Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

Heat treatment of drill pipe of strength group D

Taganrog Metallurgical Plant. Translated form Metallurg, No. 11, p. 34, November, 1989.     

Statistical analysis of fiber-optic CDMA communication systems. I. Device modeling

In this paper, we present a new methodology for analysis of all-optical fiber-optic code-division multiple-access (FO-CDMA) networks. In this analysis, we propose statistical models, based on photon-counting techniques, for some basic elements of the network, such as splitters, combiners, star couplers, and FO-CDMA passive encoders/decoders. By following the statistical variation of the photon-count of the string of pulses that constitutes the address sequence in an FO-CDMA network, we will be able to reveal the quantum-limited optical signal-to-noise ratio (OSNR) required at the transmitter output to meet the performance limits. Moreover, considering receiver thermal noise and source extinction ratio, we explore the role of using an optical preamplifier before the detector and the dependence of the performance on the transmitted power and the weight of the employed optical orthogonal codes (OOCs).     

RF Reference Signal Transport by Optical Fibers

Among the various applications of optical fibers, the transmission of time or frequency reference signals seems to have some interest in view of the immunity of the fibers from electromagnetic disturbances. An analysis of the possible causes of phase fluctuation in a link and a feasibility test for the transmission of a local oscillator signal in a receiving system are reported.     

Hydrolytic stability and protective properties of polyurethane oligomers based on polyester/ether/polyols

The present study deals with effect of the type and chemical character of incorporated polyester/polyether blocks on the hydrolytic stability of crosslinked polyurethane oligomers. Diffusion parameters of the investigated polyurethane oligomers, giving information concerning chemical changes taking place in neutral, basic and acidic aqueous environments, have also been determined.