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71.
Multimedia Tools and Applications - In the recent digitization era, image hashing is a key technology, including image recognition, authentication and manipulation detection, among many multimedia...  相似文献   
72.
Developing only Fe derived bifunctional overall water splitting electrocatalyst both for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) while performing at low onset overpotential and with high catalytic stability is a rare instance. We present here the first demonstration of unique iron-oxide nanobeads (FeOx-NBs) based electrocatalyst executing both OER and HER with high activity. Thin-film electrocatalytic FeOx-NBs assembly is surface grown via simple spray coating (SC). The unique SC/FeOx-NBs propels OER initiating water oxidation just at 1.49 VRHE (η = 260 mV) that is the lowest observable onset potential for OER on simple Fe-oxide based catalytic films reported so far. Catalyst also reveals decently high HER activity and competent overall water splitting performance in the FeOx-NBs two-electrode system as well. Catalyst also presents stable kinetics, with promising high electrochemically active surface area (ECSA) of 1765 cm2, notable Tafel slopes of just 54 mV dec1? (OER) and 85 mV dec1? (HER), high exchange current density of 1.10 mA cm2? (OER), 0.58 mA cm2? (HER) and TOF of 74.29s1?@1.58VRHE, 262s1?@1.62VRHE (OER) and 82.5s1?@-0.45VRHE, 681s1?@-0.56VRHE (HER).  相似文献   
73.
ABSTRACT

We present a theoretical model to realize the symmetric and asymmetric diffraction grating in a four-level atomic medium. The proposed atomic medium follows a double lambda configuration where four fields interact with it. We get control over symmetric and asymmetric behavior of the diffraction grating by manipulating the relative phase of the fields. Interestingly, the symmetric and asymmetric diffraction grating become prominent when the vortex beam is used instead of the plane wave. Enhanced first, second, and third-order diffraction gratings are achieved via the vortex beam. Further, we find control over asymmetric diffraction gratings by the relative phase of the fields. Coherent control of asymmetric diffraction grating in negative and positive diffracted angles is also achieved via the relative phase.  相似文献   
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This study concerns the investigation of dissipation, adsorption, and degradation of triazophos in different soils from Pakistan. These processes help in the disappearance of pesticide from the environment. Gas chromatography was used for dissipation and adsorption analysis while for degradation study mass spectrometer was used in addition of gas chromatography (GC-MS). The dissipation rate of triazophos in three different soils was 90% over 30 days with average half-life of 9.059 days. From dissipation study it was inferred that rate is variable in each soil due to climatic changes, soil nature and soil-pesticide interactions. Adsorption experiment has revealed that the adsorption of this pesticide to soil follows the pseudo first order kinetic model with rate constant value of 0.479/h and Freundlich isotherm with adsorption capacity of 1.832 mol/g. Degradation study has displayed two major metabolites, one is phosphorothioic acid, S-[2-[(1-cyano-1-methylethyl) amino]-2-oxoethyl] O,O-diethyl ester at retention time of 9.136 and the other is sulfotep at 14.304 min. The leaching potential of triazophos was also calculated from its half-life and organic carbon content present in soil which was 1.688 representing it as non leacher pesticide.  相似文献   
79.
This paper presents the use of evolutionary optimization approach to design and tune smart fuzzy controllers for heating, ventilation, and air conditioning systems or HVAC. The objective is to optimize energy consumption while accounting for user comfort requirements. The problem of energy conservation in air conditioning systems becomes a multi‐objective optimization constrained problem, which enlarges the solution search space. To solve this problem, a multi‐objective evolutionary optimization technique based on genetic algorithm (GA) is proposed. A physical experimental setup is constructed for data collection and formulation of mathematical model. A fuzzy controller is initially designed through expert knowledge, and GA is then used to tune the rules and membership functions of the fuzzy controller in order to optimize multiple objectives. Simulations and real experiments are compared to determine the effectiveness of the proposed strategy. As compared to the controller present in the real experimental air conditioner, approximately 15% energy is successfully saved with no increase in average individual dissatisfaction or discomfort index. Also, a decrease in peak individual dissatisfaction or discomfort index from 91% to 62% is observed. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
80.
In a recent paper by Zhang et al. in 2012, a Mach number-invariant scaling was proposed to account for the effect of variation of free-stream Mach number in supersonic turbulent boundary layers. The present work focuses on the effect of variation of wall temperature with strong heating and cooling at the wall. Direct numerical simulation is used to study scaling and turbulence structure of a spatially evolving Mach 2 supersonic boundary layer at a friction Reynolds number of 500. A new scaling law is proposed to account for temperature-dependent fluid-property variations. This universal scaling appears superior to the existing models with the novelty that it applies not only for the mean-velocity profile but also extends to the turbulent transport, production, and dissipation terms in the budget of the turbulent kinetic energy.  相似文献   
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