Organic–inorganic hybrid materials are of significant interest owing to their diverse applications ranging from photovoltaics and electronics to catalysis. Control over the organic and inorganic components offers flexibility through tuning their chemical and physical properties. Herein, it is reported that a new organic–inorganic hybrid, [Mn(C2H6OS)6]I4, with linear tetraiodide anions exhibit an ultralow thermal conductivity of 0.15 ± 0.01 W m?1 K?1 at room temperature, which is among the lowest values reported for organic–inorganic hybrid materials. Interestingly, the hybrid compound has a unique 0D structure, which extends into 3D supramolecular frameworks through nonclassical hydrogen bonding. Phonon band structure calculations reveal that low group velocities and localization of vibrational energy underlie the observed ultralow thermal conductivity, which could serve as a general principle to design novel thermal management materials. 相似文献
Wireless body area network (WBAN) has witnessed significant attentions in the healthcare domain using biomedical sensor-based monitoring of heterogeneous nature of vital signs of a patient’s body. The design of frequency band, MAC superframe structure, and slots allocation to the heterogeneous nature of the patient’s packets have become the challenging problems in WBAN due to the diverse QoS requirements. In this context, this paper proposes an Energy Efficient Traffic Prioritization for Medium Access Control (EETP-MAC) protocol, which provides sufficient slots with higher bandwidth and guard bands to avoid channels interference causing longer delay. Specifically, the design of EETP-MAC is broadly divided in to four folds. Firstly, patient data traffic prioritization is presented with broad categorization including Non-Constrained Data (NCD), Delay-Constrained Data (DCD), Reliability-Constrained Data (RCD) and Critical Data (CD). Secondly, a modified superframe structure design is proposed for effectively handling the traffic prioritization. Thirdly, threshold based slot allocation technique is developed to reduce contention by effectively quantifying criticality on patient data. Forth, an energy efficient frame design is presented focusing on beacon interval, superframe duration, and packet size and inactive period. Simulations are performed to comparatively evaluate the performance of the proposed EETP-MAC with the state-of-the-art MAC protocols. The comparative evaluation attests the benefit of EETP-MAC in terms of efficient slot allocation resulting in lower delay and energy consumption.
Miniaturization and energy consumption by computational systems remain major challenges to address. Optoelectronics based synaptic and light sensing provide an exciting platform for neuromorphic processing and vision applications offering several advantages. It is highly desirable to achieve single-element image sensors that allow reception of information and execution of in-memory computing processes while maintaining memory for much longer durations without the need for frequent electrical or optical rehearsals. In this work, ultra-thin (<3 nm) doped indium oxide (In2O3) layers are engineered to demonstrate a monolithic two-terminal ultraviolet (UV) sensing and processing system with long optical state retention operating at 50 mV. This endows features of several conductance states within the persistent photocurrent window that are harnessed to show learning capabilities and significantly reduce the number of rehearsals. The atomically thin sheets are implemented as a focal plane array (FPA) for UV spectrum based proof-of-concept vision system capable of pattern recognition and memorization required for imaging and detection applications. This integrated light sensing and memory system is deployed to illustrate capabilities for real-time, in-sensor memorization, and recognition tasks. This study provides an important template to engineer miniaturized and low operating voltage neuromorphic platforms across the light spectrum based on application demand. 相似文献
Internet of Things (IoT) refers to uniquely identifiable entities. Its vision is the world of connected objects. Due to its connected nature the data produced by IoT is being used for different purposes. Since IoT generates huge amount of data, we need some scalable storage to store and compute the data sensed from the sensors. To overcome this issue, we need the integration of cloud and IoT, so that the data might be stored and computed in a scalable environment. Harmonization of IoT in Cloud might be a novel solution in this regard. IoT devices will interact with each other using Constrained Application Protocol (CoAP). In this paper, we have implemented harmonizing IoT in Cloud. We have used CoAP to get things connected to each other through the Internet. For the implementation we have used two sensors, fire detector and the sensor attached with the door which is responsible for opening it. Thus our implementation will be storing and retrieving the sensed data from the cloud. We have also compared our implementation with different parameters. The comparison shows that our implementation significantly improves the performance compared to the existing system.
In orthogonal frequency division multiplexing (OFDM) system, high value of peak-to-average power ratio (PAPR) is an operational problem that may cause non-linear distortion resulting in high bit error rate. Selected mapping (SLM) is a well known technique that shows good PAPR reduction capability but inflicts added computational overhead. In this paper, using Riemann sequence based SLM method, we applied reverse searching technique to find out low PAPR yielding phase sequences with significant reduction in computational complexity. Additionally, we explored side-information free transmission that achieves higher throughput but sacrifices PAPR reduction. Finally, to overcome this loss in PAPR reduction, we proposed application of Square-rooting companding technique over the output OFDM transmitted signal. Simulation results show that the proposed method is able to compensate the sacrifice in PAPR and achieved PAPR reduction of 8.9 dB with very low computational overhead. 相似文献
Coarse wavelength division multiplexing (CWDM) network has proven to be promising lower cost network architecture for a significant cost advantage over dense wavelength division multiplexing due to the lower cost of lasers and the filters used in CWDM modules. A compatible amplifier module having bidirectional amplification capability was deployed for introducing inside stackable reconfigurable optical add/drop multiplexers in realizing large-scale CWDM networks. The amplifier module for use in the bidirectional IP transmission confirmed that the insertion losses of the nodes and the losses of the fibers connecting the nodes can be compensated effectively, allowing the network administrator to increase the number of nodes and fiber length of the network. However, the noise generated from the amplification due to amplified spontaneous emission must be considered in network design issues. In this paper, optical power penalties due to the bidirectional amplification were estimated by conducting experimentation on minimum detectable power of optical transceivers. After analyzing the power penalty issue, an IP-over-CWDM ring network was implemented and the performance of network was evaluated by monitoring the power and packet transmissions before and after the amplifier module was turned on. 相似文献
Recently, multipath routing in wireless sensor networks (WSN) has got immense research interest due to its capability of providing increased robustness, reliability, throughput, and security. However, a theoretical analysis on the energy consumption behavior of multipath routing has not yet been studied. In this paper, we present a general framework for analyzing the energy consumption overhead (i.e., energy tax) resulting from multipath routing protocol in WSN. The framework includes a baseline routing model, a network model, and two energy consumption schemes for sensor nodes, namely, periodic listening and selective wake-up schemes. It exploits the influence of node density, link failure rates, number of multiple paths, and transmission environment on the energy consumption. Scaling laws of energy-tax due to routing and data traffic are derived through analysis, which provide energy profiles of single-path and multipath routing and serve as a guideline for designing energy-efficient protocols for WSN. The crossover points of relative energy taxes, paid by single-path and multipath routing, reception, and transmission, are obtained. Finally, the scaling laws are validated and performance comparisons are depicted for a reference network via numerical results. 相似文献
High peak-to-average power ratio (PAPR) in orthogonal frequency division multiplexing (OFDM) systems seriously impacts power efficiency in radio frequency section due to the nonlinearity of high-power amplifiers. In this article, an improved gamma correction companding (IGCC) is proposed for PAPR reduction and investigated under multipath fading channels. It is shown that the proposed IGCC provides a significant PAPR reduction while improving power spectral levels and error performances when compared with the previous gamma correction companding. IGCC outperforms existing companding methods when a nonlinear solid-state power amplifier (SSPA) is considered. Additionally, with the introduction of \(\alpha , \beta , \gamma \), and \(\varDelta \) parameters, the improved companding can offer more flexibility in the PAPR reduction and therefore achieves a better trade-off among the PAPR gain, bit error rate (BER), and power spectral density (PSD) performance. Moreover, IGCC improves the BER and PSD performances by minimizing the nonlinear companding distortion. Further, IGCC improves signal-to-noise ratio (SNR) degradation (\(\varDelta _{\mathrm{SNR}}\)) and total degradation performances by 12.2 and 12.8 dB, respectively, considering an SSPA with input power back-off of 3.0 dB. Computer simulation reveals that the performances of IGCC are independent of the modulation schemes and works with arbitrary number of subcarriers (N), while it does not increase computational complexity when compared with the existing companding schemes used for PAPR reduction in OFDM systems. 相似文献