YAG：Ce Phosphors for WLED via Nano-Pesudoboehmite Sol-Gel Route

The sub-micron sized YAG ： Ce phosphors were synthesized via a modified sol-gel method by peptizing nano-pesudoboehmite particulate. It is found that YAG phase from the dried gel powders appears at 1000 ℃ then the pure YAG phase exists at a relatively lower sintering temperature of 1400 ℃. The smaller sizes of phosphors in the ranges of 1 - 3 μm are obtained due to the contribution of seeding effects of nano-sized alumina particles to strengthen each step of the processes. Both the excitation and emission spectra of photoluminescence of the phosphor obtained at 1400 ℃ meet well with the spectroscopic requirements of the WLED phosphors.     

Flammability and thermal stability studies of ABS/Montmorillonite nanocomposite

Acrylonitrile–butadiene–styrene (ABS)/montmorillonite nanocomposites have been prepared using a direct melt intercalation technique by blending ABS and organophilic clay of two different particle sizes: OMTa (5 µm) and OMTb (38 µm). Their structure and flammability properties were characterized by X‐ray diffraction, high resolution electronic microscopy (HREM), thermogravimetric analysis (TGA) and cone calorimeter experiments. The results of HREM showed that ABS/5 wt% OMTa nanocomposite was a kind of intercalated–delaminated structure, while ABS/5 wt% OMTb nanocomposite was mainly an intercalated structure. The nanocomposites showed a lower heat release rate peak and higher thermal stability than the original ABS by TGA and cone calorimeter experiments. Also, the intercalated nanocomposite was more effective than an exfoliated–intercalated nanocomposite in fire retardancy. Copyright © 2003 Society of Chemical Industry     

STRUCTURE REPRESENTATION OF THE SPECIFIC FRACTIONS FROM PINGSHUO COAL

Basic data of four fractions, PM₁, PM₆, PM₇and PM₈, derived from Pingshuo bituminous coal were obtained by ultimate analyses, mean molecular weight measure, GC/MS, ¹³C-NM R, ¹H-NM R and FTIR technigues. A method of calculating the average molecular parameters of the fractions is introduced. Based on the calculated parameters, the molecular structure models of the fractions of PM₆, PM;and PM₈are constructed. Significant structural information about the saturated hydrocarbon and aromatic hydrocarbon with heteroatom groups is given also.     

渤中28－1（BZ28－1）油田N6H水平井动态分析

本文以渤中２８－１（ＢＺ２８－１）油田Ｎ６Ｈ水平井为例，从多方面对该井的动态和产能变化进行了系统分析，所用的方法对水平井动态分析有一定的指导意义。     

微机模拟处理pH络合滴定法研究——Ⅱ.终点确定方法和最佳实验条件模拟估计程序

本文利用简便的滴定过程模型,确立了微机模拟处理实验数据,方便、准确地求解络合滴定等当点的方法。设计了最佳实验条件模拟估计程序。该法测定Zn~(2+),Pb~(2+),Cu~(2+),Fe~(3+)结果的相对误差Δ<1％。pH=6-7时,测定Ca~(2+)的相对误差为-1.61％;σ<0.001mmol,(N=5)。     

Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor

Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors with long afterglow were synthesized by solid state reaction route. The photoluminescence spectra, decay curves, thermoluminescent spectra and chromaticity coordinate curves were investigated. The results show that the luminescence intensity of Y1.94-xMgxO2S:0.06Ti (0≤x≤0.10) phosphors decrease gradually with increasing Mg2 ion content, and the shape of luminescence spectra and chromaticity coordinate change as well. Furthermore, two thermoluminescent peaks in single Ti-doped Y2O2S sample are found at 91.8 and 221.5 ℃, respectively. Nevertheless, significant different spectra were found for the Mg, Ti co-doped Y2O2S samples that three thermoluminescence peaks appear at 52.3, 141.7 and 226.8 ℃, respectively. These results indicate that the co-doped Mg ion changes the inherent trap depth of single Ti-doped Y2O2S:Ti phosphor, and induces simultaneously a new trap level in the Y1.94-xMgxO2S:0.06Ti phosphor. Based on the analysis of thermoluminescent spectra, photoluminescent spectra, decay curve and crystal structure defect, it was proposed that the varied structure defect and introduced new trap level by the doped Mg2 ions should be responsible for reducing luminescence intensity and varying color in the Y1.94-xMgxO2S:0.06Ti phosphor.     

有机介质中合成二硫化钛

本文研究了硫化氢与四氯化钛在某些有机介质中的反应，并提出了一个合成二硫化钛的新方法。该法是将干燥的硫化氢通入沸腾的四氯化铁的α－氯代萘溶液中，使硫化氢和四氯化钛发生复分解反应而生成二硫化钛。方法简便易行。Ｘ－射线物相鉴定及化学分析结果表明，产物为单一物相的、符合化学计量的二硫化钛。     

坑道用水下堵漏剂的研制

坑道水下堵漏剂的研制包括F－1、F－2和F－3型。其中F－1是一种有机堵漏剂，它可以在水中固化；F－2是一种无机防水堵漏剂，施工方便；F－3是速凝型，它可在瞬间固化，能对坑道的涌水口进行堵漏。     

On the Cutoff Wavelength of Rectangular-Shaped Microshield Line by Edge Element Method

In this paper, the cutoff characteristic of rectangular-shaped microshield transmission line has been analysed by edge element method. Dependence of cutoff wavelengths on the thickness of metallic signal strip, dielectric constant of dielectric substrate and the width of the rectangular-shaped ground conductor are presented in tabular form. Numerical results in this paper have important values in design of rectangular-shaped microshield lines in microwave and millimeter wave integrated circuits.     

Thermo-acoustic instability in the horizontal Rijke tube

The instability curve of a Rijke tube system was obtained accurately by following different paths of heat power and flow-rate for three regions and by defining its locus from the criterion based on the measured sound pressure levels. The unstable limits in the region of flow-rate lower than that at the minimal power are compared with previous data. To observe the effect of turbulence on the unstable limits, inflow turbulence was introduced by placing a bundle of circular cylinders upstream of the heating part (50< Re_d< 700). The large-amplitude inflow fluctuation may delay the transition of the chamber acoustic mode to the unstable zone even at a sufficient power.