Function Follows Form: Correlation between the Growth and Local Emission of Perovskite Structures and the Performance of Solar Cells

Understanding the relationship between the growth and local emission of hybrid perovskite structures and the performance of the devices based on them demands attention. This study investigates the local structural and emission features of CH₃NH₃PbI₃, CH₃NH₃PbBr₃, and CH(NH₂)₂PbBr₃ perovskite films deposited under different yet optimized conditions using X‐ray scattering and cathodoluminescence spectroscopy, respectively. X‐ray scattering shows that a CH₃NH₃PbI₃ film involving spin coating of CH₃NH₃I instead of dipping is composed of perovskite structures exhibiting a preferred orientation with [202] direction perpendicular to the surface plane. The device based on the CH₃NH₃PbI₃ film composed of oriented crystals yields a relatively higher photovoltage. In the case of CH₃NH₃PbBr₃, while the crystallinity decreases when the HBr solution is used in a single‐step method, the photovoltage enhancement from 1.1 to 1.46 V seems largely stemming from the morphological improvements, i.e., a better connection between the crystallites due to a higher nucleation density. Furthermore, a high photovoltage of 1.47 V obtained from CH(NH₂)₂PbBr₃ devices could be attributed to the formation of perovskite films displaying uniform cathodoluminescence emission. The comparative analysis of the local structural, morphological, and emission characteristics of the different perovskite films supports the higher photovoltage yielded by the relatively better performing devices.     

Optical I/O Technology for Tera-Scale Computing

This paper describes both a near term and a long term optical interconnect solution, the first based on a packaging architecture and the second based on a monolithic photonic CMOS architecture. The packaging-based optical I/O architecture implemented with 90 nm CMOS transceiver circuits, 1 × 12 VCSEL/detector arrays and polymer waveguides achieves 10 Gb/s/channel at 11 pJ/b. A simple TX pre-emphasis technique enables a potential 18 Gb/s at 9.6 pJ/b link efficiency. Analysis predicts this architecture to reach less than 1 pJ/b at the 16 nm CMOS technology node. A photonic CMOS process enables higher bandwidth and lower energy-per-bit for chip-to-chip optical I/O through integration of electro-optical polymer based modulators, silicon nitride waveguides and polycrystalline germanium (Ge) detectors into a CMOS logic process. Experimental results for the photonic CMOS ring resonator modulators and Ge detectors demonstrate performance above 20 Gb/s and analysis predicts that photonic CMOS will eventually enable energy efficiency better than 0.3 pJ/b with 16 nm CMOS. Optical interconnect technologies such as these using multi-lane communication or wavelength division multiplexing have the potential to achieve TB/s interconnect and enable platforms suitable for the tera-scale computing era.     

Power allocation,relay selection and energy cooperation strategies in energy harvesting cooperative wireless networks

In this paper, optimal power allocation and relay selection strategies in energy harvesting cooperative wireless networks are studied. In particular, signal‐to‐noise ratio (SNR)‐maximizing based power allocation and relay selection without and with energy cooperation—via wireless energy transfer—are considered. Moreover, total relay power minimization subject to target end‐to‐end SNR is investigated. The different optimal strategies are formulated as optimization problems, which are non‐convex. Thus, intelligent transformations are applied to transform non‐convex problems into convex ones, and polynomial‐time solution procedures are proposed. Simulation results illustrate that power allocation strategies achieve higher end‐to‐end SNR than relay selection ones. Finally, energy cooperation is shown to be effective in improving end‐to‐end SNR, while total relay power minimization balances end‐to‐end SNR, transmit power consumption, and harvested energy. Copyright © 2016 John Wiley & Sons, Ltd.     

Cross-layer speculative architecture for end systems and gateways in computer networks with lossy links

The throughput degradation of Transport Control Protocol (TCP)/Internet Protocol (IP) networks over lossy links due to the coexistence of congestion losses and link corruption losses is very similar to the degradation of processor performance (i.e., cycle per instruction) due to control hazards in computer design. First, two types of loss events in networks with lossy links are analogous to two possibilities of a branching result in computers (taken vs. not taken). Secondly, both problems result in performance degradations in their applications, i.e., penalties (in clock cycles) in a processor, and throughput degradation (in bits per second) in a TCP/IP network. This has motivated us to apply speculative techniques (i.e., speculating on the outcome of branch predictions), used to overcome control dependencies in a processor, for throughput improvements when lossy links are involved in TCP/IP connections. The objective of this paper is to propose a cross-layer network architecture to improve the network throughput over lossy links. The system consists of protocol-level speculation based algorithms at transport layer, and protocol enhancements at middleware and network layers that provide control and performance parameters to transport layer functions. Simulation results show that, compared with prior research, our proposed system is effective in improving network throughput over lossy links, capable of handling incorrect speculations, fair for other competing flows, backward compatible with legacy networks, and relatively easy to implement.     

Tubular guidance systems for daylight: Achieved and predicted installation performances

Tubular daylight-guidance systems are linear devices that channel daylight into the core of a building. The development, over the last decade, of materials with high specular reflectance has led to a large number of passive zenithal systems; the most commercially successful type of daylight guidance being installed in many parts of the world. The rapid change in technology has not been matched by the development of either reliable and standardised design methods or design criteria against which the systems may be evaluated. This paper presents the results of several surveys of daylight guidance systems in 13 working buildings. These give an indication of the conditions created, which are used as the bases of suggested design criteria. A critical review of existing performance prediction methods notes that these lag far behind comparable methods for electric lighting and conventional glazing. A number of improved methods of prediction, currently under consideration by the CIE Technical Committee TC3-38, are presented and each is tested against measured data from the installation surveys.     

Resonant tunneling through double barriers, perpendicular quantum transport phenomena in superlattices, and their device applications

New results on the physics of tunneling in quantum well heterostructures and its device applications are discussed. Following a general review of the field in the Introduction, in the second section resonant tunneling through double barriers is investigated. Recent conflicting interpretations of this effect in terms of a Fabry-Perot mechanism or sequential tunneling are reconciled via an analysis of scattering. It is shown that the ratio of the intrinsic resonance width to the total scattering width (collision broadening) determines which of the two mechanisms controls resonant tunneling. The role of symmetry is quantitatively analyzed and two recently proposed resonant tunneling transistor structures are discussed. The third section deals with perpendicular transport in superlattices. A simple expression for the low field mobility in the miniband conduction regime is derived; localization effects, hopping conduction, and effective mass filtering are discussed. In the following section, experimental results on tunneling superlattice photoconductors based on effective mass filtering are presented. In the fifth section, negative differential resistance resulting from localization in a high electric field is discussed. In the last section, the observation of sequential resonant tunneling in superlattices is reported. We point out a remarkable analogy between this phenomenon and paramagnetic spin resonance. New tunable infrared semiconductor lasers and wavelength selective detectors based on this effect are discussed.     

Developing a procurement path determination chart SEM-based approach

The choice of an appropriate procurement system is crucial to construction project success. Procurement selection is largely based on path determination charts, with at least eight key criteria needing to be weighted by decision-makers. Including certain criteria whilst ignoring client-borne transaction costs (TCs) resulting from environmental uncertainties simplifies this process. TCs are ‘unseen’ costs associated with pre- and post-contract work. The effects of uncertainties in the transaction environment and procurement systems on TCs are investigated, comparing the traditional and design-build procurement systems. A cross-sectional sample approach was deployed, involving survey questionnaire and results verification through ‘real-world’ cases. Data was sought from construction professionals in management, design and operation of construction projects. The research participants evaluate their time spent on procurement activities using a five-point Likert scale. Hypotheses of the relations between environmental uncertainties, procurement systems, and pre- and post-contract TCs are tested using a structural equation modelling (SEM) approach. The study found that TCs account for about 46.75% and 42.88% of the daily time spent by project managers in traditional and design-build procurement systems in New Zealand respectively. The study concludes that the TC concept is a useful framework for determining objective instead of subjective opinions for procurement decisions.     

Rheology of natural fibers thermoplastic compounds: Flow length and fiber distribution

The presented study investigates the flow length and the corresponding fiber content distribution in the injection‐moulded natural fiber reinforced thermoplastics and its relation to fiber type and processing parameters such as injection pressure, temperature, injection rate and mould tempering by increasing die temperature. In this research, polypropylene compounds with nominally 30 wt % hemp and sisal fibers are investigated. The influence of the injection pressure (500 and 1000 bar), melt temperature (180°C, 200°C, and 220°C), and die temperature (23°C and 80°C) on the fiber content distribution all over the sample is investigated. An increasing linear trend of fiber content along the spiral length is observed as an evidence of a fiber/polymer multiflow system. A pattern for fiber content distribution with respect to the fiber length along the injected spiral can be distinguished, where the longer fibers are usually found at the end of the injected part and the shorter fibers remain near mould entrance point. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39861.     

On optimal filters with maximum number of constraints on amplitude and phase characteristics

For optimal filters specified amplitude and phase (or group delay) characteristics, it is required that all the free parameters of the transfer function be used for the approximation. To achieve this requirement, the number of constraints on the amlitude and phase characteristics is defined first on general interpolation bases. Constant or arbitrarily prescribed lowpass or bandpass group delay and amplitude characteristics are approximated in the maximally flat, ripple or mixed sense for lumped filters, whereas highpass and band rejection characteristics are also considered for distributed or sampled data filters. The relationship between the number of free parameters and the number of amplitude and phase constraints for a given degree is derived for non-reciprocal as well as for reciprocal lossy and reciprocal reactant cases. Conditions are derived for the distribution of free parameters between the passband and stopband amplitude and phase characteristics for transfer functions with Hurwitzian denominator and also for monotonic amplitude characteristics in the transition band. Some published separate and simultaneous approximation methods are evaluated and compared on the above bases. It is pointed out that some of these methods do not satisfy the above requirements, although the optimal solution would exhibit higher performances.