Stable lead isotopes and lake sediments--a useful combination for the study of atmospheric lead pollution history

Analysis of stable lead isotopes and lead concentrations in lake-sediment deposits, not least in varved (annually-laminated) sediments, is a useful method to study lead pollution history. This paper presents details from a study of 31 lakes in Sweden. Using a strong acid digestion of sediment samples and ICP-MS analyses, we have found that Swedish lake sediments have a high natural (pre-pollution) 206[Pb]207[Pb] ratio (mean 1.52+/-0.18, range 1.28-2.01, n=31 lakes). In contrast, atmospheric lead pollution derived from metal smelting processes, coal burning and from alkyl-lead added to petrol has a lower ratio (< 1.2). Consequently, when pollution lead deposition began approximately 3500 years ago, the lead isotope ratio of the sediments started to decline, and in modern sediments it is typically < 1.2. Using the isotope and concentration values and a mixing model, the relative contribution of pollution and natural lead in sediment samples can be calculated. The pollution lead records of the Swedish lake sediments show a consistent picture of the atmospheric lead pollution history. Some noticeable features are the Roman peak (approx. 0 AD), the large and permanent Medieval increase (approx. 1000 AD), peaks at approximately 1200 and 1530 AD, the rapid increase after World War II, the peak in the 1970s, and the large modern decline.     

Comparative analysis and performance of load bearing characteristics of biogas and gasoline-fuelled electric generator

ABSTRACT

This research demonstrates a simplified purification of biogas from hybrid waste and conversion of a single cylinder spark ignition engine to use biogas. The scrubbed gas obtained showed 95% methane enriched biogas. The carburettor of the gasoline engine was modified with a tri-fuel carburettor to suit the input specimen fuel fed to the modified 2.5 kVA, 230 V, and 50 Hz reciprocating engine to generate power. Results showed that 1 kg of compressed biogas ran for 46 min with a load capacity of 1800 W on the 2.5 kVA modified generator, while a litre of gasoline ran for 72 min under the same loading capacity. A comparative assessment of the load bearing characteristics was conducted. Load condition exceeding 1000 W resulted in a voltage output drop of 14.25% on biogas while a small change in voltage of 0.06% occurred for loading conditions between 100 and 1000 W. There was 8.5% decrease in engine speed while operating on biogas with little or no change on gasoline. Maximum torque of 5 and 3.5 Nm at 1800 W electric loading was experienced for gasoline and biogas. Finally, the BSFC for gasoline and biogas at 15% loading condition was maximum at 2000 and 2400 kg/kWh, respectively.     

Features of disinfection kinetics of water containing <Emphasis Type="Italic">Escherichia Coli</Emphasis> in conditions of hydrodynamic cavitation

The paper has investigated the disinfecting effect of hydrodynamic cavitation on the microorganisms of E. coli in water. It has been found that disinfection kinetics depend on the intensity of the hydrodynamic cavitation field, the microbial load, and gas content. We have studied structure and morphology variation of the E. coli bacteria. It has been demonstrated that the antimicrobial effect is achieved owing to the physicochemical effects of the cavitation field, under whose influence there occurs mechanical destruction of cells and chemical disinfection by the radicals of hydroxyl and hydrogen peroxide.     

铝酸钙水泥、硅酸盐水泥和β-半水石膏混合物中钙矾石的膨胀性能

本文利用现场同步加速X-射线衍射、等温量热仪和膨胀测量等手段,研究了在20℃,100%相对湿度下,由25%(重量比)的铝酸钙水泥、12.5%的硅酸盐水泥、12.5%的β-半水石膏和50%的水组成的浆体的水化。水化伊始,首先形成了石膏和钙矾石,同时半水石膏也相应消耗(0-45min内)。随后石膏继续消耗,钙矾石持续形成,2h45min后石膏消耗完毕,铝酸盐-AFm开始形成,同时钙矾石的数量在7h内保持不变。热曲线的第一个峰源自机械搅拌、初始润湿和溶解,还有钙矾石和石膏的形成,第二个峰为石膏被钙矾石所替代,第三个对应于铝酸盐-AFm的形成。石膏被钙矾石替代伴随着0.7%平均线性膨胀。     

SEM-EDX analysis in the source apportionment of particulate matter on Hypogymnia physodes lichen transplants around the Cu smelter and former mining town of Karabash, South Urals, Russia

Scanning electron microscopy with energy-dispersive X-ray analysis (SEM-EDX) of particulate matter on lichen transplant thalli (Hypogymnia physodes) was assessed as a complementary technique to wet chemical analysis for source apportionment of airborne contaminants. Transplants (2 month exposure) stationed in the Cu smelter and former mining town of Karabash were compared with those from a control site 30 km south. Particulate matter in Karabash samples (715 analyses) showed higher levels of S, Pb, Cu, Sn and Zn compared with the control (598 analyses). Complex element associations among the particles confounded detailed mineralogical identifications, and therefore a simplified particle classification scheme was devised for source apportionment. Karabash samples contained high levels of particles classified as mining-related (MRP), and these were also identified in control samples, indicating wide spatial dispersion from the smelter and highlighting the sensitivity of the method. It was noted that MRP <2.5-microm diameter were poorly represented on lichen surfaces suggesting this may limit the usefulness of Hypogymnia transplants as proxies when assessing human health impacts from airborne particulates. Analyses of the lichen thallus surface (away from surface particulates) revealed high levels of Cu, Zn, Fe and Pb associated with organics in the Karabash samples compared with the control, with a proportionate loss of K, interpreted as being due to a stress-related increase in cell membrane permeability. This type of analysis may provide a novel SEM-EDX-based method for assessing lichen vitality. The techniques developed are presented and further implications of the study are discussed.     

Biofilm quantification on stone surfaces: comparison of various methods

In the present study, the efficacy of three different methods of estimating biofilm biomass on stone (amount of chlorophyll a, fluorescein diacetate hydrolysis and changes in colour) is discussed. Stone samples were sprayed with solutions of cyanobacteria and the actual microbial biomass--determined by cell culture--was compared with the biomass estimated using the different methods. Statistically significant differences between actual biomass and that estimated from the fluorescein diacetate hydrolysis method invalidate its use. However, although the results indicated the amount of chlorophyll to be a good estimator of biofilm biomass, problems in the total extraction of chlorophyll from the stone cannot be overlooked. Determination of changes in colour was found to be a good method of quantifying biofilms growing on stone.     

Assessment of environmental tobacco smoke exposure: urinary cotinine concentrations in children are strongly associated with the house dust concentrations of nicotine at home

In the present study the possibility of using nicotine in house dust as an index of environmental tobacco smoke (ETS) exposure was evaluated in an environmental investigation of 23 children with asthma. A standardized procedure for house dust sampling of nicotine with a filter holder connected to a vacuum cleaner, for a defined time and area was developed (F-nicotine). Also, house dust sampling was carried out from the vacuum cleaner bags of the homes (VC-nicotine). There was a larger variation in VC-nicotine (13-655, median 66 microg/g) compared with F-nicotine (15-393 median 156 microg/g). There were statistically significant associations between an inquiry data based ETS exposure index on the one hand, and urinary cotinine concentrations in children (U-cotinine), F-nicotine and VC-nicotine of their homes, on the other. The strong correlation between U-cotinine and F-nicotine (rs = 0.93; P < 0.0001) indicates that the new standardized house dust sampling method should be useful in ETS exposure assessment. However, further validation by a larger sample size with repeated measurements in the same homes is needed.     

Haloacetic acids and trihalomethanes in finished drinking waters from heterogeneous sources

Trihalomethanes (THM) and haloacetic acids (HAA) are the most frequent chlorination by-products (CBP) in finished drinking waters. Traditionally, THM have been used as surrogates for CBP although the quantitative association between THM and other CBP is not well established. This problem is addressed in the present study from the analysis of THM and HAA in drinking water samples from four Spanish regions, representing areas with very different CBP composition, e.g. between 86 and 8.0 microg/l of THM and 50-3.0 microg/l of HAA.The resulting dataset exhibit a statistically significant correlation between total THM and HAA (Pearson's correlation coefficient, r(p)=0.815,p<0.0005). Furthermore, specific HAA are highly correlated with specific THM or their combinations. Accordingly, multivariate linear regression analysis of the concentrations observed show that the levels in total and specific HAA can be predicted from the THM content. These results are relevant for epidemiological studies on health effects from CBP exposure since they usually involve comparison of populations consuming waters of very distinct quality.     

Radon and 'King Solomon's Miners': Faynan Orefield, Jordanian Desert

Concentrations of 222Rn were measured in ancient copper mines which exploited the Faynan Orefield in the South-Western Jordanian Desert. The concentrations of radon gas detected indicate that the ancient metal workers would have been exposed to a significant health risk and indicate that any future attempt to exploit the copper ores must deal with the hazard identified. Seasonal variations in radon concentrations are noted and these are linked to the ventilation of the mines. These modern data are used to explore the differential exposure to radon and the health of ancient mining communities.     

The impact of preoxidation of SAS on biosorption efficiency on activated carbon

We have studied the process of a prolonged dynamic filtration on activated carbon in two biosorption systems — without preoxidation treatment of the initial matter and after ozonization. It has been shown that given the uniform load on activated carbon terms of the organic matter the efficiency of the biosorption process after preozonization is 2.3 times as small compared with that that without pretreatment, which correlates with the change of adsorption free energy.