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941.
This paper embodies the first report on the pulse reversal deposition of CdSe thin films. The as-deposited and heat-treated films were characterised by XRD, optical absorption spectroscopy and electrical properties. The polycrystalline deposits of CdSe obtained indicated a hexagonal structure after heat treatment at 550°C. From the optical absorption measurements the band gap was found to be 1.71 eV. At an illumination of 70 mW cm−2 conversion efficiencies of 3.20% and 6.57% were obtained for the photoelectrodes without and with pulse reversal. 相似文献
942.
K.R. Murali A. Austine B. Jayasutha D.C. Trivedi 《Solar Energy Materials & Solar Cells》2006,90(6):753-759
CdSe thin films were brush plated on substrates maintained at temperatures in the range 30–90 °C from the precursors. The films exhibited hexagonal crystal structure. Optical band gap of 1.65 eV was obtained. XPS measurements indicated the formation of CdSe. Capacitance–voltage measurements indicated the films to exhibit n-type behaviour. A carrier density of 1017 cm−3 was obtained. Photoelectrochemical cells have exhibited higher efficiency compared to earlier reports on brush-plated films. Spectral response measurements indicated a peak quantum efficiency of 75% at 1.65 eV. 相似文献
943.
Pattabhi R. BUDARAPU Sudhir Sastry YB Brahmanandam JAVVAJI D. Roy MAHAPATRA 《Frontiers of Structural and Civil Engineering》2014,8(2):151-159
We propose a method to estimate the natural frequencies of the multi-walled carbon nanotubes (MWCNTs) embedded in an elastic medium. Each of the nested tubes is treated as an individual bar interacting with the adjacent nanotubes through the inter-tube Van der Waals forces. The effect of the elastic medium is introduced through an elastic model. The mathematical model is finally reduced to an eigen value problem and the eigen value problem is solved to arrive at the inter-tube resonances of the MWCNTs. Variation of the natural frequencies with different parameters are studied. The estimated results from the present method are compared with the literature and results are observed to be in close agreement. 相似文献
944.
In this work multi-component equiatomic and non-equiatomic AlCoCrCuFeTix hexanary high-entropy alloys (HEA) was synthesised through mechanical alloying. The prepared powder was sintered via spark plasma sintering. Influence of alloying element variation in the multi-component system was studied in terms of phase formation and crystal structure by using Thermo-Calc and X-ray diffraction characterization technique (XRD). Particle morphology and chemical analysis studies were carried out through scanning electron microscopy along with Electron Dispersive X-ray Spectroscopy. The crystal structure and nano crystallinity of the hexanary system were recognised using transmission electron microscope (TEM and Selected Area Electron Diffraction [SAED]) while the formation of a solid solution was also studied and discussed. From the XRD and TEM characterisation of 20?h in, milled powders and sintered samples, it was confirmed that the developed HEA system forms a single solid solution BCC phase. The sintered alloy exhibits 97% relative density and an average hardness of 590?VHN.Special theme block on high entropy alloys, guest edited by Paula Alvaredo Olmos, Universidad Carlos III de Madrid, Spain, and Sheng Guo, Chalmers University, Gothenburg, Sweden. 相似文献
945.
Hina Kamal Sabika Jafar Priti Mudgil Chandraprabha Murali Amr Amin Sajid Maqsood 《Journal of dairy science》2018,101(10):8711-8720
This report describes an investigation of camel whey protein hydrolysates (CWPH) produced by gastric and pancreatic enzymes for their in vitro antidiabetic, anticancer, and anti-inflammatory properties. Degree of hydrolysis (DH) ranged from 8.54 to 47.53%, with hydrolysates generated using chymotrypsin for 6 h displaying the highest DH. Reverse phase-HPLC analysis showed that α-lactalbumin underwent complete degradation, with no intact α-lactalbumin detected in CWPH. The CWPH displayed enhanced antidiabetic activity compared with intact whey proteins; with pepsin- and chymotrypsin-generated CWPH displaying greater inhibition of dipeptidyl peptidase IV (DPP-IV), α-glucosidase, and α-amylase compared with trypsin-generated CWPH. The highest antiproliferative effect was observed for CWPH generated by chymotrypsin for 3 h, with only 4.5 to 6.5% viable liver cancer cells (HepG2) remaining when tested at concentrations from 400 to 1,000 µg/mL. The highest anti-inflammatory activity was manifested by CWPH generated by pepsin at 6-h hydrolysis. We report enhanced antiproliferative, antidiabetic, and anti-inflammatory activities upon hydrolysis of camel whey proteins, indicating their potential utilization as bioactive and functional ingredients. 相似文献
946.
947.
Zinc ion conducting nanocomposite gel polymer electrolytes (NCGPEs) comprising of poly(vinyl chloride) (PVC)/poly(ethyl methacrylate) (PEMA) blend, zinc triflate [Zn(OTf)2] salt, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIMTFSI) ionic liquid (IL) and fumed silica (SiO2) viz. [PVC/PEMA–Zn(OTf)2–EMIMTFSI–SiO2] exhibited the highest ionic conductivity value of 6.71 × 10−4 Scm−1 at room temperature. The ion–filler–polymer interactions and probable conformational changes observed in the structure of the gel composites due to the entrapment of IL and dispersion of nano-sized SiO2 were confirmed from X-ray diffraction (XRD) and Attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy. Scanning electron microscopic (SEM) images of NCGPEs demonstrated uniform surface with abundant interconnected micropores. The cationic transport number of NCGPE samples has been found to be appreciably enhanced up to a maximum of 0.69 thus demonstrating a considerable improvement in Zn2+ ion conductivity. The NCGPE film possesses an electrochemical stability window up to 5.07 V (vs. Zn/Zn2+) and ensures feasible zinc stripping/plating in the redox process. The addition of SiO2 into the gel polymer electrolyte system has effectively reduced the glass-transition temperature (Tg) of the NCGPE films and also accomplished improved thermal stability up to approximately 180 °C which were ascertained from Differential scanning calorimetry (DSC) and Thermogravimetric (TG) results. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47654. 相似文献
948.
949.
Preparation and properties of silica filled PTFE flexible laminates for microwave circuit applications 总被引:1,自引:0,他引:1
Micron and nano size silica fillers are incorporated in the PTFE matrix to prepare flexible composite substrates. A proprietary process comprising of sigma mixing, extrusion, calendering followed by hot pressing (SMECH process) has been employed to obtain nearly isotropic and dimensionally stable filled PTFE substrates. Theoretical modeling has been employed to predict the effective dielectric constant of the composite system and validated the results with experimental data. The distribution of particulate filler in the PTFE matrix has been studied using scanning electron microscopy. The linear coefficient of thermal expansion and ultimate tensile strength of the composite systems with respect to filler loading have been found out. Dielectric properties of the composite substrates at X-band frequency (8.2–12.4 GHz) are measured using waveguide cavity perturbation technique. Moisture absorption of fused silica filled substrates is found out conforming to IPC-TM-650 2.6.2. 相似文献
950.
Renu Pasricha Tanushree Bala Ankush V. Biradar Shubhangi Umbarkar Murali Sastry 《Small (Weinheim an der Bergstrasse, Germany)》2009,5(12):1467-1473
A facile method for the synthesis of porous platinum nanoparticles by transmetallation reactions between sacrificial nickel nanoparticles and chloroplatinic acid (H2PtCl6) in solution, as well as at the constrained environment of the air–water interface, using a Langmuir–Blodgett instrumental setup is presented. To carry out the transmetallation at the air–water interface hydrophobized nickel nanoparticles are assembled as a monolayer on the sub phase containing platinum ions. The porous Pt nanoparticles obtained as a result of the reaction are found to act as extremely good catalysts for hydrogenation reaction. The products are well characterized by TEM, HRTEM, EDAX, and STEM. Attempts are made to postulate the plausible mechanism of this reaction to generate this kind of nanoparticle with controllable geometric shape and structure. This simple strategy has the potential to synthesize other nanomaterials of interest too. 相似文献