Study of the preparation of ruthenia based catalytic materials by heating their precursors

Thermal behaviour of hydrous ruthenia (RuO₂·nH₂O) and ruthenia containing 10% titania ((RuO₂)_0.9–(TiO₂)_0.1nH₂O) was characterised on heating in air by emanation thermal analysis (ETA), thermogravimetry (TG), differential thermal analysis (DTA) and evolved gas analysis (EGA). The anhydrous ruthenia and ruthenia containing 10% titania samples were prepared by heating their hydrous precursors at 500°C in air. The temperature intervals of the samples dehydration and crystallisation were determined. XRD, TEM and surface area measurements were also used for the characterisation of the samples. The ETA results, evaluated by a mathematical model, brought about new information about surface area and microstructure development of the intermediate products of the oxides under in situ conditions of the heating in air. A good agreement between ETA and the results of other methods was obtained. The NO_x reduction by CO was used to test the catalytic properties of these samples.     

A study on the crystallization of amorphous arsenic

The results of DTA analysis of amorphous arsenic in combination with electron microscopical study of the samples through the whole temperature range reveal that no changes of the initial state of the sample occur on heating up to crystallization temperature. Close above this temperature the spontaneous crystallization starts. It differs markedly from the case of glassy materials, like As₂Te₃, in which case at temperatures as low as the transition region T_g the crystallization nuclei of geometrically defined shapes appear and grow into crystalline grains on further heating.     

Influence of opposite sex on attraction produced by pioneer sex of four bark beetle species cohabiting pine in the Southern United States

Catches ofDendroctonus frontalis andIps avulsus on traps surrounding bolts infested with both sexes of each species in the gallery were not significantly different from catches at bolts infested only with the sex which normally pioneers the host colonization process. In contrast, the presence of the second sex in the gallery significantly reduced catches ofI. grandicollis andI. calligraphus and, additionally, the presence of females in the male galleries ofI. calligraphus significantly reduced the catch ofI. avulsus females as compared with their response to bolts infested with the maleI. calligraphus only.     

Step-growth polymerization of guanamines with unsaturated aldehydes

Summary In acid medium and at temperatures from 50 to 100°C the resins from three different guanamines and three different unsaturated aldehydes were synthesized. The products were red coloured resins, which were soluble in organic solvents and were able to cure with hexamethylenetetramine to form hard and almost insoluble products. Using a combination of NMR and GPC methods it was possible to predict the course and the mechanism of the reactions. The rates of the reactions depend on the reaction conditions and on the type of the monomer.     

Model-Reference Fuzzy Adaptive Control as a Framework for Nonlinear System Control

The paper presents a general methodology of adaptive control based on fuzzy model to deal with unknown plants. The problem of parameter estimation is solved using a direct approach, i.e. the controller parameters are adapted without explicitly estimating plant parameters. Thus, very simple adaptive and control laws are obtained using Lyapunov stability criterion. The generality of the approach is substantiated by Stone-Weierstrass theorem, which indicates that any continuous function can be approximated by fuzzy basis function expansion. In the sense of adaptive control, this implies the adaptive law with fuzzified adaptive control parameters. The proposed control algorithm may be viewed as an extension of classical adaptive control for linear plants, but compared to the latter it provides higher adaptation ability and consequently better performance if the plant is nonlinear. The global stability of the control system is assured and the tracking error converges to the residual set that depends on fuzzification properties. The main advantage of the approach is simplicity that suits control engineers since wide range of industrial processes can be controlled by the proposed method. In the paper, the control of heat exchanger is performed.     

Theoretical and Empirical Analysis of ReliefF and RReliefF

Relief algorithms are general and successful attribute estimators. They are able to detect conditional dependencies between attributes and provide a unified view on the attribute estimation in regression and classification. In addition, their quality estimates have a natural interpretation. While they have commonly been viewed as feature subset selection methods that are applied in prepossessing step before a model is learned, they have actually been used successfully in a variety of settings, e.g., to select splits or to guide constructive induction in the building phase of decision or regression tree learning, as the attribute weighting method and also in the inductive logic programming.A broad spectrum of successful uses calls for especially careful investigation of various features Relief algorithms have. In this paper we theoretically and empirically investigate and discuss how and why they work, their theoretical and practical properties, their parameters, what kind of dependencies they detect, how do they scale up to large number of examples and features, how to sample data for them, how robust are they regarding the noise, how irrelevant and redundant attributes influence their output and how different metrics influences them.     

GPU-accelerated DXT and JPEG compression schemes for low-latency network transmissions of HD, 2K,and 4K video

Low-latency transmissions of high resolution video such as HD, 2K, or 4K over both Internet and private IP networks have found a foothold in many interactive applications, ranging from collaborative environments in science and medicine to the arts and entertainment industry. In this paper we demonstrate how the power of commodity graphics processing units can be used for efficient implementation of JPEG and DXT compression. We propose an approach to fine-grained parallelization of JPEG compression and the use of auxiliary indexes for efficient decompression, which are backward compatible with the JPEG standard. In-depth performance analysis is provided to show various aspects of the proposed parallelization including the dependency on image content and on various settings of the compression algorithm, as well as the impact of compression for interactive applications in terms of end-to-end latency. The applicability of these compression schemes in medicine and cinematography has also been evaluated using double-blind ABX tests compared with uncompressed video. We describe selected successful real-world deployment use cases based on our open-source implementation within the UltraGrid framework, such as trans-Atlantic 4K interactive video streaming during the CineGrid 2011 workshop. As discussed in the paper, the proposed approaches to parallelization provide sufficient performance even for the future generation of 8K video processing systems, currently limited by availability of camera and display hardware.