Effects of peroxide crosslinking on the mechanical and morphological properties of poly(ethylene‐co‐vinyl acetate)/zeolite composites

Uncrosslinked and chemically crosslinked ethylene‐vinyl acetate copolymers (EVAs) with 5–25 volume percentages of zeolite were prepared in a melt‐mixing process and then compression‐molded on a hot‐press machine according to standard test specifications. The mechanical properties measured by tensile test showed a reduction in tensile strength and elongation at break with increasing zeolite content. However, an increasing trend was observed for tensile modulus with addition of zeolite. Experimental results for ultimate stress were compared with those from Pukanszky equation. The experimental data showed a good fit to the Pukanszky model. The improvement in the interfacial interaction for crosslinked composites was also confirmed by this model. Morphological changes of EVA/zeolite composites were analyzed by scanning electron microscopy (SEM). The fractured surface of the composites indicated more complex morphology at higher zeolite loading. The influence of crosslinking induced by 2 wt% of dicumyl peroxide on the properties of EVA/zeolite composites was also investigated. The crosslinked composites showed better tensile properties than the uncrosslinked ones, a result which might be an indication of enhanced interaction between the EVA and zeolite. Density measurements, gel content determinations, and Fourier transform infrared analyses were also performed to evaluate the crosslink content of the composites. The changes in the properties of chemically crosslinked EVA/zeolite composites were observed. Meanwhile, SEM micrographs of the crosslinked EVA/zeolite composites showed better interfacial strength between zeolite and the EVA matrix as compared to that of the uncrosslinked composites. J. VINYL ADDIT. TECHNOL., 2012. © 2012 Society of Plastics Engineers     

Phase Transformations of α-Alumina Made from Waste Aluminum via a Precipitation Technique

We report on a recycling project in which α-Al₂O₃ was produced from aluminum cans because no such work has been reported in literature. Heated aluminum cans were mixed with 8.0 M of H₂SO₄ solution to form an Al₂(SO₄)₃ solution. The Al₂(SO₄)₃ salt was contained in a white semi-liquid solution with excess H₂SO₄; some unreacted aluminum pieces were also present. The solution was filtered and mixed with ethanol in a ratio of 2:3, to form a white solid of Al₂(SO₄)₃·18H₂O. The Al₂(SO₄)₃·18H₂O was calcined in an electrical furnace for 3 h at temperatures of 400–1400 °C. The heating and cooling rates were 10 °C/min. XRD was used to investigate the phase changes at different temperatures and XRF was used to determine the elemental composition in the alumina produced. A series of different alumina compositions, made by repeated dehydration and desulfonation of the Al₂(SO₄)₃·18H₂O, is reported. All transitional alumina phases produced at low temperatures were converted to α-Al₂O₃ at high temperatures. The X-ray diffraction results indicated that the α-Al₂O₃ phase was realized when the calcination temperature was at 1200 °C or higher.     

Key Factors Influencing the Energy Absorption of Dual-Phase Steels: Multiscale Material Model Approach and Microstructural Optimization

Metallurgical and Materials Transactions A - The increase in use of dual-phase (DP) steel grades by vehicle manufacturers to enhance crash resistance and reduce body car weight requires the...     

Vibro-acoustic analysis of free piston engine structure using finite element and boundary element methods

This paper presents the results of vibro-acoustic modeling and simulation using the finite element and the boundary element methods for the free piston engine structure. A model of the engine was constructed through the use of finite element software to perform a normal mode analysis of the engine structure. The objective was to determine the mode shapes and the natural frequency that contribute to engine structure vibration. Theoretical development of the engine balance motion and frequency response was also conducted. From the simulation and finite element analysis, the force response pattern of the engine vibration was determined and then compared with its natural frequency. The vibration data were used as the input data for noise analysis using the boundary element method. The integration of the finite element and the boundary element determined the noise-frequency data of the engine structure toward the occurrence of engine noise. The information can be used by designers to analyze engine specifications and structure, especially at the preliminary design stage.     

Experiments on Surface Reconstruction for Partially Submerged Marine Structures

Over the past 10 years, significant scientific effort has been dedicated to the problem of three‐dimensional (3‐D) surface reconstruction for structural systems. However, the critical area of marine structures remains insufficiently studied. The research presented here focuses on the problem of 3‐D surface reconstruction in the marine environment. This paper summarizes our hardware, software, and experimental contributions on surface reconstruction over the past few years (2008–2011). We propose the use of off‐the‐shelf sensors and a robotic platform to scan marine structures both above and below the waterline, and we develop a method and software system that uses the Ball Pivoting Algorithm (BPA) and the Poisson reconstruction algorithm to reconstruct 3‐D surface models of marine structures from the scanned data. We have tested our hardware and software systems extensively in Singapore waters, including operating in rough waters, where water currents are around 1–2 m/s. We present results on construction of various 3‐D models of marine structures, including slowly moving structures such as floating platforms, moving boats, and stationary jetties. Furthermore, the proposed surface reconstruction algorithm makes no use of any navigation sensor such as GPS, a Doppler velocity log, or an inertial navigation system.     

Effect of sintering on the microstructure and mechanical properties of alloy titanium-wollastonite composite fabricated by powder injection moulding process

Composite biomaterials are in high demand in the medical field of today. The combination of bioactive wollastonite (WA) glass ceramic with the biocompatibility of alloy titanium (Ti6Al4V) could be a good candidate for implant applications. The rheological properties of Ti6Al4V/WA feedstock show a pseudoplastic behaviour with low activation energy. The feedstock was successfully injected as a green part with no defects. The green part was solvent debound for 6?h in heptane and thermal debound in an argon environment for 1?h. The brown part was successfully sintered at 1300?°C for 3?h with 5?°C/min heating and cooling rates. The average sintered density was 4.12?g/cm³; which is 97.5% from the theoretical density. The highest Young's modulus obtained was 18.10?GPa; which is in the range of human bone strength. EDX analysis shows that by increasing sintering temperature, the level of oxygen decreased. Cell viability test shown an absorbance increased with days increasing indicated that the cellular were proliferated on the composite Ti6Al4V/WA composite which also proved that the composite was non-toxic. This indicates that the Ti6Al4V/WA composite is suitable for bone implant applications.     

Consumer shopping behaviour on the Internet: insights from Malaysia

Shopping on the Internet enables consumers to search for information on products or services and make purchases through direct interaction with online retailers. This study investigates consumer shopping behaviour on the Internet based on four aspects, i.e. the Internet marketing environment, product characteristics, familiarity, and promotional offers. The impact of influencing factors was checked by questionnaire survey, which was then processed and evaluated. Two hundred randomly selected respondents (students and employees in a public higher learning institution in the Federal Territory of Labuan, Malaysia) participated in the survey. Multiple regression analysis was used as a statistical measure to determine the most influential relationship aspect among a series of independent variables of consumer shopping on the Internet. The results revealed that familiarity has a great influence on consumer shopping on the Internet, followed by promotional offers. The assimilation of these aspects, and the empirical examination of the factors that influence consumer shopping on the Internet, advanced understanding of these constructs and their link to dynamic technology deployment for shopping. The paper suggests managerially actionable implications, and future research directions.     

Incorporating essential oils of marjoram and rosemary in the formulation of beef patties manufactured with mechanically deboned poultry meat to improve the lipid stability and sensory attributes

The effect of addition of essential oils of marjoram (Origanum marjorana L.) and rosemary (Rosmarinus officinalis L.) at concentration of 200 mg/kg to beef patties formulated with 200 g/kg mechanically deboned poultry meat (MDPM) was studied. The proximate composition, lipid oxidation, sensory characteristics and microbial counts of beef patties manufactured with 200 g/kg MDPM (percentage of lean portion) were assessed during frozen storage at ?18 °C. Beef patties formulated with MDPM (200 g/kg) showed significant (P < 0.05) reduction in protein content and significant (P < 0.05) increase in fat content. Incorporating MDPM in beef patties formulation significantly (P < 0.05) increased the TBARS (Thiobarbituric acid reactive substance) values and significantly (P < 0.05) reduced the flavor and overall acceptability scores. Addition of essential oils of marjoram and rosemary at level of 200 mg/kg significantly (P < 0.05) reduced the TBARS and significantly (P < 0.05) increased the sensory scores of beef patties during frozen storage period. Overall, the study indicated the potential use of natural herbal essential oils to protect against lipid oxidation and improve the sensory attributes of beef patties formulated with MDPM.     

Model-based test case generation and prioritization: a systematic literature review

Software and Systems Modeling - Model-based test case generation (MB-TCG) and prioritization (MB-TCP) utilize models that represent the system under test (SUT) for test generation and...