The effect of pretreatment in a fluidized bed upon diamond synthesis on particles by chemical vapour deposition

Diamond synthesis was carried out on non-diamond particles (single- and poly-crystal silicon, quartz and SiC) by microwave plasma-enhanced chemical vapour deposition. Fine diamond particles were deposited on the non-diamond particle surface. The particle deposition density on the untreated particle substrates was strongly dependent on the surface characteristics of the particle substrates. The value ranged from 10–10⁵ mm^–2 for each particle. Particle substrates were pretreated in a gas-solid fluidized bed, and these were then used for the deposition of diamond. The pretreatment of the surface of the particle substrate in the fluidized bed greatly enhanced the nucleation of diamond. A deposition density of about 10⁷ mm^–2 was obtained on single-crystal silicon particles pretreated for 15 h. The effectiveness of the fluidized bed pretreatment on the deposition density was observed to be appreciable for the four kinds of particle examined.     

A high biotin diet improves the impaired glucose tolerance of long-term spontaneously hyperglycemic rats with non-insulin-dependent diabetes mellitus

Event-related potentials (ERPs) were recorded in a continuous memory recognition task. Readable non-words and abstract geometric figures were presented in an alternating manner with an inter-stimulus interval of 2.1 s. Probability of item repetition was 0.25, a lag of one item lay between initial presentation and repetition. OLD/NEW distinction was indicated by the subject's motor response. Using linked-mastoid electrodes for reference, material-specific hemispheric asymmetries of ERPs started 150 ms after stimulus onset in temporo-lateral and parietal recordings with ERPs elicited by non-words being lateralized to the left and those by figures to the right. Clear OLD/NEW ERP effects were found with non-words: Starting about 200-250 ms after stimulus presentation, ERPs of formerly presented (OLD) items were more positive-going in recordings over the midline than ERPs of items that were new and to be repeated (NEW). In contrast, no local OLD/NEW ERP-difference was found with figures. In some brain regions, OLD/NEW ERP-differences were larger over the left hemisphere compared to the right. This finding, however, did not differ between non-words and figures.     

Initial experience with the Cordis stent: analysis of serial angiographic follow-up

Studies were carried out on 150 workers with mental disturbances, who had been involved in the clean-up of the Chernobyl atomic energy station accident. Visual and computer analyses of EEG traces from 43 workers were compared with traces from 17 healthy subjects, and the comparison revealed that the most common features in workers were disorganization of the alpha-rhythm and strengthening of beta-1-activity in the sensorimotor cortex. In neurosis-like syndromes (13 patients), there was a significant increase in the power of the alpha-rhythm in the anterior parts of the cortex; in psycho-organic states, power as significantly reduced (especially in the left hemisphere). Contributing to the greater proportion of flat EEG traces in patients with psycho-organic syndromes as compared with other groups of patients. Most patients among the clean-up workers had increased assimilation of flashing light rhythms and weakening of non-specific and skin galvanic responses to a light stimulus. It was concluded that systemic CNS changes occurred in patients from the clean-up worker groups, especially in those with psycho-organic syndrome.     

Chemical constituents and inhibitory activities of essential oils fromCyperus brevifolius andC. kyllingia

Cyperus brevifolius andC. kyllingia are two common weeds in Hawaii. The underground parts, including the rhizomes and roots, contain allelopathic essential oils, which may contribute to the aggressive spread of these weeds in grasslands and lawns. Although morphologically similar,C. kyllingia contains more essential oils thanC. brevifolius. Also, the former is rich in terpenes, including -cyperone, -selinene, and -humulene, while the latter is rich in C₁₇ to C₂₅ n-paraffins. These chemical differences agree with their inhibitory activities against indicator species and the general observation thatC. kyllingia is the more prevalent weed of the two.On leave from the Department of Agricultural Chemistry, Kinki University, Osaka, Japan.     

Relation between low temperature fluidity and sound velocity of lubricating oil

Low temperature fluidity is important for lubricating oil. Viscoelastic solid transition temperature at atmospheric pressure T_VE0 represents the low temperature fluidity of lubricating oil, which is estimated from the occurrence of photo elastic effect by lowering the temperature using liquid nitrogen. Sound velocity in lubricating oil is measured using Sing around technique. Then the adiabatic Bulk modulus K is calculated from the measured sound velocity. A relation is found between the adiabatic bulk modulus and the viscoelastic solid transition temperature of lubricating oil. The relation depends on the molecular structure of lubricating oil. The oils of a group belong to almost same molecular structure, follows the same relation. For same molecular structure T_VE0 decreases as decreasing the adiabatic bulk modulus of lubricating oil. It is also found that, the viscoelastic solid transition temperature of blend oils can be predicted from the base oils’ T_VE0 and K.     

Realization of the Switching Mechanism in Resistance Random Access Memory™ Devices: Structural and Electronic Properties Affecting Electron Conductivity in a Hafnium Oxide–Electrode System Through First-Principles Calculations

The resistance random access memory (RRAM?) device, with its electrically induced nanoscale resistive switching capacity, has attracted considerable attention as a future nonvolatile memory device. Here, we propose a mechanism of switching based on an oxygen vacancy migration-driven change in the electronic properties of the transition-metal oxide film stimulated by set pulse voltages. We used density functional theory-based calculations to account for the effect of oxygen vacancies and their migration on the electronic properties of HfO₂ and Ta/HfO₂ systems, thereby providing a complete explanation of the RRAM? switching mechanism. Furthermore, computational results on the activation energy barrier for oxygen vacancy migration were found to be consistent with the set and reset pulse voltage obtained from experiments. Understanding this mechanism will be beneficial to effectively realizing the materials design in these devices.     

Porous silicon/Ni composites of high coercivity due to magnetic field assisted etching

ABSTRACT: Ferromagnetic nanostructures have been electrodeposited within the pores of porous silicon templates with average pore-diameters between 25 and 60 nm. In this diameter regime the pore-formation in general is accompanied by dendritic growth resulting in rough pore-walls which involves metal deposites also offering a branched structure. These side-branches influence the magnetic properties of the composite system not only due to modified and peculiar stray fields but also because of a reduced interpore-spacing by approaching of adjacent side-pores. To improve the morphology of the porous silicon structures a magnetic field up to 8 T has been applied during the formation process. The magnetic field etching results in smaller pore-diameters with less dendritic side-pores. Deposition of a ferromagnetic metal within these templates leads to less branched nanostructures and thus to an enhancement of the coercivity of the system and also to a significantly increased magnetic anisotropy. So magnetic field assisted etching is an appropriate tool to improve the structure of the template concerning the decrease of the dendritic pore-growth and to advance the magnetic properties of the composite material.     

Metal composition of Y2O3:Eu powder evaluated using particle analyzer

Y₂O₃:Eu red phosphor powder was synthesized with powders of metal–ethylenediaminetetraacetic acid (EDTA) complexes as a starting material. The compositional analysis of each metal–EDTA complexes particle and Y₂O₃:Eu particle was performed using a particle analyzer. In this study, first, the particles of a mixture of Y– and Eu–EDTA complexes were obtained by a spray drying method from solution consisting of Y– and Eu–EDTA$NH₄. Then, the metal–EDTA complex powder was fired in obtaining the Y₂O₃:Eu red phosphor. The metal composition of each particle was scattered for the powder of the metal–EDTA mixture, while it became narrow for the Y₂O₃:Eu powder. The intensity of cathodoluminescence obtained from the Y₂O₃:Eu powder increased with increasing the fired temperature. In addition, the maximum intensity was obtained from the sample with xZ0.12 for Y_2KxO₃:Eu_x.     

Influences of heat source model on welding residual stress and distortion in a multi-pass J-groove joint

Welding mechanical behaviors including residual stress and distortion are highly non-linear phenomena in nature. When numerical simulation methods such as thermal elastic plastic finite element method (FEM) are used to quantitatively predict welding residual stress and distortion, a long computational time is required especially for multi-pass joints. In real engineering structures, many weldments have large dimensions and complex shapes, and they are usually assembled by a multi-pass welding process. Therefore, it is necessary to develop time-effective computational approaches for practice engineering analysis. In this study, a method based on variable length heat sources was proposed for the analysis of thermo-mechanical behaviors for multi-pass joints. The welding residual stress field in a dissimilar metal J-groove joint with axis-symmetric geometrical shape, which was performed by a semi-circle balanced welding process, was investigated using the proposed method. The simulation results were compared with the measured data as well as the simulation results computed by a moving heat source. Meanwhile, the instantaneous line heat source was also employed to estimate the welding residual stresses in the same joint in an extreme case. The influences of heat source model (type) on welding residual stress and distortion were discussed.