Phase Assemblages of Pr α-sialon Derived from SHS-ed Powders and TEM Study on the Nucleation of Pr α-sialon

The Pr α-sialon powders prepared by self-propagating high-temperature synthesis (SHS), consisting of 55 wt% Pr α-sialon and 45 wt% of β-sialon (abbreviated as α' and β'), were hot-pressed at 1800°C for 1 h. The results showed that Pr α' phase would transfer to β' with the appearance of JEM phase (Pr(Si_{6− z} Al _z )(N_{10− z} O _z )) after sintering, thus resulting in the increase of β' phase to 86 wt%. The addition of Y₂O₃ into SHS-ed Pr α' powders as the starting materials restrains the transformation of α' to β' and prevents the formation of JEM phase as well. The nucleation mechanism of Pr α' grain during hot-pressing was investigated in terms of transmission electron microscope and energy-dispersive spectrometer analysis. Two nucleation modes of Pr α' grains were found, i.e., nucleating on the undissolved Pr α' grains and on the nuclei of (Pr, Y) α' grains precipitated from liquid phase.     

Seeded Crystallization of Leucite

The leucite crystallization kinetics from a hydrothermally derived precursor seeded with nano-crystalline leucite was investigated by X-ray diffraction and non-isothermal differential thermal analysis. The nano-crystalline leucite was prepared by high-energy milling of high-purity leucite powder and the leucite precursor was prepared by the hydrothermal method of silica sol, aluminum nitrate, and potassium nitrate. After the seeds were introduced, the crystallization temperature of the precursor was lowered by 100°C and the transition phase kalsilite did not appear during the crystallization process. When the seeded precursor was heat treated at 700°C, a small amount of cubic leucite was stabilized to room temperature. The seeded precursor showed an exothermic peak between 800° and 920°C under different heating rates. The activation energy for the growth of leucite from the seeded precursor was 256(SD9) kJ/mol.     

对煤磨MDC89-7袋式除尘器的节能环保改造

0 前言 湖南韶峰水泥集团有限公司规格为φ2.5 m×3.9 m的风扫式煤磨配套的MDC89-7袋式除尘器于1993年投用,经十多年的生产应用,其导流板及风道损坏达80%左右;外壳、主风道因烧袋和腐蚀,严重变形且花板变得很薄;反吹风道变形穿孔,提升阀密封不严,导致清灰时风量流失严重,运行阻力增加,系统产量降低,且系统中含氧量增加,带来安全隐患;除尘效率下降、污染严重,粉尘排放浓度高达1 g/m3;系统能耗高,且维修强度大(每个滤袋重50kg,每次换袋需12人)且费用高.为此,该公司于2004年4月对该煤磨除尘器进行技术改造,取得了明显的效果.     

黄荆提取物对几种害虫的杀虫活性

研究了黄荆种子二氯甲烷提取物对5种害虫的杀虫活性以及对天敌异色瓢虫的安全性。结果表明：黄荆提取物对菜青虫、小菜蛾、麦长管蚜和桃蚜都有较高的杀虫活性，尤其是对菜青虫的活性最高，稀释100倍，处理4龄幼虫死亡率可达93．3％。但对大猿叶甲的杀虫活性则很低。黄荆提取物对异色瓢虫幼虫有一定的杀虫活性，但对其成虫无任何影响。本研究结果为开发利用这一新的杀虫植物资源提供了依据。     

降低循环流化床锅炉飞灰含碳量的因素分析

循环流化床锅炉的飞灰含碳量是锅炉燃烧工况好坏的直接反映 ,其对锅炉的热效率的影响是很大的 ,它还直接影响着粉煤灰的综合开发和利用 .在对云天化循环流化床锅炉的生产实验研究中 ,分析了影响循环流化床锅炉飞灰含碳量的各种因素 (床温、煤质煤粒、一次风、二次风、床压和旋风分离器效率等 ) ,通过实验研究找到了降低循环流化床锅炉飞灰含碳量的具体而又行之有效的操作方法 ,以指导实际生产 .     

浅论食品添加剂的安全性

介绍了食品添加剂的定义、分类和作用 ,分析了国内外食品添加剂的现状、发展前景及存在的问题 ,综述了食品添加剂的安全性问题及监督管理办法。     

Phase separation in polymer blends comprising copolymers: 6. Effect of molecular architecture of block copolymers

To study the effect of the molecular architecture of a copolymer on its miscibility with corresponding homopolymers a series of block copolymers of styrene and isoprene with diblock, triblock and four-arm star architectures have been prepared and the morphologies of the blends of the copolymers and polyisoprene with different molecular weights have been examined by electron microscopy. The results show that miscibility varies in the sequence diblock>triblock>four-arm star copolymers. This sequence is in the opposite direction to the variation of the architectural complexity of the block copolymers, i.e. the more complex is molecular architecture, the greater is conformation restriction in microdomain formation and the less is solubility of homopolymer in corresponding domains.