Effects of Thermal Annealing on Formation of Micro Porous Titanium Oxide by the Sol–Gel Method

We investigated the structural and optical properties of microporous titanium oxide (TiO₂) fabricated by the sol–gel method using templates of colloidal crystals with polystyrene spheres when the annealing temperature was changed between 600° and 1000°C. From X-ray diffraction patterns and SEM images, the rutile TiO₂ annealed at a high temperature did not form periodic porous bodies, while the anatase TiO₂ annealed at lower than 800°C formed periodic porous bodies. The porous TiO₂ obtained acts as an air-sphere/TiO₂ photonic crystal with an FCC structure. It is suggested that TiO₂ sol annealed at a lower temperature do not lead to phase transition from the anatase phase to the rutile phase to obtain the air-sphere/TiO₂ photonic crystal by the sol–gel method using templates of colloidal crystals.     

Multirobot exploration for search and rescue missions: A report on map building in RoboCupRescue 2009

In the future, mobile robots may be able to assist rescue crews in search and rescue missions that take place in the dangerous environments that result from natural or man‐made disasters. In 2006, we launched a research project to develop mobile robots that can rapidly collect information in the initial stages of a disaster. One of our important objectives is three‐dimensional (3D) mapping, which can be a very useful tool for assisting rescue crews in strategizing rescue missions. To realize this 3D mapping, we identified five issues that we needed to address: (1) autonomous traversal of uneven terrain, (2) development of a system for the continuous acquisition of 3D data of the environment, (3) coverage path planning, (4) centralization of map data obtained by multiple robots, and (5) fusion of map data obtained by multiple robots. We solved each problem through our joint research. Each research institute in our group took charge of solving one of the above issues according to its area of expertise. We integrated these solutions to perform 3D mapping using our tracked vehicle, Kenaf. To validate our integrated autonomous 3D mapping system, we participated in RoboCupRescue 2009 and demonstrated our system using multiple robots on the RoboCupRescue field. In this paper, we introduce our mapping system and report the mapping results obtained at the RoboCupRescue event. © 2011 Wiley Periodicals, Inc.     

Phase-transformation study of metastable tetragonal zirconia powder

The rate of the transformation from the metastable tetragonal to the monoclinic phase of ZrO2 was measured in air from 850°C to 1000°C by neutron diffraction. This rate was found to be temperature dependent, and its measured values were considerably lower then those reported previously. The kinetics of this phase transformation is discussed in terms of a modified crystallite growth-martensitic transformation model' that includes the distribution of crystallite sizes.     

Thermally stable ion conductive polymer composites containing imide-anion-type zwitterions

Summary Zwitterion bearing highly dissociable imide anion (EIm5csI) was used as major component for stable polymer electrolytes. A polymerization of methyl acrylate in the presence of EIm5csI/LiTFSI mixture gave a flexible film with the ionic conductivity of 9.3×10^-6 Scm^-1 at 50 °C. Mixing of poly(lithium acrylate) and EIm5csI/LiTFSI mixture improved ionic conductivity (3.3×10^-5 Scm^-1 at room temperature), lithium transference number (0.44), and thermal stability.     

Methane partial oxidation by silica‐supported iron phosphate catalysts. Influence of iron phosphate content on selectivity and catalyst structure

Selective oxidation of methane to methanol and formaldehyde at atmospheric pressure was studied over a series of silicasupported FePO₄ catalysts, with iron phosphate content ranging from 2 to 16 wt%. Performance was evaluated over the range T=773–963 K, GHSV=25,000–65,000 h^–1, and CH₄ : O₂=1. The main products were formaldehyde, carbon monoxide and carbon dioxide. Small, but quantifiable amounts of methanol were also observed. Catalytic activity exhibited a clear dependence on the iron phosphate content. The highest selectivity and space time yield (STY) to formaldehyde and methanol were observed for 2 wt% FePO₄ on silica (STY of 622 and 25 g/kg_cat h, respectively). The selectivity–conversion pattern suggests that methane is oxidized directly to methanol and formaldehyde, and sequentially to carbon oxides. Characterization was performed by Xray powder diffraction, Xray photoelectron spectroscopy, and Mössbauer spectroscopy. Crystalline FePO₄ is observed at all loading levels, however, a significant fraction of the iron (58% at 2 wt% FePO₄) is present in an Xray amorphous phase. Mössbauer spectra suggest that this phase contains iron in fivefold coordination, and with a higher electron density relative to bulk FePO₄. The amount of this fivecoordinate phase present is roughly 1 wt% Fe, independent of total iron loading. XPS confirms the lower effective oxidation state of iron, and indicates that at low loading the surface is enriched in phosphorus relative to bulk FePO₄. It is proposed that iron in fivefold coordinate sites, isolated by phosphate groups, more selectively activates methane than crystalline FePO₄. As loading increases, so does the amount of crystalline FePO₄, which is proposed to more rapidly catalyze sequential oxidation of the selective products.     

Properties of Heavily Mn-doped GaMnAs with Curie Temperature of 172.5 K

The authors have investigated the magnetic properties of heavily Mn-doped ferromagnetic semiconductor Ga_1−x Mn _x As thin film with the Mn concentration x of 15.2% grown by molecular-beam epitaxy at relatively high growth temperature of 250 °C. Magnetic circular dichroism and the anomalous Hall effect measurements indicate that this thin film holds the intrinsic ferromagnetic semiconductor features. By low-temperature annealing, the resistivity was significantly decreased and the Curie temperature was largely enhanced from 95 K to 172.5 K.     

Expressions of vascular endothelial growth factor in nonparenchymal as well as parenchymal cells in rat liver after necrosis

Vascular endothelial growth factor (VEGF) can induce proliferation of sinusoidal endothelial cells. Its mRNA expression was increased in proliferating rat hepatocytes in primary culture. To clarify a role of VEGF in liver after necrosis, expressions of VEGF and its receptors were measured in the liver or liver cells isolated from rats after carbon tetrachloride intoxication. Hepatic VEGF mRNA expression increased later than 24 h after the intoxication and became prominent at 168 h when liver necrosis disappeared, while hepatic mRNA expressions of its receptors increased between 24 and 72 h. VEGF mRNA expression was increased in Kupffer cells, hepatic macrophages and stellate cells isolated from rats between 24 and 72 h after the intoxication and in hepatocytes at 168 h compared to those cells from normal rats. Immunohistochemical VEGF stains were comparable to such results. Vascular endothelial cells existed abundantly in the necrotic areas, and sinusoidal endothelial cells appeared following disappearance of the necrotic areas. VEGF mRNA expression in hepatocytes isolated from 70% resected liver was increased at 12 h after the operation and became marked between 72 and 168 h. Similar increase of hepatic VEGF expression was immunohistochemically seen. In conclusion, VEGF derives from nonparenchymal as well as parenchymal cells in rat liver after necrosis. The former might contribute to vascular endothelial cell proliferation and the latter to sinusoidal endothelial cell regeneration.