Sonoelectrochemical synthesis of a nanoscale complex of lead(II) and 2-methyl-8-hydroxyquinoline: spectroscopic, photoluminescence, thermal analysis studies and its application in an OLED

A new lead complex, [Pb(mq)₂], (mq = 2-methyl-8-hydroxyquinoline) was prepared via an electrochemical route from the oxidation of lead metal in the presence of 2-methyl-8-hydroxyquinoline in a fast and facile process. The complex was fully characterized by means of NMR and IR spectra and elemental analysis. The nanostructure of the prepared compound was obtained by sonoelectrochemical process and studied by scanning electron microscopy, atomic force microscopy, X-ray powder diffraction, IR spectroscopy and elemental analysis. Thermal stability of single crystalline and nanosize samples of the prepared compound was studied by thermal gravimetric and differential thermal analysis. The photoluminescence properties of the prepared compounds, as single crystals and as nanorods, have been investigated. The results showed a good correlation between the size and the shape of the complex particles and emission wavelength. The prepared complex was doped in PVK:PBD blend as guest and its application in the fabrication of OLED was studied. The ratio of lead complex was modified and was equal to 8 (w/w %) in PVK:PBD (100:40).     

Blast furnace slags as functional fillers on rheological,thermal, and mechanical behavior of thermoplastics

Blast furnace slags (BFS) is a secondary byproduct of iron industry, which has a combination of acidic and basic oxides and show a complex, multiphase structure. If appropriately tailored, BFS could be an effective functional filler, improving the property profile of thermoplastics such as polypropylene (PP) and polystyrene (PS). As a raw material, the proposed filler may introduce both economic and ecological advantages, as it is considered an inexpensive secondary product rather than a natural resource. The current study aims at investigating the effect of incorporating BFS as a micro‐sized filler on the rheological, thermal, and mechanical behavior of PP and PS. BFS types in this study are air‐cooled, crystalline, and amorphous, grounded types. Both types are ground into 71, 40, and 20 μm batches and introduced in 10, 20, and 30 weight fractions via melt kneading. Mixtures are then formed into 4‐mm and 2‐mm thick plates via compression molding. Slight increase in rheological factors is observed with increasing filler loading. BFS hinders the crystallization of PP, resulting in slight increase of crystallization temperatures (T_c) and lowering of crystallization enthalpy (ΔH_c). No significant effect of filler on transition temperatures (T_g) is reported. Mechanically, BFS increases the tensile modulus of PP, but decreases its strength. For PS formulations, a modest toughening effect is observed by slag filler. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43021.     

Interrogating the Tailoring Steps of Pactamycin Biosynthesis and Accessing New Pactamycin Analogues

Pactamycin is a bacteria‐derived aminocyclitol antibiotic with a wide‐range of biological activity. Its chemical structure and potent biological activities have made it an interesting lead compound for drug discovery and development. Despite its unusual chemical structure, many aspects of its formation in nature remain elusive. Using a combination of genetic inactivation and metabolic analysis, we investigated the tailoring processes of pactamycin biosynthesis in Streptomyces pactum. The results provide insights into the sequence of events during the tailoring steps of pactamycin biosynthesis and explain the unusual production of various pactamycin analogues by S. pactum mutants. We also identified two new pactamycin analogues that have better selectivity indexes than pactamycin against malarial parasites.     

Effect of Material Inhomogeneity on Thermal Performance of a Rheocast Aluminum Heatsink for Electronics Cooling

The relation between microstructural inhomogeneity and thermal conductivity of a rheocast component manufactured from two different aluminum alloys was investigated. The formation of two different primary α-Al particles was observed and related to multistage solidification process during slurry preparation and die cavity filling process. The microstructural inhomogeneity of the component was quantified as the fraction of α ₁-Al particles in the primary Al phase. A high fraction of coarse solute-lean α ₁-Al particles in the primary Al phase caused a higher thermal conductivity of the component in the near-to-gate region. A variation in thermal conductivity through the rheocast component of 10% was discovered. The effect of an inhomogeneous temperature-dependent thermal conductivity on the thermal performance of a large rheocast heatsink for electronics cooling in an operation environment was studied by means of simulation. Design guidelines were developed to account for the thermal performance of heatsinks with inhomogeneous thermal conductivity, as caused by the rheocasting process. Under the modeling assumptions, the simulation results showed over 2.5% improvement in heatsink thermal resistance when the higher conductivity near-to-gate region was located at the top of the heatsink. Assuming homogeneous thermo-physical properties in a rheocast heatsink may lead to greater than 3.5% error in the estimation of maximum thermal resistance of the heatsink. The variation in thermal conductivity within a large rheocast heatsink was found to be important for obtaining of a robust component design.     

Synthesis of Co3O4 @ Organo/Polymeric Bentonite Structures as Environmental Photocatalysts and Antibacterial Agents for Enhanced Removal of Methyl Parathion and Pathogenic Bacteria

Two green nanocomposites of Co₃O₄ decorated CTAB/bentonite (Co@CT/BE) and chitosan/bentonite (Co@CH/BE) were synthesized as enhanced and environmental photocatalysts and antibacterial agents. As photocatalysts, the products were applied in the effective oxidation of toxic methyl parathion pesticide (MP) in wastewater under a visible light source. The application of Co@CH/BE (0.02 g) resulted in the complete oxidation of MP (50 mg/L) after 40 min and complete mineralization after 60 min. while the complete oxidation and mineralization of MP (50 mg/L) by Co@CT/BE was recognized after 75 min and 100 min, respectively. The Co@CH/BE composite is of higher activity than Co@CT/BE and can cause complete oxidation for MP at high concentrations up to 100 mg/L after 75 min. The oxidation pathway was illustrated considering the existence of the hydroxyl radicals as the active oxidizing species and the identified secondary organic compounds during the oxidation tests. The detected intermediate converted into end products of CO₂ and inorganic anions of SO₄^?2, NO₃^?, and PO₄^?3 at the final stages of the oxidation processes. As antibacterial agents, the two composites exhibit considerable inhabitation zones of about 20 mm against both the Gram-positive Staphylococcus aureus and Gram-negative bacterium Vibrio Sp. The synthetic Co@CH/BE showed the best antibacterial properties with 200 μg/mL as minimum inhibitory against Staphylococcus aureus.

     

The effect of substrate surface integrity on the surface properties of TiCrN coating applied via the CAE-PVD method

This study aims to investigate how the predeposition machining processes such as magnetic grinding, turning machining, and wire electrical discharge machining can influence the surface properties including electrochemical and tribological behavior of TiCrN nanostructured coating applied on Mo40 steel substrate. A physical vapor deposition technique using cathodic arc evaporation was used to apply the coating. The crystallographic phases and the microstructure of the coating were studied by X-ray diffraction and scanning electron microscope, respectively. Rockwell-C, electrochemical impedance spectroscopy and potentiodynamic polarization, and pin-on-disk wear tests were employed to evaluate the adhesion strength, corrosion behavior, and tribological property of specimens, respectively. The electrochemical results after 24 h of exposure to 3.5 wt% NaCl solution showed that TiCrN coating pretreated with a turning process with polarization resistance of about 3525.32 Ω.cm² had the best corrosion resistance among all specimens. This was because of the improvement of the smoothness, surface quality, and adhesion after the turning process. On the other, the friction coefficient of the grounded sample is less than that of other ones. This is probably due to its higher adhesion strength and higher surface smoothness.     

Rolling element bearings absolute life prediction using modal analysis

In this paper, the authors introduce an experimental procedure for predicting the fatigue life of each individual rolling element bearing separately using vibration modal analysis. The experimental procedure was developed based on a statistical analysis. A statistical analysis was performed to find an empirical model that correlates the dynamic load capacity of rolling bearings to their dynamic characteristics (Natural frequencies and damping). These dynamic characteristics are obtained from the frequency response function of each individual bearing that results from vibration modal analysis. A modified formula to the already known Lundberg-Palmgren life formula is proposed for rolling element bearings. Given the modified formula, one can predict the fatigue life of each individual rolling element bearing based on its dynamic characteristics. The paper compares the results from the modified formula with those from Lundberg-Palmgren formula. The modified formula provides an accurate prediction for the fatigue life of each individual bearing based on its dynamic characteristics. The experimental validation of the modified formula is considered for future work. Therefore, it can be used in various applications of rolling element bearings in machinery systems.     

Some Studies on Starch Carbamate

Starch carbamate was prepared by reacting maize starch with urea using solid state technique. The different factors affecting this reaction were studied. These factors include urea concentration, type of starch, reaction and duration. The carbamate extent and carbamation reaction efficiency (%) were traced by estimating the nitrogen content of the reaction product. Solubility, viscosity and total ester content of starch carbamate samples were estimated. The carbamate extent increases by increasing urea concentration as well as reaction temperature and duration. Increasing the reaction temperature and duration has the same effect on carbamation reaction efficiency (%), while increasing urea concentration do the reverse. The solubility (%) of starch carbamate samples depends on urea concentration, reaction temperature and duration as well as the type of starch used. The maximum solubility obtained was 63% and 43% for starch carbamate derived from pregelled and native starch, respectively. Tentative mechanism for the reaction between starch and urea has been proposed.     

Room temperature oxidation of acetone by ozone over alumina-supported manganese and cobalt mixed oxides

Volatile organic compounds (VOCs) are among the major sources of air pollution. Catalytic ozonation is an efficient process for removing VOCs at lower reaction temperature compared to catalytic oxidation. In this study, a series of alumina supported single and mixed manganese and cobalt oxides catalysts were used for ozonation of acetone at room temperature. The influence of augmenting the single Mn and Co catalysts were investigated on the performance and structure of the catalyst. The manganese and cobalt single and mixed oxides catalysts of the formula Mn10%-CoX and Co10%-MnX (where X= 0, 2.5%, 5%, or 10%) were prepared. It was found that addition of Mn and Co at lower loading levels (2.5% or 5%) to single metal oxide catalysts enhanced the catalytic activity. The mixed oxides catalysts of (Mn10%-Co2.5%) and (Mn10%-Co5%) led to acetone conversion of about 84%. It is concluded that lower oxidation state of the secondary metal improves ozone decomposition and oxidation of acetone.     

CFD simulation of transverse vibration effects on radial temperature profile and thermal entrance length in laminar flow

Radial heat transfer in laminar pipe flow is characterized by a wide temperature distribution over the pipe cross‐section. We use a validated Computational Fluid Dynamics (CFD) model to show that the superimposition of a transverse vibration on the steady laminar flow of a Newtonian fluid moving in a pipe with an isothermal wall, generates considerable chaotic flow and radial mixing which result in a large enhancement in wall heat transfer as well as a considerably more uniform radial temperature field. Transverse vibration also causes the temperature profile to develop very rapidly in the axial direction reducing the thermal entrance length by a large factor. These effects are dependent on vibration amplitude and frequency, and fluid viscosity. © 2010 American Institute of Chemical Engineers AIChE J, 2011