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21.
22.
Summary The synthesis and characterization of side-chain liquid crystalline polyoxetanes containing 4-dodecanyloxyphenyl trans-4-alkylcyclohexanoate side groups are presented. All the obtained monomers exhibit smectic B mesomorphism, while all the obtained polymers present smectic A, smectic B and smectic G mesophases. A longer terminal alkyl group is leading to the formation of a more stable mesophase. 相似文献
23.
Efficiency improvement of near-ultraviolet InGaN LEDs using patterned sapphire substrates 总被引:1,自引:0,他引:1
Woei-Kai Wang Dong-Sing Wuu Lin S.-H. Han P. Horng R.-H. Ta-Cheng Hsu Huo D.T.-C. Ming-Jiunn Jou Yuan-Hsin Yu Lin A. 《Quantum Electronics, IEEE Journal of》2005,41(11):1403-1409
The use of conventional and patterned sapphire substrates (PSSs) to fabricate InGaN-based near-ultraviolet (410 nm) light-emitting diodes (LEDs) was demonstrated. The PSS was prepared using a periodic hole pattern (diameter: 3 /spl mu/m; spacing: 3 /spl mu/m) on the (0001) sapphire with different etching depths. From transmission-electron-microscopy and etch-pit-density studies, the PSS with an optimum pattern depth (D/sub h/=1.5 /spl mu/m) was confirmed to be an efficient way to reduce the thread dislocations in the GaN microstructure. It was found that the output power increased from 8.6 to 10.4 mW, corresponding to about 29% increases in the external quantum efficiency. However, the internal quantum efficiency (@ 20 mA) was about 36% and 38% for the conventional and PSS LEDs, respectively. The achieved improvement of the output power is not only due to the improvement of the internal quantum efficiency upon decreasing the dislocation density, but also due to the enhancement of the extraction efficiency using the PSS. Finally, better long-time reliability of the PSS LED performance was observed. 相似文献
24.
Heng-Ming Hsu 《Electron Devices, IEEE Transactions on》2005,52(7):1410-1414
This paper proposes a structure for transformer with high-coupling, broadband, and small chip area characteristics using current silicon-based technology. The proposed device has tight coupling (k=0.92), wide bandwidth (f/sub SR/=30.8 GHz), and minimum chip area (OD=140 /spl mu/m). Furthermore, the analytical formula for calculating mutual inductance is derived in this study; experimental results indicate that the analytical formula is feasible. The proposed transformer will be useful in designing high-performance RF integrated circuits for wireless applications. 相似文献
25.
26.
Hsu‐Wei Fang Hsien‐Chieh Wang Teh‐Hua Tsai Wei‐Bor Tsai Shao‐Yi Hou Hsuan‐Liang Liu Wun‐Hsing Lee Yung‐Chang Lu Chun‐Hsiung Huang 《应用聚合物科学杂志》2008,108(4):2428-2437
Wear of ultrahigh‐molecular‐weight polyethylene (UHMWPE) and wear‐particle‐induced osteolysis and bone resorption are the major factors causing the failure of total joint replacements. It is feasible to improve the lubrication and reduce the wear of artificial joints. We need further understanding of the lubrication mechanism of the synovial fluid. The objective of this study is to evaluate the lubricating ability of three major components in the synovial fluid: albumin, globulin, and phospholipids. An accelerated wear testing procedure in which UHMWPE is rubbed against a microfabricated surface with controlled asperities has been developed to evaluate the lubrication behavior. An analysis of the wear particle dimensions and wear amount of the tests has provided insights for comparing their lubrication performance. It is concluded that the presence of biomolecules at the articulating interface may reduce friction. A higher concentration of a biological lubricant leads to a decrease in the wear particle width. In addition, in combination with the wear results and mechanical analysis, the roles of individual biomolecules contributing to friction and wear at the articulating interface are discussed. These results can help us to identify the role of the biomolecules in the boundary lubrication of artificial joints, and further development of lubricating additives for artificial joints may be feasible. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
27.
Using chloroform/dimethylformamide (CF/DMF) co-solvent, electrospinning of poly[(R)-3-hydroxybutyrate] (PHB) solutions was carried out at ambient temperature. The effects of the applied voltage (V), flow-rate (Q), and solution viscoelastic properties on the Taylor cone, electrified jet, and fiber morphology were investigated. In addition, the electric field developed by the needle-plate electrode configuration was calculated using a finite element analysis to reveal the tip-to-collector (H) effect. Among the processing parameters (V, Q and H), it was found that Q played a key role in determining the jet diameter (dj) and electrospun fiber diameter (df), and scaling laws existed between them, i.e., dj-Q0.61 and df-Q0.33. The diameter reduction ratios of Do/dj (Do is the needle diameter) and dj/df were measured as 50-120 and 5-10, respectively; it suggested that major jet stretching took place in the straight electrified jet region, and further chain orientation could be gained by the subsequent process of jet whipping. By changing PHB concentrations from 5 to 15 wt%, the solution viscosity (ηo) was increased from 100 to 4900 cP, whereas the surface tension and solution conductivity remained unchanged; it provided a good model solution to exclusively reveal the ηo effect on the electrospinning process. Our results showed that the ηo-dependence of dj and df also followed simple scaling laws: dj-ηo0.06, and df-ηo0.39, with a prefactor depending on the processing variables, mainly the flow-rate. Regardless of the PHB concentrations used, the obtained PHB fibers showed a similar crystallinity fraction of ca. 0.63 and possession of major α-crystals together with a small amount of β-crystals with zigzag chain conformation. 相似文献
28.
Chia-Chiang Hsu Chein-Hsiun Tu 《Journal of the Chinese Institute of Chemical Engineers》2008,39(3):265-273
Vapor–liquid equilibrium (VLE) at 101.3 kPa have been determined for a ternary system (tetrahydofuran + 2-propanol + 2,2,4-trimethylpentane) and its constituent binary systems (tetrahydrofuran + 2-propanol, tetrahydrofuran + 2,2,4-trimethylpentane, and 2-propanol + 2,2,4-trimethylpentane). The activity coefficients of liquid mixtures were calculated from the modified Raoult's law. Thermodynamic consistency tests were performed for all VLE data. The VLE data of the binary mixtures and ternary mixtures were correlated using the Margules, Wilson, NRTL, and UNIQUAC activity-coefficient models. The models with their best-fitted interaction parameters of the binary systems were used to predict the ternary vapor–liquid equilibrium. All VLE data are also used to calculate the reduced excess molar Gibbs free energy gE/RT and the deviations in the boiling point ΔT. The calculated quantities of gE/RT and ΔT were fitted to variable-degree polynomials in terms of liquid composition. 相似文献
29.
Tsun-Lai Hsu Jeng Gong Keh-Yuh Yu 《Electron Devices, IEEE Transactions on》1995,42(10):1868-1871
A simple model for the analysis of the ac stress effect in poly-emitter bipolar transistors is presented. Apart from the reverse-bias induced hot-carrier effects, the forward-bias recovery effect is a key factor under ac stress, it obviously suppresses the base current degradation of the device which is caused during the reverse-bias periods. In this work, we derived the relationship between the excess base current and the stress time for different ac stress conditions. This model is verified with experimental results.<> 相似文献
30.
Healy (1) and Dempster et al. (8) proposed statistical methods to evaluate the treatment effects in animal reproductive toxicology research. Both methods assume homogeneous variance for the dams and the pups, respectively, in all the treatment groups. In this paper, via mixed effect modeling, we propose a method to estimate the treatment effects allowing heterogeneous variances for the dams and the pups, respectively, in different treatment groups. Covariates will also be included in the model. A procedure to test the fixed effects is also discussed. An example from an animal reproductive toxicological study is used to illustrate the procedures. 相似文献