Bildungsmechanismen im Primärschlackegebiet des Hochofens

Neues Verfahren zur Herstellung von großen Wüstitkristallen. Erörterung der Reaktionen zwischen Wüstit und Kalk-Kieselsäure-Gemischen. Deutung des Bildungsmechanismus im Primärschlackegebiet durch Erläuterung des Aufbaus hohler Körper aus reduzierten Eisenoxiden in Eiszapfenformen.     

Oxidation of silicon carbide in a wet atmosphere

The effects of water vapour on oxidation of pressureless-sintered silicon carbide containing alumina as a densifying aid were studied in a wet air flow with 10, 20, 30 and 40vol% H₂O at 1300° C for 100h. The oxidation kinetics were determined in a wet air flow with 20 vol % H₂O and in a dry air flow at 1300° C for times up to 360 h. The weight gain on oxidation showed an increasing tendency with increasing water vapour content. Water vapour in the atmosphere strongly influenced oxidation and accelerated the reaction. Oxidation in a wet atmosphere proceeded in a diffusion-controlled manner, in the same process as that for the dry atmosphere. No remarkable differences were noticed in the microstructure of the oxide layer and the surface roughness between the samples oxidized under the four wet conditions, but the surface roughness increased with increasing oxidation time. Water vapour evidently accelerated the devitrification of amorphous silica and promoted oxidation. Oxidation in a wet atmosphere (10 to 40 vol % H₂O for 100 h and 20 vol % H₂O up to 360 h) had a slight degrading effect on the flexural strength. The microstructure or surface roughness of the oxide layer formed during oxidation presumably had very little effect on the room-temperature strength.     

Effect of Fictive Temperature on Dynamic Fatigue Behavior of Silica and Soda-Lime Glasses

The dynamic fatigue characteristics of silica glasses with fictive temperatures of 1000°, 1100°, and 1300°C and soda-lime glasses with fictive temperatures of 470° and 530°C were measured in air. For both glasses, samples with higher fictive temperatures had a greater fatigue resistance. Inert strength of silica glasses with flctive temperatures of 1000° and 1300°C was also measured at liquid nitrogen temperature. Glass with higher flctive temperature had a greater inert strength.     

Filler reinforcement in electron beam-cured hard paint films

Filler effect on the dynamic mechanical properties of electron beam (EB)-cured hard paint films has been studied. Introducing TiO₂ particles resulted in modulus reinforcement. However, degree of reinforcement was lower compared with that for conventional thermosetting polymers. Although the degree of reinforcement for thermosetting polymers was reported to be greater when the filler-polymer interaction was stronger, the storage moduli of the present composites containing TiO₂ with different surface treatments showed no significant difference. Temperature dependence of the relative modulus and reduced damping can be explained by the particle agglomeration theory. The relative modulus showed no increase and the reduced damping showed no decrease by increasing temperature, respectively. This indicates that the present polymer is hard enough to exert large forces on the agglomerates to destroy them. It is also noted that stress relaxation around a particle will not be involved in increasing temperature, as the cross-linking was carried out at room temperature. Lower filler reinforcement compared with thermosetting polymers can be partly attributed to the particle agglomeration theory.     

Algorithms for Extracting Correct Critical Points and Constructing Topological Graphs from Discrete Geographical Elevation Data

Researchers in the fields of computer graphics and geographical information systems (GISs) have extensively studied the methods of extracting terrain features such as peaks, pits, passes, ridges, and ravines from discrete elevation data. The existing techniques, however, do not guarantee the topological integrity of the extracted features because of their heuristic operations, which results in spurious features. Furthermore, there have been no algorithms for constructing topological graphs such as the surface network and the Reeb graph from the extracted peaks, pits, and passes. This paper presents new algorithms for extracting features and constructing the topological graphs using the features. Our algorithms enable us to extract correct terrain features; i.e., our method extracts the critical points that satisfy the Euler formula, which represents the topological invariant of smooth surfaces. This paper also provides an algorithm that converts the surface network to the Reeb graph for representing contour changes with respect to the height. The discrete elevation data used in this paper is a set of sample points on a terrain surface. Examples are presented to show that the algorithms also appeal to our visual cognition.     

Factors influencing the equilibrium grain size in equal-channel angular pressing: Role of Mg additions to aluminum

Experiments were undertaken to compare the equal-channel angular (ECA) pressing of Al-1 pct Mg and Al-3 pct Mg solid-solution alloys with pure Al. The results reveal both similarities and differences between these three materials. Bands of subgrains are formed in all three materials in a single passage through the die, and these subgrains subsequently evolve, on further pressings through the die, into an array of grains with high-angle boundaries. However, the addition of magnesium to an aluminum matrix decreases the rate of recovery and this leads, with an increasing Mg content, both to an increase in the number of pressings required to establish a homogeneous microstructure and to a decrease in the ultimate equiaxed equilibrium grain size. It is concluded that alloys exhibiting low rates of recovery should be especially attractive candidate materials for establishing ultrafine structures through grain refinement using the ECA pressing technique.     

Theoretical considerations on the sensitivities of electron beam resists

A theoretical study has been carried out in order to explain the sensitivities of electron beam and X-ray resists. A preliminary investigation reveals that the behavior of these resists, on irradiation by high energy radiation, may be considered to be the electronically-excited species in the polymer. To elucidate the chemical reactions in the excited states the adiabatic potential curves are calculated by the INDO/S procedure, which considers all the valence electrons and all the singly excited electronic configurations. Polyethylene and polyisobutylene were chosen as representative of crosslinkable and degradable polymers, respectively, since there is a parallelism between the beam sensitivity of resists and the effects of high energy radiation on polymers. Polyisobutylene has many antibonding curves favorable for the main chain scission in the excited states and polyethylene does not except for one improbable state. It was concluded that degradability is explainable by the ease of bond fission in the excited states; the crosslinkability is considered to be nondegradable property.     

Bayesian calibration of embankment safety under earthquake loading

This study provides a probabilistic procedure for the back-calculation of factors of safety of embankment slopes during seismic loading. The slope stability is analyzed by the conventional circular arc slip surface method in which the seismic load is introduced in terms of a horizontal body force. The factor of safety of an embankment is inversely estimated using information whether the embankment is still safe or not after the occurrence of an earthquake. In this back-calculation, soil strengths and seismic loads are treated as random variables. This is because, in many actual situations, these two factors are usually uncertain even after the occurrence of an earthquake.The developed procedure is applied to the case records of embankment behavior during the Niigata earthquake of 1964. Six embankments are analyzed. Four of them are damaged embankments while the others are non-damaged. The factors of safety are inversely estimated and they are compared with the state of damage described in the case records.