Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible

A high-yielding fluorination of (triphos)Pt-R(+) has been achieved using an array of F(+) sources, with XeF(2) yielding R-F in minutes. The C-F coupling proved to be a stereoretentive process that proceeds via a concerted reductive elimination from a putative dicationic Pt(IV) center. The larger the steric congestion of the (triphos)Pt-C(sp3) (+) complexes, the more efficient the fluorination, seemingly a result of sterically accelerated C-F reductive elimination along with simultaneous deceleration of its competing processes (β-H elimination).     

Experimental investigations and numerical analysis for improving knowledge of incremental sheet forming process for sheet metal parts

The paper is related to the analysis of shape distortions and springback effects arising in single point incremental sheet forming in order to study the use of a FE model based on shell elements to perform simulation of the process. A comparison between numerical and experimental results is made to assess the suitability of the model. The measurements of geometrical profile of a truncated cone and springback of cut rings show that the FE model allows to predict accurate results for a set of well defined process parameters. The deformation mechanism of ISF is taken into consideration to determine the limits of the model studied.     

Relevance of the skewness index in DTI exploration of multiple sclerosis

Object  To this day, no parameter can really monitor the progression of multiple sclerosis (MS). In this study, an index the skewness (S) derived from parameters calculated in diffusion tensor imaging (DTI) has been tested on MS patients for its ability to monitor the disease course. Materials and methods  Eighteen patients underwent two examinations within 3 months consisting of a clinical evaluation (EDSS) and DTI acquisitions on a 1.5 T imager. Tensor was calculated thanks to“home-made” software. Mean diffusivity (MD) and fractional anisotropy (FA) histograms were described for normal-appearing white matter (NAWM) and gray matter (GM) of patients with S and also with usually indices peak position (pp) and peak height (ph) for the whole group of patients and for two separate groups according to their clinical status (EDSS  ≤  3 and EDSS  > 3 at month 0). Results  Although no significant clinical evolution is observed over 3 months, S in GM showed a significant shift for both MD/FA histograms towards abnormal values for the whole group of patients (p = 0.02/p = 0.04) and for the group with EDSS  ≤  3 (p = 0.04/p = 0.007), while ph and pp do not. Conclusion  S in GM could be an alternative marker to monitor the disease course before the repercussion on the clinical score.     

Indoor Ad Hoc Proximity-Location Sensing for Service Provider Selection

There are protocols that can be used by mobile clients to discover service providers in foreign networks to which they get attached, e.g., SDP of Bluetooth and SLP of IETF. These protocols do address service discovery, but do not address the selection of a service provider among a set of candidates according to a physical proximity of the client and service provider. The goal of the research described in this paper is to integrate proximity-based selection mechanisms to service discovery protocols. We present in this paper protocols that allow nomadic clients to discover and select service providers according to physical proximity.     

Low response time context awareness through extensible parameter adaptation with ORCA

Ubiquitous computing applications or widespread robots interactions execute in unforeseen environments and need to adapt to changeful available services, user needs, and variations of the environment. Context-awareness ability addresses such a need, enabling, through adaptation rules, applications to react to the perceived dynamic variations. Responses to adaptation have to be quick enough to maximize the time during which the application is coherent with its environment. Adaptation rules, associating variations of the environment to application reactions, are usually established at design time. However, in unforeseen and partially anticipated environments, we claim that adaptation rules have to be dynamically extensible to match previously unexpected variations. Our approach enables rule composition and ensures a deterministic result. We propose to use parameter adaptation to quickly respond to environmental variations and dynamic compositional adaptation to provide extensibility to the parameter adaptation. To foster even lower response times, we internalize context-awareness processing and decision into the application.     

Continuous and discrete data rebinning in time-of-flight PET

This paper investigates data compression methods for time-of-flight (TOF) positron emission tomography (PET), which rebin the 3-D TOF measurements into a set of 2-D TOF data for a stack of transaxial slices. The goal of this work is to develop rebinning algorithms that are more accurate than the TOF single-slice-rebinning (TOF-SSRB) method proposed by Mullani in 1982. Two approaches are explored. The first one is based on a partial differential equation, which expresses a consistency condition for TOF-PET data with a Gaussian TOF profile. From this equation we derive an analytical rebinning algorithm, which is unbiased in the limit of continuous sampling. The second approach is discrete: each 2-D rebinned data sample is calculated as a linear combination of the 3-D TOF samples in the same axial plane parallel to the axis of the scanner. The coefficients of the linear combination are precomputed by optimizing a cost function which enforces both accuracy and good variance reduction, models the TOF profile, the axial PSF of the LORs, and the specific sampling scheme of the scanner. Measurements of a thorax phantom on a prototype TOF-PET scanner with a resolution of 550 ps show that the proposed discrete method improves the bias-variance trade-off and is a promising alternative to TOF-SSRB when data compression is required to achieve clinically acceptable reconstruction time.     

Full CMOS continuous time filters for GSM applications

This paper describes full cmoscontinuous time filter design techniques which can meet the specifications commonly set for gsmapplications. First several cmosfilter design techniques are overviewed. The ota-ctechnique is discussed to some more detail. To overcome the main drawback of the lower total harmonic distortion in ota-ctechniques very linear operational transconductance amplifiers (ota)are required. Such an ota,together with the applied linearisation techniques is discussed. To fulfil high accuracy in cut- off frequencies of the filter an active tuning system is necessary. A new on- chip tuning system is presented. The paper concludes with a practical design example for the gsmsystem. Therein the different ota-ctechniques discussed are illustrated.     

Standards and industrial property

This article is primarily concerned with standards seen as a means for collective appropriation of technological information. It begins with an attempt to throw light on the relationships between standards, patents and licenses. Then we develop a two-stage duopolistic model whereby each firm must decide on a programme of standardization before choosing its level of production. The risks of multiple or inefficient equilibria are strong enough to justify the intervention of standardization organizations to inform and coordinate individual firms. But the paper also explains why some organizations likeetsi try to play a new role by promoting open access to master patents when used in the definition of a standard.     

Picosecond photodiffraction in semiconductor multiquantum wells and microcavities

We study the transient gratings photogenerated in the picosecond regime in three families of structures, namely : - structures of thickness in the order of one micron, including quantum wells (GaAs/GaAlAs, CdTe/ CdZnTe). A transmission modulation due to the electric field has been observed. We show that, in accordance with our calculations, this modulation is screened faster than 10 ps at a fluence of a few µJ/cm2. - A structure including GalnAs/GalnAsP MQWS in a cavity. This structure shows a top diffraction efficiency of 2.5 × 10-² at 1.55 µm for an energy of excitation in the order of 100 µJ/cm2. The diffraction efficiency exhibits several oscillations due to Fabry-Pårot effects. By introducing cavity effects in our model, we show that the diffraction efficiency is amplified by more than a factor 2 with respect to the no-cavity case. Calculations show that the diffraction efficiency may reach 6 × 10-² around 1.625 µm, for a front mirror reflectivity of 90 %. - Structures including bulk GaAs microcavities. The risetime is lower or in the order of 1 ps while the diffraction efficiency attains 1 %, with an average power of 4 mW (i.e. an energy of 2 µJ/cm²/pulse), compatible with a commutation of packets at 80 MHz.