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31.
We undertook numerical and experimental studies to develop a better incineration method for the destruction of CC14. A phenomenological model for the turbulent reaction of CC14, including a flame inhibition feature, has been successfully incorporated into a commercial code, simulating the incineration
processes of this compound. The gaseous flow solution was obtained using SIMPLEST, a derivative of Patankar’s SIMPLE algorithm,
with a k-ε turbulence model. A modified fast chemistry turbulent reaction model was developed to describe the flame inhibition
due to the presence of CC14, considering the corresponding burning velocity data of these mixtures. An experiment was carried out on a 5.2 kW laboratory
scale, transportable, cavity-type incinerator, which warrants a sufficient residence time and effective turbulent mixing by
the formation of a strong recirculation region in a combustor. To this end, the specific configuration of the incinerator
was manufactured to consist of two opposing jets and a rearward facing step. The calculated data were in close agreement with
the experimental data for the concentrations of major species, such as CCI4 and HCl, together with the temperature profiles. The experimental test gave the desired DRE of above 99.99%. 相似文献
32.
Ten selected samples with varying types and amounts of organic matter from two Miocene lacustrine basins in northwestern Turkey were analyzed by programmed-temperature open-system pyrolysis to determine methane generation potential and reaction kinetics. Open-system pyrolysis was performed at heating rates 0.1, 0.7 and 5.0 K/min, where generated gases were measured using an on-line gas chromatograph. Frequency factors and activation energy distributions of reaction kinetics for methane generation from the investigated lacustrine coals and sedimentary rocks indicated that type of kerogen controls the sequential order of methane generation. Methane from Type-III kerogen is generated at lower temperatures, which will be followed by methane from Type-II and Type-I kerogen. Methane generation potentials in the range 14-35 mg CH4/g TOC correlates also with type of organic matter. For Type-III kerogen up to 28% of the total hydrocarbon generation potential belongs to methane. The respective value is only 2% for a Type-I kerogen. 相似文献
33.
N‐(2‐hydroxy)propyl‐3‐trimethylammonium chitosan chloride (HTCC), a water‐soluble chitosan quaternary ammonium derivative, was used as an antimicrobial agent for cotton fabrics. HTCC has a lower minimum inhibition concentration (MIC) against Staphylococcus aureus, Klebsiella pneumoniae, and Escherichia coli compared to that of chitosan; however, the imparted antimicrobial activity is lost on laundering. Thus crosslinking agents were utilized to obtain a durable antimicrobial treatment by immobilizing HTCC. Several crosslinkers such as dimethyloldihydroxyethylene urea (DMDHEU), butanetetracarboxylic acid (BTCA), and citric acid (CA) were used with HTCC to improve the laundering durability of HTCC treatment by covalent bond formation between the crosslinker, HTCC and cellulose. The polycarboxylic acid treatment was superior to the DMDHEU treatment in terms of prolonged antimicrobial activity of the treated cotton after successive laundering. Also, the cotton treated with HTCC and BTCA showed improved durable press properties without excessive deterioration in mechanical strength or whiteness when compared to the citric acid treatment. With the addition of only 0.1% HTCC to BTCA solutions, the treated fabrics showed durable antimicrobial activity up to 20 laundering cycles. The wrinkle recovery angle and strength retention of the treated fabrics were not adversely affected with the addition of HTCC. Therefore, BTCA can be used with HTCC in one bath to impart durability of antimicrobial activity along with durable press properties to cotton fabric. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1567–1572, 2003 相似文献
34.
Woo Gi Lee Jin Suk Lee Byung Geon Park Mi Sun Kim Soon Chul Park Ho Nam Chang 《Korean Journal of Chemical Engineering》1996,13(5):453-456
Chemostat and total cell retention cultures with internal filter system ofSaecharomyc.es cerevisiae H1-7 were carried out to produce ethanol from wood hydrolysate. Maximum ethanol productivity obtained in a chemostat with
the aeration rate of 1 vvm was 3.79 g/(L·h). This was 20% higher than that in a chemostat without aeration. However, the substrate
was not completely consumed at the dilution rate with the maximum productivity. The realistic productivity, which has higher
than 99% conversion rate of substrate, was. 2.95 g/(L·h). The maximum productivity in the total cell retention culture was
6.65 g/(L·h) at the dilution rate of 0.19 h1 and the residual glucose concentration was negligible. 相似文献
35.
Seong Ik Yoo Tae Yeon Lee Jin‐San Yoon Ik‐Mo Lee Mal‐Nam Kim Han Sup Lee 《应用聚合物科学杂志》2002,83(4):767-776
The interfacial reaction of the polyethylene (PE)/starch blend system containing the reactive compatibilizer maleated polyethylene (m‐PE) was directly characterized by Fourier transform infrared (FTIR) spectroscopy. A significant amount of anhydride groups on m‐PE existed as hydrolyzed forms, resulting in a large amount of carboxyl groups. Using a vacuum‐heating‐cell designed in the laboratory, the carboxyl groups were successfully transformed into the dehydrolyzed state (i.e., anhydride group). This result enabled the direct spectroscopic observation of chemical reaction occurring at the interface. For the PE/starch blend system containing m‐PE, the chemical reaction at the interface was verified by the evolution of ester and carboxyl groups in the FTIR spectra. The effect of the reactive compatibilizer on the interfacial morphology was also examined by scanning electron micrography (SEM). Enhanced interfacial adhesion was clearly observed for the blend system containing reactive compatibilizer. Tensile strengths of blend systems containing m‐PE also increased noticeably compared with the corresponding system without compatibilizer. A similar observation was made for the breaking elongation data. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 767–776, 2002 相似文献
36.
Seong-Joong Kim Yeojin Ahn Jeong F. Kim Seung-Eun Nam Hosik Park Young Hoon Cho Kyung-youl Baek You-In Park 《应用聚合物科学杂志》2021,138(7):49860
To overcome the plasticization effect in polyimide membranes, many researchers have proposed crosslinking method. This can reduce an inter-segmental mobility by tightening and rigidifying the polymer chains. However, it is difficult to modify the whole polymer chains throughout the membrane because the reaction can be hindered by the diffusion rate of the crosslinker. In particular, it is hard for bulky crosslinker to penetrate a dense membrane with a small d-spacing. This study investigated the effect of crosslinking a dense Matrimid membrane with p-phenylenediamine (p-PDA) via two different crosslinking methods (i.e., methanol-swelling crosslinking process [M-SCP] and liquid-phase crosslinking process [L-PCP]). Most of the crosslinking reaction in M-SCP occurs on the membrane surface due to difficulty in penetration of the bulky p-PDA into the Matrimid dense membrane. In contrast, the L-PCP allows uniform crosslinking across the membrane. The membranes crosslinked using L-PCP showed excellent chemical resistance. Furthermore, the plasticization phenomenon was not observed in the membranes crosslinked using L-PCP with p-PDA more than 15%. Meanwhile, the membrane crosslinked using M-SCP exhibited poor plasticization and chemical resistance properties. These results showed that the L-PCP method can be more effective for the crosslinking of dense membrane to deliver both high plasticization and chemical resistance. 相似文献
37.
Shi Hyoung Ryu Hae Sung Lee Chong Nam Chu 《International Journal of Machine Tools and Manufacture》2003,43(14):2177
In this research, an effective method for the form error prediction in side wall machining with a flat end mill is suggested. The form error is predicted directly from the tool deflection without surface generation by cutting edge locus with time simulation. The developed model can predict the surface form error accurately about 300 times faster than the previous method. Cutting forces and tool deflection are calculated considering tool geometry, tool setting error and machine tool stiffness. The characteristics and the difference of generated surface shape in up milling and down milling are discussed. The usefulness of the presented method is verified from a set of experiments under various cutting conditions generally used in die and mold manufacturing. This study contributes to real time surface shape estimation and cutting process planning for the improvement of form accuracy. 相似文献
38.
Yunyoung Nam 《Multimedia Tools and Applications》2016,75(12):7003-7028
Abandoned and stolen object detection is a challenging task due to occlusion, changes in lighting, large perspective distortion, and the similarity in appearance of different people. This paper presents real-time detection methods of abandoned and stolen objects in a complex video. The adaptive background modeling method is applied to stable tracking and the ghost image removing. To detect abandoned and stolen objects, the methods determine spatio-temporal relationship between moving people and suspicious drops. The space first detection method measures the distance between a moving object and a non-moving object in spatial change analysis. The time first detection method conducts temporal change analysis and then spatial change analysis. The potential abandoned object is classified as a definite abandoned or stolen object by two-level detection approach. The time-to-live timer is applied by adjusting several key parameters on each camera and environment. In experiments, we show the experimental results to evaluate our proposed methods using benchmark datasets. 相似文献
39.
Youn‐Gyoung Chang Seong‐Hee Nam Nam‐Kook Kim Yun‐Ho Kook Jinook Kim Soon‐Sung Yoo Chang‐Dong Kim In‐Byeong Kang In‐Jae Chung 《Journal of the Society for Information Display》2009,17(4):301-307
Abstract— Recently, potential breakthrough technologies for low‐cost processing of TFT‐LCDs and new process developments for flexible‐display fabrication have been widely studied. A roll‐printing process using etch‐resist material as a replacement for photolithographic patterning was investigated. The characterization of the properties of patterns formed in roll printing, a method to fabricate cliché plates for fine patterns, and the design of a new formulation for resist printing ink is reported. The pattern position accuracy, which is one of the most important issues for the successful application of printing processes in display manufacturing was studied and how it can be improved by optimizing the blanket roll structure is explained. New design rules for the layout of the thin‐film‐transistor array was derived to improve the compatibility of roll printing. As a result, a prototype 15‐in.‐XGA TFT‐LCD panel was fabricated by using printing processes to replace all the photolithographic patterning steps conventionally used. 相似文献
40.
Bong Hyun You Byoung Jun Lee Sang Youn Han Seiki Takahashi Brian H. Berkeley Nam Deog Kim Sang Soo Kim 《Journal of the Society for Information Display》2009,17(2):87-94
Abstract— A touch‐screen‐panel (TSP) embedded 12.1‐in. LCD employing a standard existing a‐Si:H TFT‐LCD process has been successfully developed. Compared with conventional external touch‐screen panels, which use additional components to detect touch events, the new internal TSP exhibits a clearer image and improved touch feeling, as well as increased sensing speed using discrete sensing lines to enable higher‐speed sensing functions including handwriting. The new internal digital switching TSP can be fabricated with low cost because it does not require any additional process steps compared to a standard a‐Si:H TFT‐LCD. 相似文献