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991.
N. K. Kononov A. D. Belyaev S. M. Ignatov V. G. Nedorezov N. V. Rudnev A. A. Turinge 《Instruments and Experimental Techniques》2004,47(5):683-684
A digital position-sensitive X-ray imaging scintillation detector has been designed for the MEDIANA medical diagnostic station of the Kurchatov Synchrotron Radiation Center (the Kurchatov Institute). A single-crystal CsI(Tl) scintillator 8 mm thick is used as a screen with approximately 100% detection efficiency for X rays with energies as high as 100 keV. A CCD matrix of dimensions 1024 × 1024 pixels is the photodetector. The spatial resolution is five line pairs per mm in a field of vision of 35 × 35 mm for 100-keV X rays. 相似文献
992.
Junwei Fu Zhengbiao Zhang Zhenping Cheng Jian Zhu Wei Zhang Xiulin Zhu 《Polymer Bulletin》2008,61(3):287-297
A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA)
group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used
in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers.
The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE
as the RAFT agent. Number-average molecular weight (Mn,GPC) increased linearly
with monomer conversion, and molecular weight distributions were relatively narrow (PDI<
1.50). The results of chain-extension reaction, 1H NMR spectra and UV/Vis
spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine
(TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated. 相似文献
993.
M. C. ADAMS A. MATOV D. YARAR S. L. GUPTON G. DANUSER & C. M. WATERMAN-STORER 《Journal of microscopy》2004,216(2):138-152
Fluorescent speckle microscopy (FSM) uses low levels of fluorescent proteins to create fluorescent speckles on cytoskeletal polymers in high‐resolution fluorescence images of living cells. The dynamics of speckles over time encode subunit turnover and motion of the cytoskeletal polymers. We sought to improve on current FSM technology by first expanding it to study the dynamics of a non‐polymeric macromolecular assembly, using focal adhesions as a test case, and second, to exploit for FSM the high contrast afforded by total internal reflection fluorescence microscopy (TIR‐FM). Here, we first demonstrate that low levels of expression of a green fluorescent protein (GFP) conjugate of the focal adhesion protein, vinculin, results in clusters of fluorescent vinculin speckles on the ventral cell surface, which by immunofluorescence labelling of total vinculin correspond to sparse labelling of dense focal adhesion structures. This demonstrates that the FSM principle can be applied to study focal adhesions. We then use both GFP‐vinculin expression and microinjected fluorescently labelled purified actin to compare quantitatively the speckle signal in FSM images of focal adhesions and the actin cytoskeleton in living cells by TIR‐FM and wide‐field epifluorescence microscopy. We use quantitative FSM image analysis software to define two new parameters for analysing FSM signal features that we can extract automatically: speckle modulation and speckle detectability. Our analysis shows that TIR‐FSM affords major improvements in these parameters compared with wide‐field epifluorescence FSM. Finally, we find that use of a crippled eukaryotic expression promoter for driving low‐level GFP‐fusion protein expression is a useful tool for FSM imaging. When used in time‐lapse mode, TIR‐FSM of actin and GFP‐conjugated focal adhesion proteins will allow quantification of molecular dynamics within interesting macromolecular assemblies at the ventral surface of living cells. 相似文献
994.
The cellulose solvent dimethyl sulfoxide (DMSO)/tetrabutylammonium fluoride trihydrate (TBAF) was
successfully applied as reaction medium for the synthesis of allyl cellulose by conversion of the polymer
with allyl chloride in the presence of solid NaOH. Samples with degree of substitution from 0.50 to 2.98
were accessible by varying the molar ratio anhydroglucose unit:allyl chloride:NaOH and reaction time. DMSO/TBAF
was found to be an efficient reaction medium for the preparation of highly functionalized samples from spruce
sulfite pulp with degree of polymerization of about 500 even in a scale of 50 g. The allyl cellulose samples
were characterized by means of FTIR- and NMR spectroscopy. Size exclusion chromatography revealed negligible
polymer degradation during synthesis and purification of the samples. 相似文献
995.
Vanesa Rodríguez-Amor Juan P. Fernández-Blázquez Antonio Bello Ernesto Pérez María L. Cerrada 《Polymer Bulletin》2008,60(1):89-96
Summary The effect of molecular weight on the uniaxial orientation process has been analyzed in two samples of thermotropic poly(diethylene
glycol p,p′-bibenzoate), evaluating the influence of that parameter on the type of orientation obtained. Several strain rates and deformation
temperatures have been tested in order to map out the conditions for obtaining the two different kinds of orientation. The
results show that in the lower molecular weight PDEB sample (Mw=31200) it is rather easy to get exclusively perpendicular “anomalous” orientation, with the molecular axes aligned transversely
to the stretching direction. However, it is extremely difficult to obtain 100% parallel “normal” orientation. On the contrary,
either type of orientation or a mixture of them can be easily developed for the higher molecular weight PDEB sample (Mw=102900). 相似文献
996.
997.
Rolf G. Kuehni 《Color research and application》2008,33(1):5-9
Some 100 years before Albert Munsell developed his color order system, French silk merchant and inventor of a technology for producing works of art in silk velours, Gaspard Grégoire, introduced a color order system based on the color attributes hue, (relative) chroma, and lightness. Conceived in the mid‐1780s, an atlas with 1350 samples was produced before 1813 and found use in French Royal manufacturing operations and educational institutions. It was followed a few years later by one with 343 samples. Grégoire's work was subsequently overshadowed by Michel‐Eugene Chevreul's more complicated and less intuitive hemispherical system of 1839. © 2007 Wiley Periodicals, Inc. Col Res Appl, 33, 5–9, 2008 相似文献
998.
Qingzhao Yao Yuming Zhou Yanqing Sun Xiaoyun Ye 《Journal of Inorganic and Organometallic Polymers and Materials》2008,18(4):477-484
TiO2 hybrid molecular imprinted polymer (MIP) for ethofumesate using methacrylic acid (MAA) as the functional monomer and silane
coupling agent 3-(trimethoxysilyl) propylmethacrylate (KH570) as organic–inorganic connective bridge was synthesized via photo-excitation
method. Hydrogen bond was proved to act between MAA and ethofumesate for pre- and post-polymerization binding properties as
testified by UV spectrometric method. KH570 modified TiO2 nanoparticles were prepared via sonochemical reaction, which can accelerate hydrolysis, increase collision chance for the
reactive system and improve the dispersion of the nanoparticles. Scanning electron microscope (SEM), transmission electron
microscope (TEM), binding and the adsorption kinetics experiments as well as thermogravimetric analysis (TGA) were employed
for characterization. The results indicated that the hybrid MIP revealed a larger surface area and more ordered imprinting
cavities with improved thermal stability compared to organic-only MIP. Furthermore, faster adsorption kinetics and enhancive
adsorption capacity were achieved, which made it promising in chemical sensor applications. 相似文献
999.
Anastasiya Rybak Patrice A. Fokou Michael A. R. Meier 《European Journal of Lipid Science and Technology》2008,110(9):797-804
Olefin metathesis, awarded with the Nobel Prize in Chemistry 2005 for Chauvin, Grubbs and Schrock, has emerged as a powerful tool for organic as well as polymer chemistry. In oleochemistry, this reaction is well known and has been applied for many decades. Examples include the functionalization of the double bonds of different oleochemicals or the (direct) polymerization of plant oils via metathesis. More recent developments, particularly the development of better and more robust catalysts, allow for highly efficient cross‐metathesis reactions opening new possibilities for the direct introduction of chemical functionalities. Within this contribution, the development of metathesis in oleochemistry will be discussed, covering self‐metathesis as well as more recent developments in the field of cross‐metathesis that lead to desired platform chemicals. 相似文献
1000.
Muhammad Maqbool Hugh H. Richardson Martin E. Kordesch 《Journal of Materials Science》2007,42(14):5657-5660
Thin films of Praseodymium doped AlN are deposited on silicon (111) substrates at 77 K and 950 K by rf magnetron sputtering
method. About 500–1000 nm thick films are grown at 100–200 watts RF power and 5–8 mTorr nitrogen, using a metal target of
Al with Pr. X-rays diffraction results show that films deposited at 77 K are amorphous and those deposited at 950 K are crystalline.
Cathodoluminescence studies are performed at room temperature and luminescence peaks are observed in a wide range from ultraviolet
to infrared region. The most intense peak is obtained in green at 526 nm from amorphous films as a result from 3P1→3H5 transition. In crystalline films the intense peak was obtain in red at 648 nm as a result from 3P0→3F2 transition. Films are thermally activated at 1300 K for half an hour in a nitrogen atmosphere. Thermal activation enhances
the intensity of luminescence. Two peaks at 488 nm and 505 nm merged after thermal activation, giving rise to a single peak
at 495 nm. 相似文献