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排序方式: 共有84条查询结果,搜索用时 15 毫秒
1.
Bianca Stoean Dumitrita Rugina Monica Focsan Ana-Maria Craciun MÎdÎlina Nistor Tamas Lovasz Alexandru Turza Ioan-Dan Porumb Emese Gl Castelia Cristea Luminita Silaghi-Dumitrescu Simion Astilean Luiza Ioana Gaina 《International journal of molecular sciences》2021,22(6)
We report here the synthesis and structural characterization of novel cationic (phenothiazinyl)vinyl-pyridinium (PVP) dyes, together with optical (absorption/emission) properties and their potential applicability as fluorescent labels. Convective heating, ultrasound irradiation and mechanochemical synthesis were considered as alternative synthetic methodologies proficient for overcoming drawbacks such as long reaction time, nonsatisfactory yields or solvent requirements in the synthesis of novel dye (E)-1-(3-chloropropyl)-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium bromide 3d and its N-alkyl-2-methylpyridinium precursor 1c. The trans geometry of the newly synthesized (E)-4-(2-(7-bromo-10-ethyl-10H-phenothiazin-3-yl)vinyl)-1-methylpyridin-1-ium iodide 3b and (E)-1-methyl-4-(2-(10-methyl-10H-phenothiazin-3-yl)vinyl)pyridin-1-ium tetrafluoroborate 3a′ was confirmed by single crystal X-ray diffraction. A negative solvatochromism of the dyes in polar solvents was highlighted by UV-Vis spectroscopy and explanatory insights were supported by molecular modeling which suggested a better stabilization of the lowest unoccupied molecular orbitals (LUMO). The photostability of the dye 3b was investigated by irradiation at 365 nm in different solvents, while the steady-state and time-resolved fluorescence properties of dye 3b and 3a′ in solid state were evaluated under one-photon excitation at 485 nm. The in vitro cytotoxicity of the new PVP dyes on B16-F10 melanoma cells was evaluated by WST-1 assay, while their intracellular localization was assessed by epi-fluorescence conventional microscopy imaging as well as one- and two-photon excited confocal fluorescence lifetime imaging microscopy (FLIM). PVP dyes displayed low cytotoxicity, good internalization inside melanoma cells and intense fluorescence emission inside the B16-F10 murine melanoma cells, making them suitable staining agents for imaging applications. 相似文献
2.
Borràs J Casanova J Cristea T Gheorghe A Scozzafava A Supuran CT Tudor V 《Metal-Based Drugs》1996,3(3):143-148
Ternary Ni(II) complexes of hydrazine and eight heterocyclic sulfonamides possessing carbonic anhydrase (CA) inhibitory properties, were prepared and characterized by elemental analysis, spectroscopic, magnetic, thermogravimetric, and conductimetric measurements. The complexes behave as strong inhibitors for two isozymes (I and II) of carbonic anhydrase. 相似文献
3.
G. Cristea 《Computers & Structures》1997,63(6):1101-1111
The paper describes a method for estimating the degree of confidence (d. o. c.) of the nonlinear dynamic response. The structural parameters, the dynamic load and the structural response are modelled by fuzzy variables. Their degree of confidence is represented by the membership functions. The structure response, including its degree of confidence, is computed by fuzzy operations taking into account the degree of confidence of the parameters and dynamic load. The influence of the mass, damping coefficient, stiffness and dynamic load upon the response degree of confidence is analysed by the parameters variation. A C++ functions library was developed for fuzzy operations. The fuzzy variables are defined as objects belonging to the class FUZZY. The arithmetical and relational operators are overloaded for fuzzy operations. Conclusions are derived concerning the method for estimating the degree of confidence of the structural response. A method for the quality control of the computed response is proposed. 相似文献
4.
5.
A new diol with azoaromatic pendant was prepared by N-phenyl-4-amido-3,4-dichloromaleimide with 2-mercaptoethanol in the presence of NaOH, and used to obtain photosensible poly(urethane-urea)
varnish. A poly(urethane-urea) varnish bearing azobenzene chromophores, based on a poly(ethylene adipate)diol (average molecular
weight—2000), 4,4′-dibenzyldiisocyanate, diethylene glycol, trimethylolpropane, and afore-mentioned diol, were prepared and
characterized. The polymers were characterized by FTIR spectroscopy, thermal analysis (DMA, DSC, and TGA), and the photochromic
behavior by UV irradiation of thin films was discussed. 相似文献
6.
Co-Drive on-board traffic information system is a complementary tool providing a dynamic management of transportation infrastructure and traffic as well as the diffusion of accurate real-time information about the road environment and motorists’ driving behaviour. The aim of this study was to examine drivers’ acceptability of Co-Drive by investigating the impact of traffic information provided via on-board display devices on motorists’ beliefs and behaviour. 相似文献
7.
Structure–property relationship of sodium deoxycholate based poly(ester ether)urethane ionomers for biomedical applications 下载免费PDF全文
Daniela Filip Doina Macocinschi Stelian Vlad Gabriela Lisa Mariana Cristea Mirela F. Zaltariov 《应用聚合物科学杂志》2016,133(4)
New sodium deoxycholate based poly(ester ether)urethane ionomers were prepared for the development of biomedical materials. A structure–property relationship in the tested biomaterials was established by cross‐examination of the dynamic mechanical and dielectric properties, attenuated total reflection–Fourier transform infrared investigation, thermogravimetric analysis, and surface morphology characterization. A stronger ionic interaction and solvation capacity of the ions and a higher ionic conductivity were manifested in the case of poly(ethylene oxide)‐rich segments than for poly(propylene oxide)‐rich segments in these polyurethane ionomers. The molecular and ionic interactions of the bile‐salt moiety with different polyether cosoft segments influenced chain packing and conformation, supramolecular organization, and the resulting surface morphological microstructures of the polyurethane biomembranes. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42921. 相似文献
8.
Luiza G?in? Castelia Cristea Claudia Moldovan Dan Porumb Emanoil Surducan C?lin Deleanu Abdalah Mahamoud Jacques Barbe Ioan A. Silberg 《International journal of molecular sciences》2007,8(2):70-80
Application of a dynamic microwave power system in the chemical synthesis of some phenothiazine and quinoline derivatives is described. Heterocyclic ring formation, aromatic nucleophilic substitution and heterocyclic aldehydes/ketones condensation reactions were performed on solid support, or under solvent free reaction conditions. The microwave-assisted Duff formylation of phenothiazine was achieved. Comparison of microwave-assisted synthesis with the conventional synthetic methods demonstrates advantages related to shorter reaction times and in some cases better reaction yields. 相似文献
9.