Near-infrared photodetection with a diruthenium complex having redox-switchable wavelength response

We report on the electrochromic behavior of a dinuclear ruthenium complex, which provides high environmental stability together with an intense absorption maximum at 1237 nm in solution in its +3 oxidation state. To verify its optoelectronic properties, we used this complex as the photoactive material in a planar photodetector prototype for near-infrared light pulses, succeeding in the detection of a train of light pulses at a wavelength of 1280 nm.     

Working memory capacity and the top-down control of visual search: Exploring the boundaries of "executive attention".

The executive attention theory of working memory capacity (WMC) proposes that measures of WMC broadly predict higher order cognitive abilities because they tap important and general attention capabilities (R. W. Engle & M. J. Kane, 2004). Previous research demonstrated WMC-related differences in attention tasks that required restraint of habitual responses or constraint of conscious focus. To further specify the executive attention construct, the present experiments sought boundary conditions of the WMC-attention relation. Three experiments correlated individual differences in WMC, as measured by complex span tasks, and executive control of visual search. In feature-absence search, conjunction search, and spatial configuration search, WMC was unrelated to search slopes, although they were large and reliably measured. Even in a search task designed to require the volitional movement of attention (J. M. Wolfe, G. A. Alvarez, & T. S. Horowitz, 2000), WMC was irrelevant to performance. Thus, WMC is not associated with all demanding or controlled attention processes, which poses problems for some general theories of WMC. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Review of The Robot's Rebellion: Finding Meaning in the Age of Darwin.

Review of book The Robot's Rebellion: Finding Meaning in the Age of Darwin by Keith E. Stanovich (see record 2004-95228-000). In his interesting scholarly book, The Robot's Rebellion, Stanovich leads us on a journey to find meaning in a world populated by mortal biological vehicles, the robots, put on earth to replicate their masters' selfish genes. If the genes do a satisfactory job programming the robots, then the genes replicate in perpetuity and are, therefore, immortal. Stanovich's basic assumptions are: a) vehicles are designed to replicate genes; b) at least in human animals, the brain houses two minds; c) the first mind, System 1 or The Autonomous Set of Systems, evolved much earlier in evolutionary history than did the second mind, System 2 or the Analytic System; d) System 1 is associative, parallel, fast to respond, and designed to automatically serve its genetic master; e) System 2 is rule-based, serial, slow to respond, not aware of System 1 functioning but sometimes privy to System 1 output, controls executive functioning, and is capable of self-evaluation and leading the rebellion against its genetic master; and, f) memes, culturally generated ideas passed on by nongenetic means, can sometimes be as effective as System 1 at squashing the rebellion. These assumptions are derived from work in cognitive science and evolutionary biology, and provide a solid foundation for the book. Both the metaphor and the basic assumptions are embedded in detailed and informative reviews of decision theory, evolutionary psychology, memetic theory, rational philosophy, and utility theory. The interweaving of metaphor and review provides a framework that allows Stanovich to make inferences to help the general reader understand "the implications of modern science" (p. xi). He also develops criteria to evaluate memes that are needed in his quest to find meaning in human existence. In combination with the basic assumptions, these criteria are used to create an ethical ideology that will be embraced by some readers. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Predicting change for individual psychotherapy clients on the basis of their nearest neighbors.

This study extended client-focused research by using the nearest neighbor (NN) approach, a client-specific sampling and prediction strategy derived from research on alpine avalanches. Psychotherapy clients (N = 203) seen in routine practice settings in the United Kingdom completed a battery of intake measures and then completed symptom intensity ratings before each session. Forecasts of each client's rate of change and session-by-session variability were computed on the basis of that client's NNs (n = 10-50 in different comparisons). Alternative forecasts used linear or log-linear slopes and were compared with an alternative prediction strategy. Results showed that the NN approach was superior to the alternative model in predicting rate of change, though the advantage was less clear for predicting variability. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Theoretical Correlations and Measured Correlations: Relating Recognition and Recall in Four Distributed Memory Models.

This article addresses the relation between item recognition and associative (cued) recall. Going beyond measures of performance on each task, the analysis focuses on the degree to which the contingency between successful recognition and successful recall of a studied item reflects the commonality of memory processes underlying the recognition and recall tasks. Specifically, 4 classes of distributed memory models are assessed for their ability to account for the relatively invariant correlation (≈ .5) between successive recognition and recall. Basic versions of each model either under- or overpredict the intertask correlation. Introducing variability in goodness-of-encoding and response criteria, as well as output encoding, enabled all 4 models to reproduce the moderate intertask correlation and the increase in correlation observed in 2 mixed-list experiments. This model-based analysis provides a general theoretical framework for interpreting contingencies between successive memory tests. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Two Modified Semicircle Control Charts for Detecting Process Improvement

A semicircle control chart can be used in detecting both increases and decreases in the mean and/or variance. In this paper, we propose two modified semicircle charts for detecting a reduction in the process variance, a.k.a. process improvement. Each of these modified semicircle charts, namely, SC1 and SC2 has two limits, defined by the inner and outer semicircles. A process improvement is detected by the SC1 scheme if a point is plotted inside the smallest semicircle, or if two successive points are plotted between the inner and outer semicircles and by the SC2 scheme if a point plots inside the smallest semicircle or if two of three successive points plot between the inner and outer semicircles. It will be shown that the two modified semicircle charts have superior average run length (ARL) performances to the basic semicircle chart in the detection of process improvement. The ARL study is conducted by means of a simulation.     

A comparative study of exchange and aggregation models in the B2B e-marketplace

This research seeks to provide an economic framework for understanding two major forms of e-marketplaces: aggregation-oriented vs. exchange-oriented e-marketplaces. By analyzing the marginal benefit per transaction in alternative models, we are able to determine the most suitable B2B e-marketplace for a wide variety of product categories, market conditions, and procurement methods. For example, when companies sell commodities in a fragmented market, the aggregation model is suitable for spot purchasing, and the exchange model works best for systematic purchasing. In addition, the effect of supplier consolidation and information technology-enabled cost reduction on model selection is discussed.     

Oxide dispersion strengthening of nickel electrodeposits for microsystem applications

Oxide dispersion strengthened nickel (ODS-Ni) electrodeposits were fabricated to net shape using the lithography, electroforming, and molding (LIGA) process in a nickel sulfamate bath containing a suspension of 10 nm diameter Al₂O₃ particulates. Mechanical properties were compared to baseline specimens fabricated using an identical sulfamate bath chemistry without the particulates. Results revealed that the as-deposited ODS-Ni exhibited significantly higher yield strength and ultimate tensile strength (∼50 pct) than the baseline material. This increase in as-deposited strength was attributed to Orowan strengthening. The ODS-Ni also showed improved retention of room-temperature strength after annealing over a range of temperatures up to 600 °C. Nanoindentation measurements revealed that the properties of the dispersion-strengthened deposit were uniform through its thickness, even in narrow, high aspect ratio structures. Microscopy revealed that this resistance to anneal softening was due to an inhibition of grain growth in the presence of the oxide dispersion. At elevated temperatures, the strength of the ODS-Ni was approximately 3 times greater than that of the baseline material although with a significant reduction in hot ductility.