficient and power‐efficient procedure, which is insensitive to propagation delay, for identifying neighbors in an LDN by optimizing the network offered load using either unslotted or slotted protocols. The procedure is adapted to the scenario when node cardinality and distribution are either known or unknown in advance. We achieve improvements as high as 80% in time and 45% in power consumption for our proposed approach compared with approaches developed previously for TCN. Furthermore, we analyze our proposed approach with the inclusion of the capture effect and packet receive time variations. We also provide a closed form formula for finding the optimum guard time and a procedure to estimate the packet receive time variations. Copyright © 2012 John Wiley & Sons, Ltd.     

Prioritized Medium Access Control in Cognitive Radio Ad Hoc Networks: Protocol and Analysis

Cognitive radio (CR) technology enables opportunistic exploration of unused licensed channels. By giving secondary users (SUs) the capability to utilize the licensed channels (LCs) when there are no primary users (PUs) present, the CR increases spectrum utilization and ameliorates the problem of spectrum shortage. However, the absence of a central controller in CR ad hoc network (CRAHN) introduces many challenges in the efficient selection of appropriate data and backup channels. Maintenance of the backup channels as well as managing the sudden appearance of PUs are critical issues for effective operation of CR. In this paper, a prioritized medium access control protocol for CRAHN, PCR-MAC, is developed which opportunistically selects the optimal data and backup channels from a list of available channels. We also design a scheme for reliable switching of a SU from the data channel to the backup channel and vice-versa. Thus, PCR-MAC increases network throughput and decreases SUs’ blocking rate. We also develop a Markov chain-based performance analysis model for the proposed PCR-MAC protocol. Our simulations, carried out in \(NS-3\) , show that the proposed PCR-MAC outperforms other state-of-the-art opportunistic medium access control protocols for CRAHNs.     

Chromophore-Free Sealing and Repair of Soft Tissues Using Mid-Infrared Light-Activated Biosealants

Poor strength, infection, leakage, long procedure times, and inflammation limit the efficacy of common tissue sealing devices in surgeries and trauma. Light-activated sealing is attractive for tissue sealing and repair, and can be facilitated by the generation of local heat following absorption of nonionizing laser energy by chromophores. Here, the inherent ability of biomaterials is exploited to absorb nonionizing, mid-infrared (midIR) light in order to engender rapid photothermal sealing and repair of soft tissue wounds. In this approach, the biomaterial simultaneously acts as a photothermal convertor as well as a biosealant, which dispenses the need for exogeneous light-absorbing nanoparticles or dyes. Biomechanical recovery, mathematical modeling, histopathology analyses, tissue strain mapping using digital imaging correlation, and visualization of the biosealant-tissue interface using hyperspectral imaging indicate superior performance of midIR sealing in live mice compared to conventional sutures and glue. The midIR-biosealant approach demonstrates rapid sealing of soft tissues, improves cosmesis, lowers potential for scarring, obviates safety concerns because of the nonionizing light used, and allows adoption of a wide diversity of biomaterials. Taken together, the studies demonstrate a novel advance both in biomaterials for surgical sealing along with the use of nonionizing midIR light, with high potential for clinical translation.