New Type Anode for Calcium Ion Batteries Based on Silicon Carbide Monolayer

Silicon - A theoretical research study was conducted into the possibility of using a two-dimensional graphene-like material silicon carbide nano-sheet (2D-SiCNS) as an anode in rechargeable Ca-ion...     

Energy and peak-current per-cycle estimation at RTL

We present novel macromodeling techniques for estimating the energy dissipated and peak-current drawn in a logic circuit for every input vector pair (we call this the energy-per-cycle and peak-current-per-cycle, respectively). The macromodels are based on classifying the input vector pairs on the basis of their Hamming distances and using a different equation-based macromodel for every Hamming distance. The variables of our macromodel are the zero-delay transition counts at three logic levels inside the circuit. We present an automatic characterization process by which such macromodels can be constructed. The energy-per-cycle macromodel provides a transient energy waveform, and can also be used to estimate the moving average energy over any time window, whereas peak-current-per-cycle macromodel provides peak-current which can be used for studying IR drop problems. Some key features of this technique are: 1) the models are compact (linear in the number of inputs); 2) they can be used for any input sequence; and 3) the characterization is automatic and requires no user intervention. These approaches have been implemented and models have been built and tested for many circuits. The average errors observed in estimating the energy-per-cycle and peak-current-per-cycle are under 20%. The energy-per-cycle model can also be used to measure the long-term average power, with an observed error of under 10% on average.     

Primary repair is superior to initial palliation in children with atrioventricular septal defect and tetralogy of Fallot

OBJECTIVE:The objective was to explore the best management algorithm for atrioventricular septal defect in conjunction with tetralogy of Fallot. METHODS: We reviewed the cases of 38 children referred to our division (March 1981-August 1997) who had atrioventricular septal defect associated with tetralogy of Fallot; 32 (84%) had Down syndrome. Twenty-one received initial palliation with a systemic-to-pulmonary artery shunt; of these, 2 (9.5%) died before complete repair. Thirty-one children underwent complete repair; 14 of these (45%) had undergone initial palliation (mean age at shunt 20 +/- 24 months). Right ventricular outflow obstruction was relieved by a transannular patch in 22 (71%); 14 (64% of 22) had a monocuspid valve inserted. Four required an infundibular patch. RESULTS: Two children (6.4%) died early after repair; 1 had undergone previous palliation. Patients with palliation underwent repair at an older age (78 vs 36 months), required longer ventilatory support (8 vs 4 days) and inotropic support (8 vs 4 days), and had longer intensive care stays (11 vs 6 days) and hospital stays (24 vs 15 days). Eleven children (35%) underwent reoperation, 7 (58%) for right ventricular outflow reconstruction and pulmonary arterioplasty. Reoperation was more frequent in the palliation group than in the primary operation group (64% vs 12%). The single late death was related to a reoperation in the palliation group. CONCLUSIONS: Atrioventricular septal defect with tetralogy of Fallot can be repaired with a low mortality rate. Initial palliation with a shunt resulted in a more complex postoperative course and a higher reoperative rate. Primary repair is superior to initial palliation with later repair.     

Estimating power dissipation in VLSI circuits

With the shift to low power IC design for personal computing and communication applications, designers' priorities turn to accurate and efficient estimation of power consumption in ICs. Traditional current and power estimation techniques based on a SPICE-like simulation do not provide the necessary efficiency for such an application, and thus new approaches have been recently proposed. In this, the first of a series of articles that reflect the new orientation of this column, Professor Farid Najm of the University of Illinois at Urbana-Champaign presents an overview of different techniques for estimating power consumption in large-scale IC designs. He also discusses computer aided design tools to help in the task     

Impact of bismuth oxide on the structure,optical features and ligand field parameters of borosilicate glasses doped with nickel oxide

Understanding the impact of bismuth cations on the optical properties of borosilicate glass is significant for manipulating borate glass applications. In this paper, the influence of bismuth cations on both structural and optical properties of borosilicate glass doped with NiO was investigated. Different glass samples, containing different amounts of Bi₂O₃ and a constant amount of NiO, were prepared and studied. Infrared (IR) analysis was carried out to study the internal structure within the investigated glass samples. Optical absorption studies were performed to investigate the impact of Bi₂O₃ content on optical properties of the BiBaNiB-glasses. Astonishingly, with Bi₂O₃ addition, an absorption band at 380 nm has appeared. Moreover, this band is overlapped with the Urbach edge; which regularly produced an artificial edge-like feature at ~450 nm. A detailed deconvolution protocol has been implemented for an appropriate understanding of these spectra and unraveling the hidden Urbach edge. Optical band gap energy, linear and nonlinear refractive index for each BiBaNiB sample were calculated. Furthermore, the metallization criterion was calculated to examine the metallic or insulating nature of the BiBaNiB-glasses. The values of the nonlinear third-order susceptibility and nonlinear refractive index were increased with Bi₂O₃ doping. The BiBaNiB-glasses exhibited outstanding stability and optical band gap than the pristine glass sample, which makes it possible for practical applications.     

Synthesis,characterization and adsorption studies of h-BN crystal for efficient removal of Cd2+ from aqueous solution

In the present study, hexagonal boron nitride (h-BN) was synthesized from boric acid and melamine by thermal annealing method in a nitrogen atmosphere. The pure h-BN was used as an efficient sorbent for the uptake of Cd²⁺ ions from the solution phase. The kinetics and sorption studies of metal ions onto the h-BN were carried out in batch adsorption experiments at different temperature, time, pH, sorbent dosage, and concentration of metal ions. The optimum pH for the removal of the Cd²⁺ ions was found to be pH 7. The effect of temperature showed that the process of Cd²⁺ sorption remained endothermic in the range of 298 K–328 K. The Lagergren's first and Ho's second kinetic models were tested to interpret the adsorption kinetic data, however the present data was explained well by Ho's model for kinetics. The thermodynamic perameters ΔG, ΔS and ΔH were determined using the available adsorption data at different temperatures. The physicochemical properties of the synthesized product were also characterized before and after adsorption by different analytical techniques like FT-IR, TGA, XRD and Point of Zero Charge (PZC). The morphology of the surface was analyzed with the help of Scanning Electron Microscopy. The h-BN proved to be an efficient adsorbent for the uptake of the Cd²⁺ ions from aqueous media.     

H∞ filtering of discrete-time interconnected systems with failed interconnections

The H_∞ filtering problem for interconnected systems is addressed in this paper. In order to facilitate the stability analysis of interconnected systems under the conditions of failed interconnections, a strategy related to switched systems is introduced. Assume that the interconnections among these subsystems disconnect based on the mode-dependent average dwell time (MDADT), a switching signal is implemented to denote the failed interconnections cases. In the aid of the MDADT method, a filter is designed such that the fault detection (FD) system is asymptotically stable and satisfies the weighted H_∞ performance. Finally, a numerical simulation is provided to show the effectiveness of the proposed filter.     

Nonmonotonic Coupled Dissolution-Precipitation Reactions at the Mineral–Water Interface

Dissolution is inherent to fluid-mineral systems. Yet its impact on minerals reacting with electrolytes is overlooked. Here, a novel nonmonotonic behavior for the surface interactions of carbonates (calcite and Mg-calcite) with organic acids is reported. Applying a bioinspired approach, Mg-calcite sensors via amorphous precursors, avoiding any preconditioning with functional groups are synthesized. A quartz crystal microbalance is used to study the mass changes of the mineral on contact with organic acids under varying ionic conditions, temperatures, and flow velocities. Supported by confocal Raman microscopy and potentiometric titrations, nonmonotonous mass developments are found as a function of Ca²⁺ concentration and flowrate, and attributed to three coupled chemical reactions: i) carbonate dissolution via Ca²⁺ ion complexation with organic molecules, and the formation of organo-calcium compounds as ii) a surface phase at the mineral–water interface, and iii) particles in the bulk fluid. These processes depend on local ion contents and the precipitation onset (i.e., saturation index) of organo-calcium salts, both of which substantially differ in the bulk fluid and in the fluid boundary layer at mineral interfaces. This continuum between dissolution and precipitation provides a conceptual framework to address reactions at mineral interfacial across disciplines including biomineralization, ocean acidification and reservoir geochemistry.     

Synergy of climate change and local pressures on saltwater intrusion in coastal urban areas: effective adaptation for policy planning

ABSTRACT

This article examines the relative impacts of anthropogenic interventions and global climate change on the dynamics of saltwater intrusion in highly urbanized coastal aquifers. For this purpose, simulations of the impacts of sea-level rise and abstraction scenarios for the near future were undertaken for a pilot aquifer using a multi-objective 3D variable-density flow and solute transport model. We find that sea-level rise associated with climate change has less influence on the encroachment of salinity than anthropogenic abstraction, which has a more appreciable impact on saltwater intrusion through greater sensitivity to water consumption and seasonality.