Enhanced transport of colloidal oil droplets in saturated and unsaturated sand columns

Colloidal-sized triacylglycerol droplets demonstrated enhanced transport compared to ideal latex colloid spheres in both saturated and unsaturated quartz sand columns. Oil droplets (mean diameter 0.74 ± 0.03 μm, density 0.92 g cm(-3), ζ-potential -34 ± 1 mV) were injected simultaneously with latex microsphere colloids (FluoSpheres; density 1.055 g cm(-3), diameters 0.02, 0.2, and 1.0 μm, ζ-potentials -16 ± 1, -30 ± 2, and -49 ± 1, respectively) and bromide into natural quartz sand (ζ-potential -63 ± 2 mV) via short-pulse column breakthrough experiments. Tests were conducted under both saturated and unsaturated conditions. Breakthrough of oil droplets preceded bromide and FluoSpheres. Recovery of oil droplets was 20% greater than similarly sized FluoSpheres in the saturated column, and 16% greater in the 0.18 ± 0.01 volumetric water content (VWC) unsaturated column. Higher variability was observed in the 0.14 ± 0.01 VWC column experiments with oil droplet recovery only slightly greater than similarly sized FluoSpheres. The research presents for the first time the direct comparison of colloidal oil droplet transport in porous media with that of other colloids, and demonstrates transport under unsaturated conditions. Based on experimental results and theoretical analyses, we discuss possible mechanisms that lead to the observed enhanced mobility of oil droplets compared to FluoSpheres with similar size and electrostatic properties.     

To call or not to call—That is the question (while driving)

We studied whether decisions to engage in cell phone conversation while driving and the consequences of such decisions are related to the driver's age, to the road conditions (demands of the driving task), and to the driver's role in initiating the phone call (i.e. the driver as caller vs. as receiver). Two experiments were performed in a driving simulator in which driver age, road conditions and phone conversation, as a secondary task, were manipulated. Engagement in cell phone conversations, performance in the driving and the conversation tasks, and subjective effort assessment were recorded. In general, drivers were more willing to accept incoming calls than to initiate calls. In addition, older and younger drivers were more susceptible to the deleterious effects of phone conversations while driving than middle aged/experienced drivers. While older drivers were aware of this susceptibility by showing sensitivity to road conditions before deciding whether to engage in a call or not, young drivers showed no such sensitivity. The results can guide the development of young driver training programs and point at the need to develop context-aware management systems of in-vehicle cell phone conversations.     

Advances in Polyimide‐Based Materials for Space Applications

The space environment raises many challenges for new materials development and ground characterization. These environmental hazards in space include solar radiation, energetic particles, vacuum, micrometeoroids and debris, and space plasma. In low Earth orbits, there is also a significant concentration of highly reactive atomic oxygen (AO). This Progress Report focuses on the development of space‐durable polyimide (PI)‐based materials and nanocomposites and their testing under simulated space environment. Commercial PIs suffer from AO‐induced erosion and surface electric charging. Modified PIs and PI‐based nanocomposites are developed and tested to resist degradation in space. The durability of PIs in AO is successfully increased by addition of polyhedral oligomeric silsesquioxane. Conductive materials are prepared based on composites of PI and either carbon nanotube (CNT) sheets or 3D‐graphene structures. 3D PI structures, which can expand PI space applications, made by either additive manufacturing (AM) or thermoforming, are presented. The selection of AM‐processable engineering polymers in general, and PIs in particular, is relatively limited. Here, innovative preliminary results of a PI‐based material processed by the PolyJet technology are presented.     

Degree distribution of the FKP network model

Power laws, in particular power-law degree distributions, have been observed in real-world networks in a very wide range of contexts, including social networks, biological networks, and artificial networks such as the physical internet or abstract world wide web. Recently, these observations have triggered much work attempting to explain the power laws in terms of new ‘scale-free’ random graph models. So far, perhaps the most effective mechanism for explaining power laws is the combination of growth and preferential attachment. In [A. Fabrikant, E. Koutsoupias, C.H. Papadimitriou, Heuristically optimized trade-offs: A new paradigm for power laws in the internet ICALP 2002, in: LNCS, vol. 2380, pp. 110–122], Fabrikant, Koutsoupias and Papadimitriou propose a new ‘paradigm’ for explaining power laws, based on trade-offs between competing objectives. They also introduce a new, simple and elegant parametrized model for the internet, and prove some kind of power-law bound on the degree sequence for a wide range of scalings of the trade-off parameter.     

Correlations (updated) for predicting the flow through MSF plant interstage orifices

So far, very few design correlations for interstage flow in MSF plants have been published, and their validation for a broad range of conditions is absent. Based on all experimental data with small-scale MSF units that was available to us, correlations for the orifice coefficient were developed for a wide range of flow and flashing conditions, in stages without and with downstream baffles, and a draft was presented at a past IDA congress. This paper recorrelates them in a much better way. These correlations are the first to use such a large amount of data, and the first to employ appropriate dimensionless variables. While their standard error and correlation coefficient are satisfactory, we note that the data came from a variety of sources and for channel widths of at most 0.53 m. Consequently, they should be used with some caution, and further extensive well-instrumented experiments are highly recommended.     

Stabilizing RNA by the sonochemical formation of RNA nanospheres

Biological macromolecules, including DNA, RNA, and proteins, have intrinsic features that make them potential building blocks for the bottom-up fabrication of nanodevices. Unlike DNA, RNA is a more versatile molecule whose range in the cell is from 21 to thousands of nucleotides and is usually folded into stem and loop structures. RNA is unique in nanoscale fabrication due to its diversity in size, function, and structure. Because gene expression analysis is becoming a clinical reality and there is a need to collect RNA in minute amounts from clinical samples, keeping the RNA intact is a growing challenge. RNA samples are notoriously difficult to handle because of their highly labile nature and tendency to degrade even under controlled RNase-free conditions and maintenance in the cold. Silencing the RNA that induces the RNA interference is viewed as the next generation of therapeutics. The stabilization and delivery of RNA to cells are the major concerns in making siRNAs usable drugs. For the first time, ultrasonic waves are shown to convert native RNA molecules to RNA nanospheres. The creation of the nanobubbles is performed by a one-step reaction. The RNA nanospheres are stable at room temperature for at least one month. Additionally, the nanospheres can be inserted into mammalian cancer cells (U2OS). This research achieves: 1) a solution to RNA storage; and 2) a way to convert RNA molecules to RNA particles. RNA nanosphere formation is a reversible process, and by using denaturing conditions, the RNA can be refolded into intact molecules.     

Post-war reconstruction and conservation of the historic Jewish Quarter in Jerusalem, 1967–1975

The aim of this paper is to examine post-war planning and reconstruction of the historic Jewish Quarter of the Old City of Jerusalem from 1967 to 1975. It focuses on the role of conservation of cultural heritage in determining the quarter's character, on the interaction between ‘top-down’ national and municipal planning and grassroots initiatives, on deviations from planning and declared policies, and on historical and geographical factors affecting restoration. Public opinion, individual initiatives, and response to immediate needs were more decisive in determining the character of the reconstruction than much of the planning. Intentional and unanticipated spatial changes within the Jewish Quarter and in its relationships with surrounding areas had a particularly profound effect on its character.