上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.     

立管系统中严重段塞流的一维瞬态模型

严重段塞流主要出现在下倾管段、紧接有一上倾管段或立管段的气、液两相混输海底管道中。根据严重段塞流形成的4个阶段,从一维瞬态流体力学方程出发,建立了一个简化的、准平衡态的严重段塞流数学模型,该模型考虑了流体的物性及流动瞬态效应,可对严重段塞长度、段塞周期、流动速度、压力等特性参数的变化进行模拟。与其他瞬态多相流模型相比,本文模型具有数学模型简单、计算效率高的特点。数值模拟结果表明:当管径较小时,无论介质是空气和水,还是空气和油,由本文模型计算得到的段塞周期和压力结果都与实验数据吻合较好;当管径较大时,若介质为空气和水,则本文模型计算结果与OLGA软件模拟结果较接近;若介质为石油和天然气,在模拟工况范围内,除了小气量工况下偏差较大外,本文模型计算结果与OLGA软件模拟结果相比,段塞周期偏差在25%以内,压力偏差在10%以内;此外,用本文模型计算液塞生长阶段时间t1比Saga-tun模型模拟结果更接近实测结果。     

Preparation and Characterization of Zeolite Beta with Low SiO_2/Al_2O_3 Ratio

Zeolite beta with a low SiO2/Al2O3 ratio was synthesized by a novel two-step process.The synthesized sample was characterized with XRD,SEM,FTIR,and N2 adsorption-desorption and solid-state MAS NMR.The results showed that aluminium species were inserted into the framework of zeolite beta.The BET surface area,volume,and particle size of the zeolite beta sample decreased with decreasing SiO2/Al2O3 ratio.Our process was proved an efficient route to synthesize zeolite beta with a low SiO2/Al2O3 ratio.     

运用高压旋喷建造土坝坝基灌浆盖板技术

地坝坝基进行帷幕灌浆时，由于坝基无混凝土盖板，不能进行裂隙冲洗，灌浆压力受到限制，因而灌浆效果有限。采用高压旋喷在坝基建造灌浆盖板，改善了灌浆条件，取得了良好的灌浆效果，并且有效地截断坝基表层的渗漏，减少了坝基的接触冲刷破坏，温缺口水库大坝灌浆试验的成功为坝基无混凝土盖板条件下灌浆和坝基防渗加固处理探索了一条新路子。     

共轭高分子三阶非线性光学材料

概述了ｎ－共轭高分子材料的三阶非线性光学性质，着重讨论了化学结构对其光学非线性的影响，说明了ｎ－共轭聚合物的三阶非线性极化率主要取决于共轭主链的结构，侧链取代基的变化对其非线性影响不大，文中展望了共轭高分子材料在集成光学中的应用前景。     

Monolithic Catalysts with Low Noble-Metal Content for Exhaust Purification of Small Gasoline Engines

A series of low noble-metal coment monolithic catalysts for exhaust purification of small gasoline engines was investigated, and it was found that the Pt/Rh-OSM/Al2O3 （where OSM was oxygen storage material） catalyst with Ce0.5Zr0.5-MnOx（3%MnOx） OSM held low light-off temperature for CO, HC, and NO; quite wide three-way window, and outstanding thermal stability. The catalyst could efficiently comrol exhaust emission of small gasoline engines.     

Neural networks modeling signal responses and taxol production of cultured Taxus chinensis cells induced by bio-elicitor

Quantitatively describing the signal transduction process is important for understanding the mechanism of signal regulation in cells, and thus, poses both a challenge and an opportunity for chemical and biochemical engineers. An artificial neural network (ANN), in which we took the signal molecules as neural nodes, was constructed to simulate the generation of active oxygen species (AOS) in Taxus chinensis cells induced by a bio-elicitor. The relative contents of AOS in cells predicted by the ANN model agreed well with the experimental data and three notable stages of AOS increase were observed from the 3D figure of AOS generation. The robustness of AOS trajectories indicated that signal regulation in vivo was an integral feedback control model that ensured the adaptation of Taxus chinensis to environmental stress. The artificial neural network was able to predict taxol production as well as determine the optimal concentration of oligosaccharides needed for it.     

破碎岩体内灌浆抬动破坏的成因分析

文章根据破碎岩体内的工程实践,针对在破碎岩体内灌浆极易出现的"抬动破坏"问题,分析了"抬动破坏"的成因及其与之相关的地质环境和对工程的影响,总结了相应的处理原则和工程措施。     

State observability and condition observability for a class of interacting discrete event systems

This paper introduces the concepts of state observability and condition observability for condition systems, a class of systems composed of discrete state components which interact via discrete binary signals called conditions. Given a set of externally observed conditions, state observability implies that the state of the system can be determined from the observations, and condition observability implies that all unobserved input and output conditions of the system can be determined from the observations. In this paper, we present a class of systems which is state observable and condition observable. We present a method to synthesize an observer system to provide state and condition signal estimates for a single component subsystem.     

Holmium-doped Porous Silicon Prepared by a New Electrochemical Approach and Its Photoluminescence

Ｐｏｒｏｕｓｓｉｌｉｃｏｎ（ＰＳ）ｗａｓｆｏｕｎｄｔｏｅｍｉｔｖｉｓｉｂｌｅｌｕｍｉｎｅｓｃｅｎｃｅａｔｒｏｏｍｔｅｍｐｅｒａｔｕｒｅｂｙＣａｎｈａｍｉｎ１９９０［１］．Ｔｈｉｓｐｈｅｎｏｍｅｎｏｎｉｍｐｌｉｅｄａｐｏｔｅｎｔｉａｌａｐｐｌｉｃａｔｉ...