Deposition of dense isotropic carbon from acetylene in fluidized bed

Pyrolytic carbon was deposited from acetylene in a fluidized bed at 1100°C on alumina microspheres. In case when only argon was used as the diluent gas, density and BAF of the deposit decreased and deposition yield increased with increasing acetylene concentration. Hydrogen sypply suppressed carbon formation and, consequently, caused an increase in density and Lc. BAF was relatively independent of hydrogen concentration. It was found that high density, isotropic carbon can be deposited from acetylene at 1100°C, if an appropriate proportion of hydrogen is added.     

Thermal Expansion of Solid Solutions in the ZrTiO4—In2O3—M2O5 (M = Sb, Ta) System

Axial and dilatometric thermal expansions and phase transformations were studied for solid solutions having the α-PbO₂ structure in the ZrTiO₄—In₂O₃—M₂O₅ (M = Sb, Ta) system with nominal formulas of Zr _x Ti _y In _z Sb _z O₄ and Zr _x Ti _y In _z Ta _z O₄ where x + y + 2 z = 2. With increased substitution of z , the cell volume increased, the difference in the b parameters at room temperature between those quenched from 1400° and 1000°C decreased, and the thermal expansion decreased. The axial thermal expansion of ZrTi _y In _z · Ta _z O₄ with z = 0.3 was almost identical with that of HfTiO₄, and those with z = 0.4 and z = 0.45 were smaller than that of HfTiO₄. Unit-cell volumes of these compound were compared with those of single oxides to make it clear that the unit-cell volume of ZrTiO₄ was small anomalously and to distinguish the normal and abnormal substitution systems. These results were explained by the working hypothesis proposed for these compounds.     

Design of moving magnet type pickup actuator using inserted coil

Recently, the demand of the information storage devices with large storage capacity such as Blu-ray Disc and high-definition television is increased. In keeping with this trend, the optical storage devices are also required to have high data transfer rate and large storage capacity. To satisfy these requirements, the actuator for optical disc drive should have a high servo bandwidth to compensate the vibration of optical disc. The servo bandwidth is limited by some flexible modes of the actuator, thus it is essential to make these frequencies of flexible modes to high frequency region. The frequency of flexible mode depends on materials and shape. Stiff materials and simple shape is useful to increase the frequency of flexible mode. In this paper, we suggested a moving magnet type actuator having flexible modes which are happened at high frequency region. Generally, the moving magnet type actuator has an advantage to increase the frequency of flexible mode because the moving magnet type actuator has simple structure and the Young’s modulus of magnet is high. However, large moving mass and inefficiency of Electromagnetic (EM) circuit cut down driving sensitivities of actuator. To improve driving sensitivities, we designed the model with the closed EM circuit for tracking actuation. The design of experiments (DOE) procedure is applied to get proper design parameters and the variable metric method (VMM) which is a technique of optimization is used to improve driving sensitivity. The lens holder is also improved based on the optimization result of EM circuit. And to make up for the low efficiency of EM circuit, the thermal stability is checked on condition that the input current is very high. At last, the final design of moving magnet type actuator is suggested and it is verified that the driving performance and the structural stiffness of the final design is sufficient.     

Logic circuit synthesis using Prolog

This paper briefly reviews the current use of CAD in logic design, and then describes an expert system used to synthesize logic circuits. Specialized knowledge dealing with standard TTL ICs is written in Prolog and AGE, and the results are compared.     

Sulfated Hyaluronan Binds to Heparanase and Blocks Its Enzymatic and Cellular Actions in Carcinoma Cells

We examined whether sulfated hyaluronan exerts inhibitory effects on enzymatic and biological actions of heparanase, a sole endo-beta-glucuronidase implicated in cancer malignancy and inflammation. Degradation of heparan sulfate by human and mouse heparanase was inhibited by sulfated hyaluronan. In particular, high-sulfated hyaluronan modified with approximately 2.5 sulfate groups per disaccharide unit effectively inhibited the enzymatic activity at a lower concentration than heparin. Human and mouse heparanase bound to immobilized sulfated hyaluronan. Invasion of heparanase-positive colon-26 cells and 4T1 cells under 3D culture conditions was significantly suppressed in the presence of high-sulfated hyaluronan. Heparanase-induced release of CCL2 from colon-26 cells was suppressed in the presence of sulfated hyaluronan via blocking of cell surface binding and subsequent intracellular NF-κB-dependent signaling. The inhibitory effect of sulfated hyaluronan is likely due to competitive binding to the heparanase molecule, which antagonizes the heparanase-substrate interaction. Fragment molecular orbital calculation revealed a strong binding of sulfated hyaluronan tetrasaccharide to the heparanase molecule based on electrostatic interactions, particularly characterized by interactions of (−1)- and (−2)-positioned sulfated sugar residues with basic amino acid residues composing the heparin-binding domain-1 of heparanase. These results propose a relevance for sulfated hyaluronan in the blocking of heparanase-mediated enzymatic and cellular actions.     

Corrosion characteristics of reduced activation ferritic steel, JLF-1 (8.92Cr–2W) in molten salts Flibe and Flinak

Static corrosion tests were performed in molten salts, LiF–BeF₂ (Flibe) and LiF–NaF–KF (Flinak), at 500 °C and 600 °C for 1000 h. The purpose is to investigate the corrosion characteristics of reduced activation ferritic steels, JLF-1 (8.92Cr–2W) in the fluids. The concentration of hydrogen fluoride (HF) in the fluids was measured by slurry pH titration method before and after the exposure. The HF concentration determined the fluoridation potential. The corrosion was mainly caused by dissolution of Fe and Cr into the fluids due to fluoridation and/or electrochemical corrosion. Carbon on the surface might be dissolved into the fluids due to the corrosion, and this resulted to the decrease of carbide on the surface. The corrosion depth of the JLF-1 specimen, which was obtained from the weight losses, was 0.637 μm in Flibe at 600 °C and 6.73 μm in Flinak at 600 °C.     

Measurement of residual stresses in injection‐molded polymer parts by time‐resolved fluorescence

Time‐resolved fluorescence properties of 9‐methylanthracene (9MAn) dispersed in film of polyvinylchloride (PVC) containing carbon black were studied under tensile loadings. The fluorescence lifetime of 9MAn decreased from 5.70 to 5.55 ns, whereas the stresses acting on the films increased from 0 to 3 MPa. The change in fluorescence lifetimes of 9MAn during the stress relaxation process showed that the fluorescence lifetimes were correlated with the stresses, not with the strains. The results suggest that 9MAn is a useful probe for monitoring stresses acting on the matrix. With the use of the fluorescence properties of 9MAn, the residual tensile stresses on the skin‐layer of PVC injection‐molded test pieces were estimated. The estimated residual stresses were about ～ 1 MPa. The residual stresses were relaxed to 0 MPa with annealing at 100°C. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2600–2603, 2002     

Syntheses of Spinon Thermal Conductivity Materials in Sr–Cu–O System by Glass‐Ceramics Technique

We have synthesized spinon thermal conductivity materials in Sr–Cu–O system by glass‐ceramics technique. The materials are promising for active control of thermal energy in microelectronic devices because of high and anisotropic thermal conduction, its controllability, and electric insulation. Nevertheless, research on these materials has been limited to that concerning theoretical perspectives and investigation of physical properties using large single crystals. In this study, we adopt glass‐ceramics technique to synthesize these materials: We prepared melt‐quenched multicomponent oxides including SrO and CuO, and checked its glass‐forming ability and crystallization behaviors by heating. As a result, we have found that SrCuO₂ and Sr₁₄Cu₂₄O₄₁, known as the spinon thermal conductivity materials, are synthesized using SrO–CuO–?Li₂O–?Al₂O₃?–Ga₂O₃ system. This synthesis process for the system will provide practical application of the spinon thermal conductivity materials.