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71.
Mohammad Hossein Habibi Mojtaba Nasr-Esfahani Terry A. Egerton 《Journal of Materials Science》2007,42(15):6027-6035
TiO2—methylcellulose (MC) nanocomposite films processed by the sol-gel technique were studied for phocatalytic applications. Precalcined
TiO2 nanopowder was mixed with a sol and heat treated. The sol suspension was prepared by first adding titanium tetra isopropoxide
(Ti(OPr)4 or TTP) to a mixture of ethanol and HCl (molar ratio TTP:HCl:EtOH:H2O = 1:1.1:10:10) and then adding a 2 wt.% solution of methylcellulose (MC). The TiO2 nanopowder was dispersed in the sol and the mixture was deposited on a microscope glass slide by spin coating. Problems of
film inhomogeneity and defects which caused peeling and cracking during calcinations, because of film shrinkage, were overcome
by using MC as a dispersant. Effect of MC on the structure evaluation, crystallization behavior and mechanical integrity with
thermal treatment up to 500 °C are followed by SEM, XRD and scratch test. XRD Scanning electron microscopy (SEM) showed that
the composite films with MC have much rougher surface than films made without MC. Composite films heat treated at approximately
500 °C have the greatest hardness values. For the composite thick film, the minimum load which caused the complete coating
removal was 200 g/mm2, an indication of a strong bond to the substrate. Photocatalytic activities of the composite film were evaluated through
the degradation of a model pollutant, the textile dye, Light Yellow X6G (C.I. Reactive Yellow 2) and were compared with the
activity of (i) a similar composite film without MC, and (ii) a TiO2 nanopowder. The good mechanical integrity make this composite film an interesting candidate for practical catalytic applications. 相似文献
72.
Prediction of geological hazardous zones in front of a tunnel face using TSP-203 and artificial neural networks 总被引:3,自引:0,他引:3
Andisheh Alimoradi Ali Moradzadeh Reza Naderi Mojtaba Zad Salehi Afshin Etemadi 《Tunnelling and Underground Space Technology incorporating Trenchless Technology Research》2008,23(6):711-717
This research aims at improving the methods of prediction of hazardous geotechnical structures in the front of a tunnel face. We propose and showcase our methodology using a case study on a water supply system in Cheshmeh Roozieh, Iran. Geotechnical investigations had previously reported three measurements of the newly established method of TSP-203 (Tunnel Seismic Prediction) along 684 m of the 3200 m long tunnel up to a depth of 600 m. We use the results of TSP-203 in a trained artificial neural network (ANN) to estimate the unknown nonlinear relationships between TSP-203 results and those obtained by the methods of Rock Mass Rating classification (RMR – treated here as real values). Our results show that an appropriately trained neural network can reliably predict the weak geological zones in front of a tunnel face accurately. 相似文献
73.
Shamsipur M Hosseini M Alizadeh K Mousavi MF Garau A Lippolis V Yari A 《Analytical chemistry》2005,77(1):276-283
Spectrofluorometric studies on the binding properties of 5-pyridino-2,8-dithia[9](2,9)-1,10-phenanthrolinephane (L) toward La3+, Sm3+, Gd3+, Yb3+, and Nd3+ in methanol solution revealed the occurrence of both 1:1 and 2:1 (ligand/metal) complexation with a stability order of Nd3+ > Yb3+ > Gd3+ > Sm3+ > La3+. Consequently, L was used as a suitable neutral ionophore for the preparation of a novel polymeric membrane-selective electrode for Nd3+ ion. The electrode exhibited a Nernstian response over a wide concentration range (1.0 x 10(-6)-1.0 x 10(-2) M) with a low limit of detection of 7.9 x 10(-7) M. The electrode possesses a fast response time of <5 s and can be used for at least 9 weeks without observing any considerable deviation. The proposed electrode revealed a very good selectivity for Nd3+ over a wide variety of alkali, alkaline earth, transition, and heavy metal ions, including members of the lanthanide family other than Nd3+. The potentiometric response of the electrode is independent of the pH of test solution in the pH range 4.0-6.5. The proposed electrode was successfully applied to the recovery of Nd3+ ion from tap water samples and, also, as an indicator electrode, in potentiometric titration of neodymium(III) ions. 相似文献
74.
A comparison of antireflection surfaces based on the two-dimensional binary gratings and thin-film coatings is presented. First, a two-dimensional hybrid binary grating is proposed and analyzed by use of a vector-based implementation of the rigorous coupled-wave analysis method. The optimum parameters of the structure are determined and the effects that changing them have on spectral characteristics of the structure are studied. Then this structure is compared with multilayer thin-film antireflection filters. These filters are designed by genetic algorithm and needle methods, which are powerful methods for multilayer filter design. The comparison results show that the sensitivity of the grating to changes in the incident wavelength is high. However, a reflectance of the order of 10(-3)% at the design wavelength can be achieved. The sensitivity of designed antireflection thin-film filters to wavelength changes is lower, however, and the minimum achievable reflectance is higher. 相似文献
75.
This paper presents a new methodology demonstrating the feasibility and advantages of a state-time formulation for dynamic simulation of complex multibody systems which shows potential advantages for exploiting massively parallel computing resources. This formulation allows time to be discretized and parameterized so that it can be treated as a variable in a manner similar to the system state variables. As a consequence of such a state-time discretization scheme, the system of governing equations yields to a set of loosely coupled linear-quadratic algebraic equations that is well-suited in structure for some families of nonlinear algebraic equations solvers. The goal of this work is to develop efficient multibody dynamics algorithm that is extremely scalable and better able to fully exploit anticipated immensely parallel computing machines (tera flop, peta flop and beyond) made available to it. 相似文献
76.
Mohammad Reza Karafi Ramin Narimani Yousef Hojjat Mojtaba Gheybi 《The International Journal of Advanced Manufacturing Technology》2010,50(9-12):953-960
This paper presents a method for automatic control of arc length in tungsten inert gas (TIG) welding process using the arc voltage. By using this method, the role of operator in arc length control is played by an automatic control system based on a predefined arc voltage value for any special welding operation. A dynamic model for feed-rate mechanism and the relation between variations of arc length and voltage are described in details. Using a proportional-integral controller, variations of arc length in welding path is compensated with an automatic feed-rate mechanism in a normal direction to the welding path. By keeping the voltage constant during the process, a stable weld with higher quality and better appearance is obtained specially in welding of uneven surfaces. Theoretical and practical investigations show that the suggested method is able to control the TIG welding process successfully. Test results show that an accurate weld is obtained without the interference of the operator, and by comparing the predefined values of arc voltage with what is practically obtained, the welding gap is automatically adjusted. 相似文献
77.
Elham Khanniri Mojtaba Yousefi Nasim Khorshidian Sara Sohrabvandi Amir M Mortazavian 《International Journal of Dairy Technology》2019,72(1):8-14
The effects of locust bean, carboxymethyl cellulose, a mixture of locust bean and carboxymethyl cellulose and Persian gum on different properties of nonfat doogh were studied over a period of 28 days. The results showed that samples containing a mixture of locust bean and carboxymethyl cellulose had the highest stability. Furthermore, the rheological behaviour of the doogh changed from Newtonian to pseudoplastic. Better sensory acceptability was shown for the treatments containing a mixture of locust bean gum and carboxymethyl cellulose. In general, it was shown that a mixture of locust bean and carboxymethyl cellulose could be of practical use in the industrial production of nonfat doogh. 相似文献
78.
Gholamhossein Sodeifian Mojtaba Raji Morteza Asghari Mashallah Rezakazemi Amir Dashti 《中国化学工程学报》2019,27(2):322-334
SAPO-34 nanocrystals (inorganic filler) were incorporated in polyurethane membranes and the permeation properties of CO2, CH4, and N2 gases were explored. In this regard, the synthesized PU-SAPO-34 mixed matrix membranes (MMMs) were characterized via SEM, AFM, TGA, XRD and FTIR analyses. Gas permeation properties of PU-SAPO-34 MMMs with SAPO-34 contents of 5 wt%, 10 wt% and 20 wt% were investigated. The permeation results revealed that the presence of 20 wt% SAPO-34 resulted in 4.45%, 18.24% and 40.2% reductions in permeability of CO2, CH4, and N2, respectively, as compared to the permeability of neat polyurethane membrane. Also, the findings showed that at the pressure of 1.2 MPa, the incorporation of 20 wt% SAPO-34 into the polyurethane membranes enhanced the selectivity of CO2/CH4 and CO2/N2, 14.43 and 37.46%, respectively. In this research, PU containing 20 wt% SAPO-34 showed the best separation performance. For the first time, polynomial regression (PR) as a simple yet accurate tool yielded a mathematical equation for the prediction of permeabilities with high accuracy (R2 > 99%). 相似文献
79.
Ali Akbari Nasser Arsalani Bagher Eftekhari-Sis Mojtaba Amini Gholamreza Gohari Esmaiel Jabbari 《Frontiers of Chemical Science and Engineering》2019,13(3):563-573
Octavinyl polyhedral oligomeric silsesquioxane (POSS) was polymerized on the surface of Fe3O4 nanoparticles (NPs) and then the NPs were functionalized with carboxylic acid groups using thiol-ene click reactions with thioglycolic acid.The as-prepared Fe3O4@POSS-COOH magnetic hybrid NPs had mesoporous structures with an average particle diameter of 15 nm and a relatively high specific surface area of 447 m^2· g^-1.Experimental results showed that 4 mg of Fe3O4@POSS-COOH NPs efficiently adsorbed and removed methylene blue from water at 5 min.This is due to the presence of both carboxylic acid and pendant vinyl groups on the Fe3O4@POSS-COOH NPs.These NPs could be easily withdrawn from water within a few seconds under moderate magnetic field and showed high stability in acid and alkaline aqueous mediums. 相似文献
80.
Ahmadi Hossein Arji Goli Shahmoradi Leila Safdari Reza Nilashi Mehrbakhsh Alizadeh Mojtaba 《Universal Access in the Information Society》2019,18(4):837-869
Universal Access in the Information Society - The Internet of Things (IoT) is an ecosystem that integrates physical objects, software and hardware to interact with each other. Aging of population,... 相似文献