Heavy metals in maternal and cord blood

Heavy metal concentrations have been determined in maternal and cord blood samples collected from mothers in the age group 20-25 years with full-term neonates (37-40 weeks). The concentrations of Pb, Cd, Cu and Zn were found to be low in cord blood as compared to mother's blood and the ratio between cord blood and maternal blood for the respective elements was found to be approximately 0.80, 0.86, 0.47 and 0.40. On the other hand, the concentrations of Fe and Mg in the mother's blood were found to be lower than those in the cord blood. Prenatal exposure to lead in Mumbai, though low (5.1 microg/dl), is approximately 2-3 times higher than that observed in Canada or Italy. A strong correlation (r = 0.79) between the maternal and cord blood lead levels has been observed during the present study.     

Partitioning of polycyclic aromatic hydrocarbons between dissolved and particulate phases in natural waters

Quantities of polycyclic aromatic hydrocarbons (PAH), some of which are carcinogens, enter natural waters in effuents of coke production and other high-temperature industrial pyrolysis processes. Because of their low water solubilities. PAH compounds are generally considered to occur in particulate form in lakes and rivers. However, present studies of ¹⁴C-anthracene adsorption by autoclaved yeast cells indicated that significant fractions of both dissolved and particulate forms of PAH may exist in natural waters. Quantities of anthracene adsorbed exceeded values for PAH adsorption onto mineral surfaces by more than an order of magnitude: suspended organic material may thus be more important than mineral particles in adsorption of PAH compounds. Adsorption was highly dependent upon the yeast cell concentration, and varied widely through the range of suspended organic solids normally encountered in natural waters. The heat of adsorption (5.2 kcal/mole) was characteristic of a physical adsorptive process. Because ecological effects and pathways of dissolved and particulate PAH may differ, adsorptive partitioning may be important in determining PAH hazards to higher organisms in aquatic food chains, and ultimately to man.     

Trace-metal concentrations in normal human liver: methods to cope with marked variability

Concentrations of trace elements in human tissues characteristically vary widely, and the distributions of most concentrations are skewed to the right. Examination of some of the factors which contribute to the marked variability and skewness of the concentrations revealed that: (1) distributions of concentrations are satisfactorily normal (Gaussian) after logarithmic transformation, (2) ash weight is the best frame of reference in which to report results, (3) the distributions of metal concentrations are not further normalized by adjustments which assume that tissue lipid or collagen contains a fixed fraction of the metal found in the parenchyma, and (4) the choice of sample site within the liver is of minimal significance.     

Method for detecting moment connection fracture using high-frequency transients in recorded accelerations

The 1994 Northridge earthquake caused brittle fractures in steel moment frame building connections, despite causing little visible building damage in most cases. Future strong earthquakes are likely to cause similar damage to the many un-retrofitted pre-Northridge buildings in the western US and elsewhere. Without obvious permanent building deformation, costly intrusive inspections are currently the only way to determine if major fracture damage that compromises building safety has occurred. Building instrumentation has the potential to provide engineers and owners with timely information on fracture occurrence. Structural dynamics theory predicts and scale model experiments have demonstrated that sudden, large changes in structure properties caused by moment connection fractures will cause transient dynamic response. A method is proposed for detecting the building-wide level of connection fracture damage, based on observing high-frequency, fracture-induced transient dynamic responses in strong motion accelerograms. High-frequency transients are short (<1 s), sudden-onset waveforms with frequency content above 25 Hz that are visually apparent in recorded accelerations. Strong motion data and damage information from intrusive inspections collected from 24 sparsely instrumented buildings following the 1994 Northridge earthquake are used to evaluate the proposed method. The method’s overall success rate for this data set is 67%, but this rate varies significantly with damage level. The method performs reasonably well in detecting significant fracture damage and in identifying cases with no damage, but fails in cases with few fractures. Combining the method with other damage indicators and removing records with excessive noise improves the ability to detect the level of damage.     

In situ dialysis for the determination of the state of trace elements in natural waters

A new method is described which enables determination of the concentration of truly dissolved forms of trace elements in natural waters without substantial influence of adsorption on the walls of apparatus and vessels. The method also simplifies further analysis of the ionic and molecular forms of trace elements. It consists in immersing a dialysis bag, filled with pure water, directly into the natural water in situ and allowing the dialysis and adsorption equilibriu to be established. Conditions for the use of this method are discussed and results of the determination of the dissolved fraction of 20 elements in river water, as compared with the results by filtration and ultrafiltration are presented. Neutron activation analysis was used for the elemental determinations.     

Development of passive viscoelastic damper to attenuate excessive floor vibrations

Recent changes in the construction of building floors have included the use of light material composite systems and long span floor systems. Although these changes have many advantages, such floor systems can suffer from excessive vibration due to human activities. This problem is exacerbated in office buildings due to the reduction in inherent damping associated with modern fit outs. Excessive floor vibrations are often realised after the completion of construction or following structural modifications and normally arise due to inadequate knowledge of the damping values in the design process. Thus rectification measures are normally required to reduce floor accelerations. This paper proposes a new innovative passive viscoelastic damper to reduce floor vibrations. This damper can be easily tuned to the fundamental frequency of the floor and can be designed to achieve various damping values. The paper discusses the analytical development of the damper with experimental results presented on a prototype to demonstrate its effectiveness.     

Seismic methods for study of soil building properties

Bulletin of Engineering Geology and the Environment - Information about distribution of elastic wave propagation velocities Vp, Vs in the subsurface zone of a soil mass can be obtained rapidly and...     

Long-term geophysical observations on the inguri dam rock foundation

Bulletin of Engineering Geology and the Environment - It has been found that during construction of the dam, prior to the filling of the reservoir, compaction and loading of the rocks under the...     

Combined nitrification/denitrification in a membrane reactor

An ever stricter legislation regulating wastewater leads to an increasing demand for biological treatment plants which are able to selectively eliminate nitrogen from wastewaters with a high influent concentration, even when operating in partial influent mode. A membrane-tube-module (MSM) reactor (Membran-Schlauch-Modul-Reaktor) was constructed and realized in the IUV at the University of Bremen. The present approach makes use of all the various layers of the whole biofilm, enabling nitrification and denitrification processes to run simultaneously in one and the same biofilm under optimized conditions. The biological degradation capacity of the system was first successfully tested with synthetic wastewater, and subsequently in a real application with effluents from a recycling of animal carcasses plant and from a coke-oven plant. A mathematical model was devised which describes this biofilm system. The resulting equations were solved by means of the simulation software AQUASIM.     

The bacterial population of piggery-waste anaerobic digesters

A survey was made of the anaerobic and facultatively anaerobic bacteria present in piggery waste, digesting piggery waste and domestic anaerobic sludge sludge used to start a piggery waste digester. An influence of the input waste was shown in that streptococci, the predominant facultatively anaerobic bacteria in the piggery waste, were the predominant bacteria in the digesting waste, and they replaced Enterobacter, predominant in the domestic sludge, when a piggery waste digestion had been established from this latter material. Cellulolytic or methanogenic bacteria could not be detected in the piggery waste but populations of these, and other hydrolytic bacteria, became established at different times during the buildup of digestion by gradual addition of piggery waste to water. The bacteria concerned in degradation of the waste constituents were all anaerobes.Production of methane from H₂/CO₂, formate and butyrate could be detected in mixed cultures from dilutions of digester contents, but the only methanogenic bacterium that could be isolated in pure culture was Methanobacterium formicicum, which uses H₂/CO₂ or formate only.