A Novel Self-aligned and Maskless Process for Formation of Highly Uniform Arrays of Nanoholes and Nanopillars

Fabrication of a large area of periodic structures with deep sub-wavelength features is required in many applications such as solar cells, photonic crystals, and artificial kidneys. We present a low-cost and high-throughput process for realization of 2D arrays of deep sub-wavelength features using a self-assembled monolayer of hexagonally close packed (HCP) silica and polystyrene microspheres. This method utilizes the microspheres as super-lenses to fabricate nanohole and pillar arrays over large areas on conventional positive and negative photoresist, and with a high aspect ratio. The period and diameter of the holes and pillars formed with this technique can be controlled precisely and independently. We demonstrate that the method can produce HCP arrays of hole of sub-250 nm size using a conventional photolithography system with a broadband UV source centered at 400 nm. We also present our 3D FDTD modeling, which shows a good agreement with the experimental results.     

Preparation of sol–gel-based nanostructured hybrid coatings; part 1: morphological and mechanical studies

Attempts have been made using sol–gel-based precursors to produce hybrid organic–inorganic clearcoats. To this end, a typical automotive acrylic/melamine clearcoat with tetramethyl ortosilicate (TEOS) and methacryoloxy propyltrimethoxysilane (MEMO) were used to obtain nanostructured silica clusters produced in situ embedded in the polymeric matrix. Microscopic techniques including scanning electron microscope (SEM), atomic force microscope (AFM), and transmission electron microscope (TEM) were utilized to investigate the morphology of coatings. The effect of each precursor on coating mechanical properties was also studied using dynamic mechanical thermal analysis (DMTA) as well as micro and nanoindentation techniques. It was found that using TEOS and MEMO (in non-hydrolyzed state), the mechanical properties of the resulting films were negatively influenced. The decreased hardness, lower T _g and cross-linking density, and reduced elastic modulus were observed with non-hydrolyzed precursors. In addition, the phase separation of organic and inorganic domains occurred in the presence of pristine sol–gel precursors. However, using hydrolyzed precursors (HTEOS and HMEMO), the mechanical properties were notably improved. While HTEOS resulted in an increase in coating T _g, and cross-linking density as well as improved elastic modulus and hardness, HMEMO caused an increase in coating hardness but lowered coating T _g and cross-linking density.     

On the Source of Jitter in a Room-Temperature Nanoinjection Photon Detector at 1.55 $mu hbox{m}$

The transient response of a nanoinjection infrared photon detector was studied by exploring the relation between lateral charge transfer and jitter. The jitter of the device was measured to be 15 ps at room temperature. The jitter was almost independent of the pulse power, even after device saturation. Spatial maps for delay and amplitude were acquired. The carrier velocity was extracted from the measurements and compared with that of the simulation model. The jitter due to transit time was calculated to be in agreement with the measured data, which indicated that the jitter is primarily transit time limited.     

Compounding fibre grade polyethylene terephthalate with a hyperbranched additive and studying its dyeability with a disperse dye

A hyperbranched polymer which comprised a polyesteramide structure was used to study improvements in dyeability of fibre grade polyethylene terephthalate films. The optical measurements of the dyed samples showed that, by increasing the percentages of the dendritic additive, K/S as a dye uptake parameter changed in the presence or absence of a carrier. The amount of chroma increased while the hue did not change significantly. The dyeability of the prepared samples was attributed to the decrease in glass transition temperature and the lower crystallinity of the polymer, as studied by differential scanning calorimetry. Thus, a new fibre grade polyethylene terephthalate, which is dyeable, could be obtained, with less need to use a toxic carrier compound.     

A mechanistic study of degradation of a typical automotive clearcoat caused by bird droppings

This study aims at investigating the degradation mechanism of an automotive clearcoat caused by bird droppings. Natural bird droppings and their synthetic equivalent (pancreatin) were utilized for this purpose. The presence of highly-etched areas on the surface of coatings and structural variations of clearcoat after being attacked by these materials corresponded to a catalyzed hydrolytic degradation. This finding was obtained using different analytical techniques. Based on these studies, three possible hypotheses were presented, including acid catalysis, metal ion catalysis, and enzymatic catalysis. The conditions required for the occurrence of each hypothesis were discussed. It was found that acid and metal ions have a weak contribution to catalyze the hydrolysis reaction of clearcoat, whereas enzymes existing in bird droppings were mainly responsible for this hydrolytic degradation.     

Electro-conductive modification of polyethylene terephthalate fabric with nano carbon black and washing fastness improvement by dopamine self-polymerized layer

Modification of textiles with new applications target such as electroconductive fabrics has recently attracted researchers. In this article, carbon black nanoparticles (CB NPs) were applied to polyester fabric through two separate high temperature (HT) exhaustion processing with NaOH and cetyltrimethylammonium bromide (CTAB) as alkali hydrolysis catalyst and dispersing agents. To improve the stability of CB NPs on the fabric a self-polymerized compound, dopamine (DA) was used in a simple dipping method at room temperature for 24 h to form a thin layer of PDA on CB NPs-treated fabric. Field emission scanning electron microscopy (FESEM) was used to study the morphology of the fabrics confirming presence of CB NPs. EDX and mapping patterns showed the percentage and distribution of carbon, nitrogen, and oxygen elements on the fabric surface. The treated fabric indicated an electrical resistance of 14 kΩ turns a LED device on with a 10 V power supply. Self-polymerized DA on the fabric surface led to more nitrogen and oxygen caused higher CB NPs stability. Furthermore, the tensile strength results revealed a 25.8% lower tenacity on the treated fabric. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48035.     

New strategies in model order reduction of trajectory piecewise‐linear models

Model order reduction based on trajectory piecewise linearization (TPWL) is a beneficial technique for approximating nonlinear models. One efficient method for building projection matrix in TPWL reduction is by aggregation of projection matrices of linearization points (LPs). However, in this method, the size of projection matrix will also grow up by increasing the number of LPs, which yield the increment of the size of reduced model. In other words, the size of reduced model will depend on the number of LPs. In this paper, we will address this issue and propose two new strategies for obviating this problem. Contrarily to former works in TPWL modeling, we established a model via TWPL based on output weighting of parallel linear models. Then, we proposed two reduction strategies for suggested TPWL model. The first algorithm inspires from former works in this field but in a parallel structure that enable segregation of projection matrices whereas the second algorithm remedies the problem by considering the high‐order TPWL model as a unit linear model and reduces this model like a linear model but uses back projection method for constructing different outputs. The efficiency of methods is shown by comparison with former TPWL methods through vast simulations. Copyright © 2015 John Wiley & Sons, Ltd.     

Polyimide/organo‐montmorillonite nanocomposites: A comparative study of the organoclays modified with aromatic diamines

Six organophilic clays have been obtained through cation‐exchange between sodium montmorillonite (Na^+‐Mt) and the hydrochloride salts of aromatic diamines (DA1–6). The results obtained by thermogravimetric analysis (TGA) showed that the organophilic clays start to decomposition within 150–340°C, which shows that they are thermally stable compared with conventional montmorillonite modified with aliphatic long‐chain quaternary alkyl ammonium salts. The highest thermal stability and interlayer basal spacing were observed for the organoclay obtained from 3,3′‐sulfonyl dianiline (DA2), and therefore it was chosen for preparing clay/polymer nanocomposite materials (CPN). Polyimide/clay nanocomposite materials consisting of benzophenone‐3,3′,4,4′‐tetracarboxylic dianhydride (BTDA) and 2‐(5‐(3,5‐diaminophenyl)‐1,3,4‐oxadiazole‐2‐yl)pyridine (POBD) were also obtained by an in situ polymerization reaction through a thermal imidization. DA2‐Mt was used as filler at different concentrations. Both the thermal stability and the glass transition temperature (T_g) are increased with respect to pure polyimide (PI) at low clay loadings. At high clay concentrations, the organoclay particles make aggregate and as results of this phenomena T_g and thermal stability are decreased. POLYM. COMPOS., 36:613–622, 2015. © 2014 Society of Plastics Engineers     

Microfluidic Synthesis of Ultrasmall Chitosan/Graphene Quantum Dots Particles for Intranasal Delivery in Alzheimer's Disease Treatment

Nanoparticles (NPs) based therapies for Alzheimer's disease (AD) attract interest due to their ability to pass across or bypass the blood-brain barrier. Chitosan (CS) NPs or graphene quantum dots (GQDs) are promising drug carriers with excellent physicochemical and electrical properties. The current study proposes the combination of CS and GQDs in ultrasmall NP form not as drug carriers but as theranostic agents for AD. The microfluidic-based synthesis of the CS/GQD NPs with optimized characteristics makes them ideal for transcellular transfer and brain targeting after intranasal (IN) delivery. The NPs have the ability to enter the cytoplasm of C6 glioma cells in vitro and show dose and time-dependent effects on the viability of the cells. IN administration of the NPs to streptozotocin (STZ) induced AD-like models lead to a significant number of entrances of the treated rats to the target arm in the radial arm water maze (RAWM) test. It shows the positive effect of the NPs on the memory recovery of the treated rats. The NPs are detectable in the brain via in vivo bioimaging due to GQDs as diagnostic markers. The noncytotoxic NPs localize in the myelinated axons of hippocampal neurons. They do not affect the clearance of amyloid β (Aβ) plaques at intercellular space. Moreover, they showed no positive impact on the enhancement of MAP2 and NeuN expression as markers of neural regeneration. The memory improvement in treated AD rats may be due to neuroprotection via the anti-inflammation effect and regulation of the brain tissue microenvironment that needs to be studied.