Evaluation of Antioxidant Activity,and Nutritional and Chemical Composition of Ficus amplissima Smith Fruit

The present study was evaluated using the following in vitro antioxidant methods: 2,2′-azinobis (3-ethyl-benzothiozoline)-6-sulfonic acid disodium salt, phosphomolybdenum, ferric reducing antioxidant power, metal ion chelating activity, super oxide anion radical scavenging, hydrogen peroxide, and hydroxyl radical. Among these assays, acetone extract showed maximum free radical scavenging activity in 2,2′-azinobis (3-ethyl-benzothiozoline)-6-sulfonic acid disodium salt, phosphomolybdenum, metal ion chelating, superoxide anion, hydrogen peroxide, and hydroxyl radical assays. Moreover, the physiochemical, nutritional, and anti-nutritional parameters were analyzed. Its qualitative and quantitative composition was studied by gas chromatography-mass spectroscopy and out of 27 peaks, 27 compounds were identified. These compounds have the property of antioxidant, antimicrobial, and anti-inflammatory activity.     

A coprecipitation technique to prepare Sro.5Bao.5Nb206

An aqueous mixture of ammonium oxalate and ammonium hydroxide was used to coprecipitate barium and strontium ions as oxalates and niobium ions as hydroxide under basic conditions. This precursor on calcining at 750°C yielded Sr_0.5Ba_0.5Nb₂O₆ phase. This is a much lower temperature than that prepared by traditional solid state method (1000°C) as reported for the formation of Sr_0.5Ba_0.5Nb₂0₆ (SBN). Transmission electron microscopic (TEM) investigations revealed that the average particle size was 80 nm for the calcined powders. The room temperature dielectric constant at 1 kHz was found to be 1100. The ferroelectric hysteresis loop parameters of these samples were also studied.     

Green synthesis of silver nanoparticles using Zea mays and exploration of its biological applications

The biosynthesis of silver nanoparticles (AgNPs) has been proved to be a cost effective and environmental friendly approach toward chemical and physical methods. In the present study, biosynthesis of AgNPs was carried out using aqueous extract of Zea mays (Zm) husk. The initial colour change from golden yellow to orange was observed between 410 and 450 nm which confirmed the synthesis of AgNPs. Also, dynamic light scattering‐particle size analysis confirmed the average size to be 113 nm and zeta potential value of −28 kV. The morphology of synthesised Zm AgNPs displayed flower‐shaped structure, X‐ray diffraction pattern revealed the strongest peaks at 2θ = 38.6° and 64° which proved that the nanoparticle has the face centred crystalline structure. The Fourier transform infrared spectroscopy results showed strong absorption bands at 1394.53, 2980.02 and 2980.02 cm⁻¹ due to the presence of alkynes, carboxylic acids, alcoholic and phenolic groups. The maximum zone of inhibition was observed against Salmonella typhi (22 mm) and Candida albicans (18 mm). The synthesised nanoparticles exhibited more free radical scavenging activity than the aqueous plant extract. This is the first report on the synthesis of AgNP from Zm husk, delivers the efficient and stable Zm AgNPs through simple feasible approach toward green biotechnology.Inspec keywords: silver, nanoparticles, nanofabrication, light scattering, particle size, X‐ray diffraction, crystal structure, Fourier transform infrared spectra, absorption coefficients, free radicalsOther keywords: green synthesis, silver nanoparticles, biosynthesis, environmental friendly approach, aqueous extract, Zea mays husk, colour change, golden yellow, dynamic light scattering‐particle size analysis, average size, zeta potential value, flower‐shaped structure, X‐ray diffraction pattern, face centred crystalline structure, Fourier transform infrared spectroscopy, absorption bands, alkynes, carboxylic acids, alcoholic groups, phenolic groups, Salmonella typhi, Candida albicans, free radical scavenging activity, aqueous plant extraction, green biotechnology, size 113 nm, wavelength 410 nm to 450 nm     

Pyrolysis and combustion kinetics of Fosterton oil using thermogravimetric analysis

Thermogravimetric analysis (TGA) was used to examine the thermal behavior of Fosterton oil mixed with reservoir sand. TGA experiments were performed in nitrogen and air atmospheres at the heating rate of 10 °C/min up to 800 °C. In this study, four sets of TGA runs were performed to examine the thermal behavior of Fosterton whole oil, and the coke sample derived from the whole oil. Similar to previous studies in the literature, we also observed low-temperature oxidation (LTO), fuel deposition (FD), and high-temperature oxidation (HTO) in the non-isothermal combustion experiment. Higher activation energy values were obtained in reaction regions at higher temperatures. The mean activation energy for whole oil in nitrogen and air atmospheres was 33 and 126 kJ/mol, respectively. Fresh coke samples derived from whole oil were subjected to isothermal combustion at different temperatures from 375 to 500 °C. Arrhenius model was used to obtain the kinetic parameters from the TGA data. From the model, the Arrhenius parameters such as activation energy (E = 127 kJ/mol) and the pre-exponential factor (A = 1.6 × 10⁸/min) were determined for the coke combustion. The results showed a close agreement between the kinetic model and experimental data for different combustion temperatures. It was observed that the apparent order of combustion reaction for different temperatures approach unity.     

Anomalous Dielectric Behaviour in Melt Quenched Lithium Borate Glasses

Transparent glasses of lithium tetraborate (Li₂B₄O₇) were prepared by a splat quenching technique. X-ray powder diffraction (XRD) and high resolution transmission electron microscopic studies revealed the amorphous nature of the as-quenched samples. The glassy nature of these samples was confirmed by differential thermal analysis. Physical properties such as density, dielectric and ac conductivity have been studied. Glasses of Li₂B₄O₇ exhibit a dielectric anomaly close to the crystallization temperature which is attributed to the interfacial polarization caused by Li⁺ ion motion within the borate network.     

An investigation on the machinability of Al-SiC metal matrix composites using pcd inserts

The paper attempts to study the machinability issues of aluminium-silicon carbide (Al-SiC) metal matrix composites (MMC) in turning using different grades of poly crystalline diamond (PCD) inserts. Al-SiC composite containing 15%wt of SiC was used as work material for turning and PCD inserts of three different grades were used as cutting tools. Experiments were conducted at various cutting speeds, feeds and depth of cuts and parameters, such as surface roughness, specific power consumed, and material removal rate were measured. The worn surface of the insert was examined by scanning electron microscope (SEM). The surface finish observed was found to be much lower than the theoretical surface roughness. The influence of cut was examined for the different grades of PCD inserts. It was observed that the 1600 grade PCD inserts performed well from the surface finish and specific power consumption points of view closely followed by the 1500 grade.     

Prediction of tensile strength of friction stir welded aluminium matrix TiCp particulate reinforced composite

The usage of particulate reinforced metal matrix composite (MMC) is steadily increasing due to its properties such as high specific strength, high specific modulus and good wear resistance. Aluminium matrix composite (AMC) plays an important role to meet the above requirements. Effective utilization of AMC is based on not only its production but also on fabrication methods. Among AMCs, those based on particulate reinforcements are particularly attractive, due to their lower production costs. Aluminium matrix titanium carbide reinforced composite (Al–TiC_p) was produced in an inert atmosphere by indigenously developed Modified Stir Casting Process with bottom pouring arrangement (3–7% TiC by weight). Friction stir welding process (FSW) is employed to make weld joints. The welding parameters such as axial force, welding speed, tool rotational speed, percentage TiC addition etc., and profile of the tool were considered for analysis. In this study, an attempt is made to predict ultimate tensile strength (UTS) of the welded joints using a mathematical model. The FSW specimens without any post-weld heat treatment belonging to a different set of parameters tested, exhibited a high joint efficiency (most of them ranging from 90% to 98%) with respect to the ultimate tensile strength of the base material AA6061. It was found from the analysis of the model that the tool pin profile and the welding speed have more significant effect on tensile strength.     

Grafting of glycidylmethacrylate onto demineralized xenogeneic bone in aqueous medium

Summary Demineralized xenogeneic bone (DXB) was prepared from bovine cortical tibia and graft copolymerized with glycidylmethacrylate (GMA) using a combination of potassium persulfate (K₂S₂0₈) and sodium metabisulfite (Na₂S₂O₅)as redox initiating system in aqueous medium. To optimize the reaction condition, the concentrations of backbone, monomer, initiator, temperature and time were varied. The percent grafting was found to increase initially and thereafter decrease in most of the cases. The optimum temperature and time were found to be 40°C and 180 minutes, respectively. The grafting results have been discussed and a reaction mechanism is proposed. Functional groups and structural changes of the graft copolymer were determined by Fourier transform infrared (FT-IR) spectroscopic method for proof of grafting and the results are discussed. Received: 12 August 2002/Revised version: 30 October 2002/ Accepted: 25 November 2002 Correspondence to R. Murugan     

Removal of organics in water using hydrogen peroxide in presence of ultraviolet light

The optimum conditions for the removal of dissolved organic impurities from water using hydrogen peroxide (50%) followed by ultraviolet irradiation were investigated. The photochemically initiated hydroxyl radical (OH) oxidation reduced the total organic carbon (TOC) content of distilled water samples by about 88% and of tap water by 98%. Extraction with hexane of equal volumes of water samples before and after H₂O₂/u.v. treatment followed by gas chromatographic analysis of the concentrated extracts indicated that about 12% of the electron-capturing, residual organics remained after this treatment. These results support the conclusion drawn from total organic carbon analysis that this simple method yields water nearly free of organic impurities.