The role of the interface in melt linear viscoelastic properties of LLDPE/LDPE blends: Effect of the molecular architecture of the matrix

The rheological properties of blends consisting of a long chain branched low‐density polyethylene (LDPE) and two linear low‐density polyethylenes (LLDPE) are studied in detail. The weight fractions of the LDPE used in the blends are 5 and 15%. The linear viscoelastic characterization is performed at different temperatures for all the blends to check thermorheological behavior and miscibility in the melt state. Blends containing metallocene LLDPE as the matrix display thermorheologically complex behavior and show evidences of immiscibility in the melt state. The linear viscoelastic response exhibits the typical additional relaxation ascribed to the form deformation mechanism of dispersed phase droplets (LDPE). The Palierne model satisfactorily describes the behavior of these blends in the whole frequency range explored. However, those blends with Ziegler‐Natta LLDPE as the matrix fulfill the time‐temperature superposition, but exhibit a broad linear viscoelastic response, further than the expected for an immiscible system with a sharp interface. The rheological analysis reveals that, in addition to the droplets form relaxation, another mechanism at lower frequencies exists. The broad linear response of the blends with the Ziegler‐Natta LLDPE can be explained by hypothesizing a strong interaction between the high molecular weight linear fraction of the LLDPE and the low molecular weight (almost linear) chains of the LDPE phase, forming a thick interface with its own viscoelastic properties. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Electrically Enhanced Readout System for a High‐Frequency CMOS‐MEMS Resonator

The design of a CMOS clamped‐clamped beam resonator along with a full custom integrated differential amplifier, monolithically fabricated with a commercial 0.35 μm CMOS technology, is presented. The implemented amplifier, which minimizes the negative effect of the parasitic capacitance, enhances the electrical MEMS characterization, obtaining a 48 × 10⁸ resonant frequency‐quality factor product (Q×f_res) in air conditions, which is quite competitive in comparison with existing CMOS‐MEMS resonators.     

Two Endogenous Substrates for Polyphenoloxidase in Pericarp Tissues of Postharvest Rambutan Fruit

Abstract: The catalytic oxidation of phenolic substrates by polyphenoloxidase (PPO) causes pericarp browning of postharvest rambutan fruit. In the present study, PPO and its endogenous substrates were extracted from rambutan pericarp tissues (RPT). The substrate extracts were sequentially partitioned with ethyl acetate and n-butanol. The analysis of total phenolic content showed that the most phenolic compounds were distributed in ethyl acetate fraction. By high-performance liquid chromatography (HPLC), (−)-epicatechin (EC) and proanthocyanidin A2 (PA2) were identified from this fraction. After reacting with rambutan PPO, EC turned brown rapidly within 10 min, indicating that it was a significant endogenous substrate. Although PA2 could also be oxidized by the PPO, it turned brown very slowly. In addition, because EC and PA2 were continually catalyzed into browning products by PPO during storage of the fruit at 4 and 25 °C, their contents in RPT gradually declined with the extended storage time. It was further observed that both substrate contents in rambutan fruit storing at 25 °C decreased more rapidly than that storing at 4 °C, suggesting that low temperature inhibited the catalytic oxidation of substrates so as to slow down pericarp browning. Practical Application: Pericarp browning is a serious problem to storage and transport of harvested rambutan fruit. A generally accepted opinion on the browning mechanism is the oxidation of phenolic substrates by PPO. Ascertaining PPO substrates will effectively help us to control enzymatic reaction by chemical methods so as to delay or even prevent pericarp browning of harvested rambutan fruit.     

Press hardening of alternative materials: conventional high- strength steels

The increase in strength of new high strength steels (HHS) and advanced high strength steels (AHHS) has led to forming issues, such as high springback, low formability, increase of forming forces and tool wear. These problems increase thecosts of manufacturing and maintaining stamping tools in the automotive industry. The aim of this research was to analyse the advantages of applying the press- hardening process toconventional HSS and AHSS steel to increase their formability and therefore reduce the number of forming steps and productioncosts. With this aim in mind, the press-hardening process was used to manufacture an industrialcomponent using four different automotive steel grades: dual phase (DP),complex phase (CP), transformation- induced plasticity (TRIP) and martensitic (MS) grade. Springback measurements werecarried out, together with an analysis of the obtained final mechanical properties and microstructures. The results showed that the formability of all the materials increased. The mechanical properties of theCP800 and TRIP700 materials were maintained or even improved, whereas those of the MS1200 and HCT980X materials were significantly reduced. Weconclude that press hardening is a suitable manufacturing process forCP800 and TRIP700components.     

Age-related changes of NADPH-diaphorase-positive neurons in the rat inferior colliculus and auditory cortex

Nitric oxide (NO) has been implied in age-related changes of the central nervous system (CNS) and the central auditory pathway. The present study was conducted to investigate whether the number of NO-producing cells and their morphometric characteristics in the inferior colliculus (IC) and the auditory cortex (AC) are changed with the increasing age of the subjects. IC and AC sections of adult and senile Wistar rats were studied using the histochemical detection of NADPH-diaphorase activity (NADPH-d), a marker for neurons containing nitric oxide synthase (NOS). Our results showed a decreased area of the somas of NADPH-d-positive neurons in the dorsal cortex (DC) of the IC and a diffuse loss of NADPH-d-positive neurons in the senile IC and primary cortical auditory area (Te1). However, an increased number of NO-producing cells have been shown by other authors in different parts of the ageing auditory pathway and CNS. It seems that age-related changes in NADPH-d-positive cells may follow a region-specific route. These changes may be related to hearing impairments with increasing age.     

Design and implementation of mechanical resonators for optimized inertial electromagnetic microgenerators

This work describes the design and implementation of an electromagnetic inertial microgenerator for energy scavenging from ambient vibrations. The structure of the device is based in a mechanical resonator formed by a permanent magnet (inertial mass) mounted on a polymeric membrane, in combination with a fixed micromachined coil. ANSYS simulations are carried out to investigate the influence of the resonator geometry on the resonant frequency and on the parasitic damping, and to analyze the optimum geometry of the coil for optimization of the electromagnetic coupling in the devices. Generator prototypes have been fabricated with a modular manufacturing process in which the electromagnetic converter and the mechanical resonator are manufactured separately, diced and then assembled. The experimental results show the ability of these devices to generate power levels in the range of 50 μW with output voltages in the range of hundreds of mV. The parasitic damping of the resonator structures is estimated from the fitting of the experimental data, and suggests the existence of an intrinsic limitation of the polymers related to spring stiffening effects at large excitation amplitudes. The comparison of the simulations and the experimental results indicate that further optimizations of this parameter and of the coil series resistance would allow increasing the generated power in more than one order of magnitude.     

Chemical composition,digestibility and protein quality of 12 sunflower (Helianthus annuus L) cultivars

Twelve sunflower (Helianthus annuus L) cultivars grown in Spain were analysed and tested in experiments with rats. The dehulled seeds contained an average of 32.2 MJ kg⁻¹ dry matter (DM) gross energy, 653 g kg⁻¹ DM fat, 60 g kg⁻¹ DM total non-starch polysaccharides (NSP) and 6 g kg⁻¹ DM Klason lignin. The sunflower seed hulls contained 20.2 MJ kg⁻¹ DM gross energy, 53 g kg⁻¹ DM fat, 562 g kg⁻¹ DM total NSPs and 239 g kg⁻¹ DM Klason lignin. The sunflower samples were dehulled and partially defatted (to ∼17% fat) and included in diets for rats. The dehulled, partially defatted samples contained on average 74.6 g nitrogen kg⁻¹ DM and 1.409 mg g⁻¹ phenolic compounds (chlorogenic acid + caffeic acid + derivative 1 + derivative 2) varying from 0.677 to 2.847 mg g⁻¹. Groups of five growing rats were fed diets (9.38% crude protein) containing one of the sunflower cultivars as the only source of protein. Apparent ileal and faecal digestibilities were determined by using an indigestible marker (Cr₂O₃) and faecal digestibility based on total faecal collections. Apparent ileal, caecal and faecal digestibilities of organic matter were 81.2–91.5% (P = 0.05), 95.8–97.1% (P = 0.005) and 94.7–95.3% (P = 0.94) respectively. The apparent faecal digestibilities of DM, energy and protein (N × 6.25) were 93.2–93.8%, 93.5–94.3% and 81.6–84.3% respectively with no differences among cultivars. Biological value (BV) ranged between 63.8 and 73.2% (P = 0.0001) and net protein utilisation (NPU) between 59.9 and 69.5% (P = 0.0001). BV and NPU were positively correlated with lysine and threonine contents, but no correlation with the analysed phenolic compounds was detected. © 1999 Society of Chemical Industry     

Aldo Rossi and the architecture of Spanish democratic transition in Seville

In the second half of the 1970s, during the Spanish transition to democracy, a new generation of young architects in Seville reassessed the city in relation to Italian debates and their strong political drive. Concerned about the destruction of Seville’s historical centre by the Franco regime’s urban planning, these architects found in Aldo Rossi not only their main figure of reference, but also a powerful object of fascination. Moreover, Rossi’s presence in Seville between 1975 and 1978 had a fundamental influence on the early work of young Sevillian architects and the subsequent planning of the city under the first democratic administrations. However, a particular analysis of Rossi’s ideas in comparison to the works of that time in Seville showed how these young local architects did not always fully bring on board Rossi’s political position through their architectural projects. Rather, these architects’ reading of Rossi favoured figure over structure, visual aspects over relational ones, and ultimately had an important impact in the way the city’s historical centre developed in the 1980s and 1990s.