Thermally exfoliated graphene oxide reinforced fluorinated pentablock poly(l‐lactide‐co‐ε‐caprolactone) electrospun scaffolds: Insight into antimicrobial activity and biodegradation

Three‐dimensional fluorinated pentablock poly(l ‐lactide‐co‐ε‐caprolactone)‐based scaffolds were successfully produced by the incorporation of thermally exfoliated graphene oxide (TEGO) as an antimicrobial agent with an electrospinning technique. In a ring‐opening polymerization, the fluorinated groups in the middle of polymer backbone were attached with a perfluorinated reactive stabilizer having oxygen‐carrying ability. The fiber diameter and its morphologies were optimized through changes in TEGO amount, voltage, polymer concentration, and solvent type to obtain an ideal scaffold structure. Instead of the widely used graphene oxide synthesized by Hummer's method, TEGO sheets having a low amount of oxygen produced by thermal expansion were integrated into the fiber structure to investigate the effect of the oxygen functional groups of TEGO sheets on the degradation and antimicrobial activity of the scaffolds. There was no antimicrobial activity in TEGO‐reinforced scaffolds in the in vitro tests in contrast to the literature. This study confirmed that a low number of oxygen functional groups on the surface of TEGO restricted the antimicrobial activity of the fabricated composite scaffolds. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43490.     

Using hybridized ANN-GA prediction method for DOE performed drying experiments

Abstract

Coal is an important component in the energy industry and plays a key role in energy-producing facilities. Moisture is a common condition that has a considerable impact on coal. Coal drying has long been a question of great interest in a wide range of fields. Defining parameters in the coal drying is obtained by experiments. High costs, time constraints, and repetition of an experiment are one of the most frequently stated problems with experimental works. Using qualitative methods with experiments can be more useful for identifying and characterizing the coal drying process. The purpose of this article is finding the effective parameters in the coal drying process by using a hybridized prediction method. Genetic Algorithm (GA) and Artificial Neural Network (ANN) are hybridized with each other to identify and characterize the coal drying process. GA-ANN algorithm is applied to the coal drying process to predict the moisture of coal, but it does not provide a decent result at first. Later, the Design of Experiment (DoE) methodology is performed to determine the main effects of six parameters. Two scenarios are generated because two parameters are not statistically significant. The first scenario excludes the air relative humidity parameter, and the second scenario excludes the air relative humidity and the velocity of air parameters. Following the application of the DoE method, GA-ANN reaches decent results in scenario-2.     

Effects of annealing on the structural and magnetic properties of flame spray pyrolyzed MnFe2O4 nanoparticles

In this study, manganese ferrite (MnFe₂O₄) nanoparticles were produced through flame spray pyrolysis (FSP). To investigate the effects of heat treatment, the nanoparticles were annealed between 400 and 650°C for 4 h in air in a comparative manner. The structural, chemical, morphological, and magnetic properties of the nanoparticles were evaluated using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), dynamic light scattering (DLS), and vibrating sample magnetometry (VSM), respectively. The XRD results showed that the nanoparticles synthesized by the FSP method exhibited the MnFe₂O₄ spinel ferrite structure. The annealing process led to the decomposition of MnFe₂O₄ into various phases. According to the morphological analysis, the as-synthesized particles were hemispherical–cubic in shape and had an average particle size of less than 100 nm. In addition, the chemical bond structures of the nanoparticles were confirmed in detail by XPS elemental analysis. The highest saturation magnetization was recorded as 33.50 emu/g for the as-produced nanoparticles. The saturation magnetization of the nanoparticles decreased with increasing annealing temperature, while coercivity increased.     

Graphene oxide-containing isocyanate-based polyimide foams: Enhanced thermal stability and flame retardancy

Isocyanate-based graphene oxide-containing polyimide foams were synthesized by a semi-prepolymer method. In this method, while the first solution containing pre-polymer was derived from pyromellitic dianhydride and excess polymethylene polyphenylene isocyanate (PM200), the second solution contains dianhydride derivatives, water, catalysts, surfactants, and graphene oxide. PIFs were prepared with 0%, 0.25%, 0.50%, 0.75%, and 1% graphene oxide by weight, respectively. PIFs exhibited a minimum side reaction and urea generation was not seen for all PIFs instead of imide bonding. The addition of graphene oxide (GO) leads to a more close-packed structure. Therefore, crosslinking density and thermal stability of graphene oxide-containing polyimide foams increased. Upon the addition of 1% GO, almost seven times higher compression strength was obtained compared to neat PIFs. Also, LOI values supported the theory that thermally stable and flame retardant PIFs can be synthesized via the isocyanate-based process with GO.     

Compressive mechanical properties of sawdust/high density polyethylene composites under various strain rate loadings

This article is concerned with the static and dynamic mechanical properties of high‐density polyethylene (HDPE) reinforced with sawdust (SD) at a strain rate of up to 10³ s^?1. In this study, the static and dynamic properties of HDPE/SD composites with different filler loadings of 5, 10, 15, 20, and 30 wt% SD were deliberated at different levels of strain rates (0.001, 0.01, 0.1, 650, 900, and 1100 s^?1) using a conventional universal testing machine and the split Hopkinson pressure bar apparatus. The results showed that the stress–strain curves, yield behavior, stiffness, and strength properties of the HDPE/SD composites were strongly affected by both the strain rate and the filler loadings. Furthermore, the rate sensitivityof the HDPE/SD composites showed a great dependency on the applied strain rate, increasing as the strain rate increased. However, the thermal activation values showed a contrary trend. Meanwhile, for the postdamage analysis, the results showed that the applied strain rates influenced the deformation behavior of the tested HDPE/SD composites. Moreover, for the fractographic analysis at dynamic loading, the composites showed that all the specimens underwent a severe catastrophic deformation. J. VINYL ADDIT. TECHNOL., 24:162–173, 2018. © 2016 Society of Plastics Engineers     

Biosynthesis of the Myxobacterial Antibiotic Corallopyronin A

Corallopyronin A is a myxobacterial compound with potent antibacterial activity. Feeding experiments with labelled precursors resulted in the deduction of all biosynthetic building blocks for corallopyronin A and revealed an unusual feature of this metabolite: its biosynthesis from two chains, one solely PKS‐derived and the other NRPS/PKS‐derived. The starter molecule is believed to be carbonic acid or its monomethyl ester. The putative corallopyronin A biosynthetic gene cluster is a trans‐AT‐type mixed PKS/NRPS gene cluster, containing a β‐branching cassette. Striking features of this gene cluster are a NRPS‐like adenylation domain that is part of a PKS‐type module and is believed to be responsible for glycine incorporation, as well as split modules with individual domains occurring on different genes. It is suggested that CorB is a trans‐acting ketosynthase and it is proposed that it catalyses the Claisen condensation responsible for the interconnection of the two chains. Additionally, the stereochemistry of corallopyronin A was deduced by a combination of a modified Mosher's method and ozonolysis with subsequent chiral GC analyses.     

Controlled synthesis of copper nano/microstructures using ascorbic acid in aqueous CTAB solution

This paper describes a low-temperature green chemical synthesis of various morphologies of copper nano/microstructures. These syntheses achieved high yields in aqueous solution using ascorbic acid as a reductant and the cationic surfactant cetyltrimethylammonium bromide (CTAB) as a capping agent. The resulting copper particles were characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and UV-Vis. absorption spectroscopy techniques. From the SEM analysis, it was found that different morphologies of copper particles, including submicron polyhedrons, micrometer rods, spherical nanoparticles, and nanowires were obtained by varying factors such as the molar ratio of reactants (ascorbic acid and CuSO₄·5H₂O), pH, reaction time, and temperature. Increasing the molar ratio of ascorbic acid to precursor salt and increasing the pH led to a decrease in the size of copper particles formed. At short reaction times, spherical copper nanoparticles with an average diameter of 90 nm are obtained. When the reaction time was prolonged, the nanoparticles transformed into nanowires with diameters in the range of 100-250 nm, and lengths of up to 6-8 μm. When the reaction temperature was decreased, Cu mixed with Cu₂O particles were obtained instead of Cu particles. The resultant copper particles were confirmed by EDX and XRD to be pure Cu, with face-centred cubic (fcc) structures.     

Treatment of phenol formaldehyde production wastewater by electrooxidation-electrofenton successive processes

ABSTRACT

Treatments of phenol formaldehyde producing wastewater (PFPW) by electrooxidation (EO) and electro-Fenton (EF) successive processes were carried out in a batch electrolytic reactor using graphite (Gr) and stainless steel (Ss) electrodes. After the completion of the EO process, the wastewater was further treated with EF process. The influence of operating variables such as current density, operating time, initial pH_i and H₂O₂ concentration was evaluated for removals of phenol, TOC and COD in PFPW. Gr/Gr, Gr/Ss or Ss/Ss and Ss/Gr electrode pair were used as anode and cathode. The best removal efficiency in the EO process was obtained with Gr/Gr (93%) as compared to Gr/Ss (82%), Ss/Ss (63%) and Ss/Gr (55%). The removal efficiencies for the EO process using Gr-Gr electrode pair were obtained as 93% for phenol, 61% for COD and 44% for TOC at initial pH_i 7,5 g/L of NaCl, 50 mA/cm² and 5 h. In the EF process, the removal efficiencies at pH_i 3,5 mA/cm² and 30 mM H₂O₂ and 45 min were 100% for phenol, 76% for COD and 59% for TOC. This study provided that the successive processes are an effective method for the removal of phenolic compounds from the wastewater.     

Cathodic electrodeposition of Y(OH)3 and Y2O3 nanostructures from chloride bath. Part II: Effect of the bath temperature on the crystal structure,composition and morphology

Ultra-fine nanoparticles, mono-dispersed nanospheres and nanorods of Y(OH)₃ and Y₂O₃ were successfully prepared via electrodeposition from chloride bath at different temperatures of 10, 25, 40 and 80 °C followed by heat-treatments at 600 °C in dry air atmosphere. Thermal behavior of the hydroxide samples was investigated by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis. The structural and morphological characteristics of the products were determined by X-ray diffraction (XRD), FT-IR, scanning and transmission electron microscopy (SEM and TEM). Effects of bath temperature on the mechanism of base electrogeneration and deposit formation on the cathode surface were proposed and discussed. The results showed that the crystal structure, composition and morphology of the products are mainly affected by the temperature of electrodeposition bath.