New Approach to Structure–Property Correlations of Different Films of Sorbitan Esters and Their Self-Assembly into Viscoelastic Monolayers

This publication is focused on the structural origin of viscoelasticity in Langmuir monolayers. To improve the understanding of the structural origin of viscoelasticity of surfactant films, we systematically studied interfacial films of different sorbitan esters with saturated (Span 60 and 65) and unsaturated (Span 80 and 85) paraffin chains by means of surface rheology, Langmuir isotherms, X-ray reflectometry (XRR), and Brewster angle microscopy (BAM). The results of two-dimensional shear rheological measurements revealed the existence of temporarily cross-linked networks. In dynamic BAM experiments, we observed a swinging motion of the monolayers as a result of a sudden externally initiated mechanical perturbation. The viscoelastic film response, which relaxed with time as the external force vanished, could be traced back to the presence of foam-like supramolecular structures that interlinked solid-condensed domains. The temperature dependence of the elastic response implied that the solid domains decomposed at temperatures close to the bulk melting point of Span 60 and Span 65. We concluded that insoluble surfactants formed solid domains at the interface, which were linked with each other by nonsolid areas, giving viscoelastic films. These newly discovered insights into coherent film formations could provide new opportunities for designing mechanically stable surfactant interfaces.     

Effect of variable friction coefficient on sheet metal drawing

A variable friction model that relates the parameters of sheet metal drawing to the local lubrication conditions taking place during the deformation, has been integrated to a finite element program. Variable friction coefficients for the contacting surfaces are determined from the friction model, which uses the related parameters obtained at each time step of the finite element program as inputs. A number of numerical runs have been performed and the strains are compared with the experimental results for circular blanks. A good agreement is obtained between the numerical and experimental results for the variable friction model used.     

Determining of heat balance design criteria for laying hen houses under continental climate conditions

This study focuses on the heat balance status of laying hen houses in regions with continental climate. The material consists of 45 laying hen houses from 27 commercial farms selected from the survey area where continental climate prevails. These laying hen houses differ from each other with respect to capacity, planning system and materials used in construction. First observations were conducted on the size and dimensions of laying hen houses as well as construction materials used, insulation, heat loss factors, ventilation capacity, ground space per hen and total size of laying hen house in order to assess the sufficiency of heat balance. Then, seven laying hen house models were developed. These models were developed by considering the present situation in operating laying hen houses, relevant literature, features of continental climate and suggestions made by firms manufacturing laying hen house construction materials in Turkey. These models give heat conduction coefficients that will prevent moisture concentration and ensure heat balance under continental climate conditions and suggest different sets of materials that can be used on walls and roofs. At the end of the study, under the condition of no moisture on surface of structural components and in areas where the indoor and outdoor temperatures are 25.3 °C and 20.2 °C, respectively, maximum total heat conduction coefficients are calculated to be between 1.38 and 1.73 Kcal/m² °C h. According to the features of area and housing, for providing heat balance, total heat conduction coefficients requirements are calculated to be between 0.62 and 2.08 Kcal/m² °C h for walls, 0.33 and 1.62 Kcal/m² °C h for roofs. In research area, minimum ventilation capacities are determined as 0.72 m³/h hen for carbon dioxide balance and, according to outdoor temperature, as 0.83–1.20 m³/h hen for water vapor balance. Heat loss factors are calculated to be between 0.10 and 0.15 Kcal/°C h hen. We believe that these suggestions will greatly facilitate the work of project engineers in the design of laying hen houses in regions and areas with continental climate.     

Computational investigation of testing parameter effects on abrasive wear behaviour of AL2O3 particle-reinforced MMCS using statistical analysis

The wear rate model of 7.3?vol.% Al₂O₃ particle-reinforced aluminium alloy composites with 16 and 66???m particle sizes fabricated by molten metal mixing method was developed in terms of applied load, particle size of reinforcement, abrasive grain size and sliding distance based on the Taguchi method. The two-body abrasive wear behaviour of the specimens was investigated using a pin-on-disc abrasion test apparatus where the sample slid against different SiC abrasives under the loads of 2 and 5?N at the room conditions. The orthogonal array, signal-to-noise ratio and analysis of variance were employed to find out the optimal testing parameters. The test results showed that particle size of reinforcement was found to be the most effective factor among the other control parameters on abrasive wear, followed by abrasive grain size. Moreover, the optimal combination of the testing parameters was determined and predicted. The predicted wear rate results were compared with experimental results and found to be quite reliable.