Convective heat transfer inside a rotating cylinder with an axial air flow

This article presents an experimental identification technique for the convective heat transfer coefficient inside a rotating cylinder with an axial airflow. The method consists in heating the outer face of the cylinder using infrared lamps, and acquiring the evolution of the external surface temperature versus time using an infrared camera. Heat transfer coefficients are identified via three methods. The first one is based on an inverse model, the second one assumes the wall of the cylinder as a thermally thin wall and the third one is based on an analytical method permitting to obtain the temperature field within the whole cylinder. The experiments were carried out for a rotational speed ranging from 4 to 880 rpm corresponding to rotational Reynolds numbers varying from 1.6×10³ to 4.7×10⁵ and an air flow rate varying from 0 to which corresponds to an axial Reynolds numbers ranging from 0 to 3×10⁴. Correlations connecting the Nusselt number to the axial and rotational Reynolds numbers are also proposed.     

Theoretical and numerical investigation of flow stability in porous materials applied as volumetric solar receivers

This article reports results of a theoretical analysis as well as a numerical study investigating the occurrence of flow instabilities in porous materials applied as volumetric solar receivers. After a short introduction into the technology of volumetric solar receivers, which are aimed to supply heat for a steam turbine process to generate electricity, the general requirements of materials applied as solar volumetric receivers are reviewed. Finally, the main methods and results of the two studies are reported. In the theoretical analysis it is shown that heat conductivity as well as permeability properties of the porous materials have significant influence on the probability of the occurrence of flow instabilities. The numerical study has been performed to investigate the occurrence of unstable flow in heated ceramic foam materials. In the simulations a constant heat flow of radiation, that is absorbed in a defined volume, and constant permeability coefficients are assumed. Boundary conditions similar to those of the 10 MW Solucar Solar project have been chosen. In a three dimensional, heterogeneous two phase heat transfer model it was possible to simulate local overheating of the porous structure. The parameters heat conductivity, turbulent permeability coefficient and radial dispersion coefficient have been varied systematically. Consequently, for a heat flux density of 1 MW/m² a parameter chart could be generated, showing the possible occurrence of “unstable” or “stable” thermal and fluid mechanical behaviour. These numerical results are beneficial for the design of optimized materials for volumetric receivers.     

Kinetics and thermodynamic behavior of WO3 and WO3:P thin films

 There is a considerable interest in the research and development of materials and devices, that can be used for optical switching of large-scale glazings. Several potential switching technologies are available for glazings, including those based on electrochromic, thermochromic and photochromic phenomena. One of the most promising technologies for optical switching devices is electrochromism (EC). In order to improve the electrochromic properties of tungsten oxide, we have investigated the effect of phosphorous insertion on the electrochromic behavior of oxide films prepared by the sol–gel process.The kinetics and thermodynamics of electrochemical intercalation of lithium into Li_xWO₃ and Li_xWO₃:P films prepared by the sol–gel process were investigated. The standard Gibbs energy for lithium intercalation was calculated. The chemical diffusion coefficients, D, of lithium intercalation into oxide, were measured by galvanostatic intermittent titration technique (GITT), as functions of the depth of lithium intercalation.     

Optical and electrochemical properties of V2O5:Ta Sol–Gel thin films

Vanadium and tantalum-doped vanadium pentoxide, V₂O₅ and V₂O₅:Ta thin films (2.5 and 5 mol% of Ta) were prepared using sol–gel dip-coating technique.The coating solutions were prepared by reacting vanadium (V) oxytripropoxide and tantalum ethoxide (V) as precursors using anhydrous isopropyl alcohol as solvent.The films were deposited on a transparent glass substrate with ITO conducting film by dip-coating technique, with a withdrawal of 20 cm/min from the vanadium–tantalum solution and heat treated at 300 °C for 1 h. The resulting films were characterized by cyclic voltammetry, optical spectroscopy and by X-ray diffraction analysis (XRD). XRD data show that the films thermally treated at 300 °C were crystalline.A charge density of 70 mC/cm² was obtained for the film with 5 mol% of Ta, with an excellent stability up to 1500 cycles.     

Growth and characterization of ZnO thin films prepared by electrodeposition technique

ZnO thin films were deposited on either indium tin oxide-coated glass or copper substrate by the electrodeposition process, using zinc chloride and flowing air as precursors. The effect of pH on the structural and morphological ZnO films was studied and the optimum deposition conditions have been outlined. The kinetics of the growth of the films have been investigated. We note that the rate of deposition of ZnO in an acidic solution was larger than in a basic solution. The structure of the films was studied using X-ray diffractometry (XRD) and transmission electron microscopy (TEM). The surface morphology and thickness of the films were determined using scanning electron microscopy. The X-ray diffraction analysis shows that the films are polycrystalline with hexagonal crystal structure (zincite) at pH 4. The optical transmittance of ZnO decreases with varying film thickness. The optical energy bandgap was found to be 3.26 eV.     

Farm mechanization leading to more effective energy-utilizations for cassava and yam cultivations in Rivers State, Nigeria

Surveys have been conducted, under the auspices of the Ministry of Agriculture and Agricultural Development Projects (ADPs), in the 23 local-government areas of the Rivers State, Nigeria. A structured questionnaire, personal visits to farms and interactions with information repositories were used. The quantities of energy consumed by tractors used in activities associated with the growing of cassava and yam crops in those areas were compared with traditional operations, using just manual labour. Within the period of 1986–2004, the total energy utilizations in the production of these crops, in the 23 local government areas, were 2738.87 and 33.5 MJ for tractor-power and traditional-manual operations, respectively. The tractorization intensity (TI) dropped from 0.352 hp/ha in 1986 to 0.345 hp/ha in 2004. This result was below the presently advocated 0.5 hp/ha for agricultural operations in order to increase crop production. This study identified the causes of this shortfall and recommended, at least for the short-term future, that farm industrialization of all sectors should be subsidized.     

Xerographic properties of a-Se:Te photoconductors

It is shown that the dark decay of the electrostatic surface potential on a corona-charged a-Se:Te alloy photoreceptor occurs via electric field-enhanced xerographic depletion discharge (FEXDD) in which Poole-Frenkel-assisted thermal emission of holes from deep mobility-gap states and their subsequent sweep out generates a negative bulk space charge. The theoretical model development is applied to explain the observed experimental dark discharge data over a wide range of charging (initial) voltages. It is shown that although the time required for the surface potential to decay to its half value t_1/2 initially increases with the charging voltage V₀ at the highest charging voltage, t_1/2 actually decreases with V₀. Results obtained from cycled-up xerographic experiments on single and double-layer photoreceptors are also reviewed and discussed in conjunction with transient photoconductivity experiments     

Sprayed CuInS2 films grown under Cu-rich conditions as absorbers for solar cells

CuInS₂ films were prepared by the spray pyrolysis method using either copper-rich solutions or the recrystallization of low-crystallinity film in the presence of an intentionally deposited Cu_xS layer. KCN-etched films were characterized by XRD, SEM and EDX. The Cu/In molar ratio of 1.5–4.0 in the solution resulted in well-crystallized CuInS₂ films with the mean crystallite size of 120 nm. SEM study showed nonuniform surface with irregularly placed large grain domains in the flat film. The two-step process resulted in a uniform film with the crystallite size of 50 nm. Films exhibited an In-rich composition. Solar cells based on a recrystallized absorber showed an improved quantum efficiency spectrum.     

Investigation of pulsed non-melt laser annealing on the film properties and performance of Cu(In,Ga)Se2 solar cells

Pulsed non-melt laser annealing (NLA) has been used for the first time to modify near-surface defects and related junction properties in Cu(In,Ga)Se₂ (CIGS) solar cells. CIGS films deposited on Mo/glass substrates were annealed using a 25 ns pulsed 248 nm laser beam at selected laser energy density in the range 20–60 mJ/cm² and pulse number in the range 5–20 pulses. XRD peak narrowing and SEM surface feature size increase suggest near-surface structure changes. Dual-beam optical modulation (DBOM) and Hall-effect measurements indicate NLA treatment increases the effective carrier lifetime and mobility along with the sheet resistance. In addition, several annealed CdS/CIGS films processed by NLA were fabricated into solar cells and characterized by photo- and dark-J–V and quantum efficiency (QE) measurements. The results show significant improvement in the overall cell performance when compared to unannealed cells. The results suggest that an optimal NLA energy density and pulse number for a 25 ns pulse width are approximately 30 mJ/cm² and 5 pulses, respectively. The NLA results reveal that overall cell efficiency of a cell processed from an unannealed film increased from 7.69% to 13.41% and 12.22% after annealing 2 different samples at the best condition prior to device processing.     

A Mathematical Study for Laminar Boundary‐Layer Flow,Heat, and Mass Transfer of a Jeffrey Non‐Newtonian Fluid Past a Vertical Porous Plate

In this article, we investigate the nonlinear steady‐state boundary‐layer flow, heat and mass transfer of an incompressible Jeffrey non‐Newtonian fluid past a vertical porous plate. The transformed conservation equations are solved numerically subject to physically appropriate boundary conditions using a versatile, implicit finite‐difference technique. The numerical code is validated with previous studies. The influence of a number of emerging non‐dimensional parameters, namely, Deborah number (De), Prandtl number (Pr), ratio of relaxation to retardation times (λ), Schmidt number (Sc), and dimensionless tangential coordinate (ξ) on velocity, temperature, and concentration evolution in the boundary layer regime are examined in detail. Furthermore, the effects of these parameters on surface heat transfer rate, mass transfer rate, and local skin friction are also investigated. It is found that the velocity is reduced with increasing Deborah number whereas temperature and concentration are enhanced. Increasing λ enhances the velocity but reduces the temperature and concentration. The heat transfer rate and mass transfer rates are found to be depressed with increasing Deborah number, De, and enhanced with increasing λ. Local skin friction is found to be decreased with a rise in Deborah number whereas it is elevated with increasing λ. And an increasing Schmidt number decreases the velocity and concentration but increases temperature. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21111