Surface properties of magnesium oxide obtained from basic magnesium carbonate: Influence of preparation conditions of magnesium carbonate

Surface area, total basicity and base strength distribution (weak, strong and intermediate strength basic sites) of magnesium oxide obtained from basic magnesium carbonate (by its decomposition at 873 K) prepared by precipitation using different magnesium slats, precipitating agents and precipitating conditions (viz. concentration of magnesium salt. pH, temperature, mode of mixing and ageing period) have been thoroughly investigated. The total basicity and base strength distribution of the different magnesium oxide samples have been determined by step-wise thermal desorption of carbon dioxide from 323 to 1253 K. The chemical composition of basic magnesium carbonate and the surface properties and carbon dioxide content of magnesium oxide are found to be strongly influenced by the aforementioned preparation conditions of basic magnesium carbonate.     

Self-created Rules and Conflict Management Processes: The Case of Water Users' Associations on Waghad Canal in Maharashtra,India

In India, community participation is receiving much importance in water planning and management. However, in the absence of effective institutional arrangements to govern the allocation and maintenance activities, it is more likely that such participation will fail to achieve the desired results. Therefore, the present study is an attempt to assess the self-created rules adopted by two Water Users' Associations (WUAs) in Maharashtra State, India, to govern the use and distribution of water resources. The paper describes the perception of the members with regard to some of these self-created rules. It was observed that both the WUAs studied had effectively enforced these rules, leading to improved water management and efficient conflict management process. Although preliminary, the findings indicate scope for designing strategies to achieve the objective of forming a federation — better planning and distribution of water among WUAs.     

An Experimental and Theoretical Study of the Flow of Xerographic Developer Powders from Small Hoppers

An experimental and theoretical study is presented which characterizes the flow of xerographic developer powders out of small hoppers. A small hopper in this reference is defined as one having a maximum height of 12 in. Two walls of the hopper converge at the gate and the remaining two walls are parallel to each other. The flow is studied as a function of the gate opening, hopper angle, particle size, the total height of the particulate material in the hopper, and the angle of repose. Experimental results are presented for particle diameters between 100 ? and 600 ?. A theory is presented to predict flow rates. The predicted functional dependence agrees very well with the observations. The predicted flow rates are about 3.75 times higher than the observed ones. It is suggested that this is due to a resistive force originating in particle interactions. Inclusion of this correction factor in the theory results in very good agreement between theoretical predictions and experimental observations.     

Alternate Testing of RF Transceivers Using Optimized Test Stimulus for Accurate Prediction of System Specifications

In the recent past, with the emergence of System-on-Chip (SoC), focus has shifted towards testing system specifications rather than device or module specifications. While the problem of test accessibility for test stimulus application and response capture for such high-speed systems remains a challenge to the test engineers, new test strategies are needed which can address the problem in a practical manner. In this paper, the problem of testing the transmitter and the receiver subsystems of a RF transceiver for system level specification is addressed. Instead of using different conventional test stimuli for testing each of the system level specifications of RF subsystems, a specially crafted test stimulus is used for testing all the specifications from the response of the subsystem-under-test. A new simulation approach has also been developed to perform fast behavioral simulations in frequency domain for the system-under-test. In the test method, frequency domain test response spectra are captured and non-linear regression models are constructed to map the spectral measurements onto the specifications of interest. In the presented simulation results, the test stimuli have been validated using netlist level simulation of the subsystem-under-test and specifications have been predicted within an error of ±3% of the actual value.Soumendu Bhattacharya was born in Calcutta, India, in 1978. He received his Bachelors degree from Indian Institute of Technology, Kharagpur, India, in 2000. In 2002, he received the M.S.E.E. degree in electrical engineering from Georgia Institute of Technology, Atlanta, USA. He is currently working toward his Ph.D. degree. In the summer of 2001, he worked as a summer intern in National Semiconductor, Santa Clara, CA, USA. His research interests are in the area of test generation for mixed-signal and RF circuits and systems and design-for-test.Achintya Halder received the B.S. degree in electronics and electrical communication engineering from the Indian Institute of Technology, Kharagpur, in 1998. He worked as an IC design engineer with Texas Instruments until 2000. Currently, he is a Ph.D. student and a research assistant with the School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta. His research area is analog/RF and mixed signal testing.Ganesh P. Srinivasan received the B.E. degree in Electronics and Communication Engineering from the National Institute of Technology and Science, University of Madras, Chennai (Madras), India, in 2002. He received the M.S. degree in Electrical and Computer engineering from the Georgia Institute of Technology, Atlanta, GA, in 2004 and is currently pursuing his Ph.D. degree in Electrical and Computer Engineering at the Georgia Institute of Technology, Atlanta, GA. His research interests include low cost testing approaches for analog/RF and mixed-signal circuits, and improving performance of low cost testers for enabling high quality tests.Abhijit Chatterjee received the Bachelor of Technology degree in electrical engineering from the Indian Institute of Technology, Kanpur, India, in 1981, the M.S. degree in electrical engineering and computer science from University of Illinois at Chicago in 1983 and the Ph.D. degree in electrical and computer engineering from the University of Illinois at Urbana-Champaign in 1990. Until December 1992, he was a Research Staff Member at the General Electric Research and Development Center in Schenectady, NY. His work has been cited by the Wall Street Journal and presented on a Japanese network TV program called High Tech Shower International. He is a collaborating partner in NASAs New Millennium Project. Dr. Abhijit Chatterjee is also the author of one U.S. patent and has over one hundred publications in referenced journals and conferences.     

Comparison of the Effects of an Ionic Liquid and Other Salts on the Properties of Electrospun Fibers, 2 – Poly(vinyl alcohol)

Understanding the effect of conductivity in electrospinning solutions is crucial in order to improve or control the electrospinning process. In this paper the effect of adding small amounts (0.039–0.259 mol · kg^?1) of three different conductive additives to aqueous solutions of polyvinyl alcohol has been investigated. The salts were HMICl (a room temperature ionic liquid), TEBAC (a quaternary ammonium salt) and KCl. Addition of these salts caused a steady increase in the solution conductivity but the fiber diameter was typically greater than that of PVA alone, and exhibited an oscillatory trend. The oscillatory trend on the fiber diameter is attributed to fiber backbuilding and fusion that occurs prior to deposition on the collector.

     

Effect of PP-g-MAH compatibilizer content in polypropylene/nylon-6 blends

A method commonly used to induce compatibility between polyamides and polyolefins is by chemical modification of the polyolefins. This concept has been employed to produce compatibilized blend of nylon 6 (N6) and polypropylene copolymer (PPCP) by adding maleic anhydride grafted polypropylene (PP-g-MAH) as a third component. The blends of N6, PPCP and PP-g-MAH were prepared using a twin screw extruder. TEM of the blends revealed better dispersion and reduction in the size of the dispersed phase. In case of N6 rich blends, about 25% increase in tensile strength was observed with just three phb of PP-g-MAH. The maximum impact strength and flexural modulus were observed at around 30% PPCP. The incorporation of PP-g-MAH increased the flexural modulus of N6/PPCP blends significantly.     

Synthesis and characterization of MgAl2O4–ZrO2 composites

Different types of dense 5–97% ZrO₂–MgAl₂O₄ composites have been prepared using a MgAl₂O₄ spinel obtained by calcining a stoichiometric mixture of aluminium tri-hydroxide and caustic MgO at 1300 °C for 1 h, and a commercial yttria partially stabilized zirconia (YPSZ) powder as starting raw materials by sintering at various temperatures ranging from 1500 to 1650 °C for 2 h. The characteristics of the MgAl₂O₄ spinel, the YPSZ powder and the various sintered products were determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), BET surface area, particle size analysis, Archimedes principle, and Vickers indentation method. Characterization results revealed that the YPSZ addition increases the sintering ability, fracture toughness and hardness of MgAl₂O₄ spinel, whereas, the MgAl₂O₄ spinel hampered the sintering ability of YPSZ when sintered at elevated temperatures. A 20-wt.% YPSZ was found to be sufficient to increase the hardness and fracture toughness of MgAl₂O₄ spinel from 406 to 1314 Hv and 2.5 to 3.45 MPa m^1/2, respectively, when sintered at 1600 °C for 2 h.     

Development of advanced fiber-reinforced polymer composites by polymer hybridization technique: Emphasis on cure kinetics,mechanical, and thermomechanical performance

Polymer hybridization technique, consisting of an interlayer arrangement of different polymers, acts as the most economical and promising technique in augmenting the glass fiber-reinforced polymer composite's mechanical properties. This investigation focuses on the effect of cure kinetics on the flexural behavior of glass-polymer hybrid (GPH) composite, and also elucidates the comparative analysis on the mechanical behavior of glass-epoxy (GE) composite, glass-vinyl ester (GVE) composite, and GPH composite. The optimal postcuring temperature has been found to be 200°C for GPH composite among the other postcuring temperatures conducted at 140, 170, and 230°C. Among all these abovementioned composites, highest flexural strength and interlaminar shear strength properties have been recorded by the 200°C postcured GPH composite leading to 10.87 and 18.76% increment, respectively, compared with GE composite. Furthermore, thermomechanical characterization has been done to know the viscoelastic behavior of the GPH composite postcured at different temperatures using dynamic mechanical thermal analysis. The fracture morphology of flexural tested composite samples demonstrated a combination of failure modes. Relevant information on the chemical restructuring and fracture morphology of experimented composite material using Fourier-transform infrared (FTIR) spectroscopy and Scanning electron microscopy (SEM) has also been studied.