New approach to avoid erroneous interpretation of results derived from generalized two-dimensional correlation analysis for applications in catalysis

Surface characterization and catalysis can significantly benefit from the application of generalized two-dimensional (2D) correlation analysis. This two-dimensional approach allows a better resolution of overlapping peaks, can reveal new features not readily observable in the raw spectra, gives clear evidence for spectral intensities that change as an effect of a perturbation applied to the system, and allows the establishment of time sequences for the changes occurring in different spectral features of interest for determining reaction intermediates and/or mechanisms. The interpretation of the synchronous and asynchronous plots was observed to lead to erroneous time sequences when spectral features change in a non-monotonic way, such as a biphasic or oscillatory behavior, under the influence of a perturbation. We propose a new approach to the 2D correlation analysis to avoid misinterpretation of the results calculated in the asynchronous plot. Progressive correlation analysis (ProCorA) calculates the synchronous plot from the first two spectra of the data matrix and one spectrum is added at every step of the analysis. The sequence of changes can be set up from the progressive evolution of peaks in both the synchronous and asynchronous plots.     

Investigating the wear characteristics of engineered surfaces: low-temperature plasma nitriding and TiN + MoS x hard-solid lubricant coating

Significant progress has been made in the past decade in plasma nitriding with a majority of the research work focusing on improving hardness and wear resistance of the nitrided surface through the reduction of nitriding temperature, pressure or time. Hard-solid lubricating coatings have also been extensively studied for lowering the wear rate and coefficient of friction of traditional hard coatings such as TiN by the combined effect of hardness and solid lubrication. In this study, the wear characteristics of low-temperature plasma-nitrided steel substrate performed using a Saddle-field fast atom beam source and TiN + MoS _x hard-solid lubricant coating deposited by a closed-field magnetron-sputtering technique have been investigated. The thin hard layer in plasma-nitrided substrates exhibited much higher hardness and lower wear compared to the untreated substrate in pin-on-disc wear testing. In addition, the study of the wear track morphology of the nitrided samples evidenced significant reduction of deeper ploughing and plastic deformation due to higher hardness and load supporting of the nitrided layer. On the other hand, due to the incorporation of MoS₂ in TiN coating, the wear resistance and coefficient of friction were greatly improved in TiN + MoS _x coating compared to pure TiN coating. In contrast to TiN coating, a relatively smoother wear track with less abrasive wear also supported the beneficial effects of adding MoS₂ in TiN coating.     

Efficient driving-capability programmable frequency divider with a wide division ratio range

A programmable frequency divider with close-to-50% output duty-cycle, with a wide division ratio range, is presented. The proposed divider has also provisions for binary division ratio controls, and has demonstrated operation at frequencies as high as 3.5 GHz. With the above features, the proposed divider can be used in phase-locked loops, and is capable of driving various clocked circuits, which need different clock frequencies. The proposed divider has division ratios from 8 to 510, but it can easily be extended to higher ranges by simply adding more divider stages. The divider circuit has been realised in a 0.18-mum RF CMOS process. Test results show that the output duty-cycle is 50% when the division ratio is an even number. For odd division ratios the worst-case duty-cycle is 44.4% when the division ratio is 9. The output duty-cycle becomes closer to 50% when the division ratio is an increasing odd number. For each division ratio, the output duty-cycle remains constant for different chips, with different input frequencies from gigahertz down to kilohertz ranges, and with different power supply voltages.     

Keyboard design through physiological strain measurements

The physiologically tolerable range of positions for the joints of the upper extremities have been investigated for typing tasks by recording the myoelectric activities of the involved muscles. For long-term typing tasks a split keyboard is recommended allocating a key field to each hand. The fields should be rotated against each other in the horizontal plane and inclined laterally.     

Geometrical approach of planar hyper-redundant manipulators: Inverse kinematics,path planning and workspace

A new method for inverse kinematics for hyper-redundant manipulators is proposed in this paper to plan the path of the end-effector. The basic idea is that for a given smooth path consisting of points close enough to each other; computing the inverse kinematics for these points is carried out geometrically using the proposed method. In this method, the angles between the adjacent links are set to be the same, which makes lining up of two or more joint axes impossible; therefore, avoiding singularities. The manipulability index has been used to show how far the manipulator from the singularity configuration is. The determination of the workspace of the manipulator using the proposed method has been presented in this paper. The simulation results have been carried out on a planar and a three dimensional manipulators. The effectiveness of the proposed method is clearly demonstrated by comparing its result with results calculated by the well-known method of measuring manipulability which is used for singularity avoidance for the last two decades.     

Malicious insiders attack in IoT based Multi-Cloud e-Healthcare environment: <Emphasis Type="Italic">A Systematic Literature Review</Emphasis>

The emergence of Internet of Things (IoT) has introduced smart objects as the fundamental building blocks for developing a smart cyber-physical universal environment. The IoTs have innumerable daily life applications. The healthcare industry particularly has been benefited due to the provision of ubiquitous health monitoring, emergency response services, electronic medical billing, etc. Since IoT devices possess limited storage and processing power, therefore these intelligent objects are unable to efficiently provide the e-health facilities, or process and store enormous amount of collected data. IoTs are merged with Cloud Computing technology in Multi-Cloud form that basically helps cover the limitations of IoTs by offering a secure and on-demand shared pool of resources i.e., networks, servers, storage, applications, etc., to deliver effective and well-organized e-health amenities. Although the framework based on the integration of IoT and Multi-Cloud is contributing towards better patient care, yet on the contrary, it is challenging the privacy and reliability of the patients’ information. The purpose of this systematic literature review is to identify the top security threat and to evaluate the existing security techniques used to combat this attack and their applicability in IoT and Multi-Cloud based e-Healthcare environment.